File name: Pandora240s1_Thessaloniki_20250324_L2Fit_fout2c13d20231018p1-8.txt File generation date: 20250324T223806.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Alkiviadis Bais Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 240 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora240_OF_v2d20220707.txt Instrument calibration file used: Pandora240s1_CF_v13d20231018.txt Level 1 file used: Pandora240s1_Thessaloniki_20250324_L1_smca1c13d20231018p1-8.txt Full location name: Thessaloniki Short location name: Thessaloniki Country of location: Greece Location latitude [deg]: 40.6336 Location longitude [deg]: 22.9561 Location altitude [m]: 60 Local noon date: 20250324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 for VP 20231018 First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0967 305.2379 305.3790 305.5201 305.6613 305.8024 305.9434 306.0845 306.2256 306.3666 306.5076 306.6487 306.7897 306.9307 307.0717 307.2126 307.3536 307.4945 307.6355 307.7764 307.9173 308.0582 308.1991 308.3400 308.4808 308.6217 308.7625 308.9034 309.0442 309.1850 309.3258 309.4665 309.6073 309.7480 309.8888 310.0295 310.1702 310.3109 310.4516 310.5923 310.7330 310.8736 311.0143 311.1549 311.2955 311.4361 311.5767 311.7173 311.8578 311.9984 312.1389 312.2795 312.4200 312.5605 312.7010 312.8415 312.9819 313.1224 313.2628 313.4033 313.5437 313.6841 313.8245 313.9649 314.1053 314.2456 314.3860 314.5263 314.6666 314.8069 314.9472 315.0875 315.2278 315.3680 315.5083 315.6485 315.7888 315.9290 316.0692 316.2094 316.3495 316.4897 316.6298 316.7700 316.9101 317.0502 317.1903 317.3304 317.4705 317.6106 317.7506 317.8907 318.0307 318.1707 318.3107 318.4507 318.5907 318.7307 318.8706 319.0106 319.1505 319.2904 319.4303 319.5702 319.7101 319.8500 319.9898 320.1297 320.2695 320.4093 320.5491 320.6889 320.8287 320.9685 321.1083 321.2480 321.3877 321.5275 321.6672 321.8069 321.9466 322.0863 322.2259 322.3656 322.5052 322.6448 322.7845 322.9241 323.0637 323.2032 323.3428 323.4824 323.6219 323.7614 323.9010 324.0405 324.1800 324.3194 324.4589 324.5984 324.7378 324.8773 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250324T095217.3Z 9214.411312 250 1 13.89 2 40.19 163.55 83.33 226.93 0.00 1 0.00 1 0 17 1.244e-02 9.042e-03 8.010e-03 5.043e-03 1.877698e-01 2.600179e-03 2.257347e-03 -6.000000e+00 7.150100e-03 226.86 -2.00 3.50 -2.00 315.21 0.00e+00 -1.033734e-04 2.319548e-04 6.397553e-05 -6.000000e+00 3.110062e-04 277.89 -2.00 20.00 -2.00 314.69 0.00e+00 1.308 0.000 302.00 328.00 3 5.6383e+00 6.6605e-03 1.6113e-02 -6.0000e+00 1.7768e-02 2.6031e-03 7.3899e-03 9.4597e-03 -6.0000e+00 1.9255e-02 -7.7849e-03 4.2530e-03 4.6637e-03 -6.0000e+00 1.1437e-02 -1.5738e-03 1.9400e-03 1.3274e-03 -6.0000e+00 4.9288e-03 4.2591e-04 5.5811e-04 1.3816e-04 1.5888e-05 -6.0000e+00 3.2842e-04 -8.0374e-03 0.0000e+00 12 9 1 12 1 1 68.04 23.75 0.84 -0.00804 -0.00384 3 2 1 8 0 3472.231 20.00 23.75 24.48 27.75 28.00 36.8 1045.72 1291 -2452 134 -5380 554 1759 -223 -144 -3907 -115 -2435 -2775 286 -1891 624 2301 -229 2560 3320 638 240 153 1668 -1060 1009 39 -1243 -412 514 -634 -1269 1746 1580 -2176 -2757 1626 -1129 693 1034 -1308 -13 -398 129 -1152 -836 -211 -1208 -1358 -437 1374 163 767 598 414 2406 1990 1654 605 1439 33 433 1713 346 725 -270 -26 473 -614 1484 42 -1069 -17 2 326 5 524 -713 -646 100 -1617 -1187 -2154 -3316 -1852 -1272 -592 741 -221 105 499 317 260 266 1166 977 -424 276 769 -651 298 -496 -711 -150 1123 -934 -1175 -586 -1097 185 751 628 -352 909 19 -55 711 672 372 531 124 684 603 757 -431 1476 -63 228 369 266 -262 227 -502 -921 40 -313 89 200 -349 23 -750 333 -607 346 -708 38 -1587 136 419 -58 -42 -1294 -38 -786 -925 103 -712 256 990 -102 1148 1510 308 117 74 812 -559 501 20 -631 -207 238 -292 -622 867 847 -1203 -1391 802 -636 415 685 -1009 -10 -312 103 -925 -666 -166 -988 -1079 -333 1032 132 608 495 360 2074 1756 1485 541 1253 30 399 1577 344 751 -270 -24 423 -541 1410 43 -1106 -18 2 345 5 482 -608 -563 87 -1511 -1216 -2298 -3738 -2159 -1510 -741 912 -280 131 621 361 286 283 1220 1038 -502 336 971 -855 370 -614 -812 -176 1328 -1158 -1511 -790 -1464 256 1040 900 -501 1261 25 -67 881 808 472 694 172 953 825 1010 -548 1852 -77 275 438 338 -334 299 -671 -1263 54 -453 128 292 -525 35 -1088 466 -867 SS 20250324T101002.6Z 9214.423641 256 1 54.79 2 39.42 170.38 85.73 229.99 0.00 1 0.00 1 0 17 1.474e-02 8.079e-03 7.879e-03 3.751e-03 1.808353e-01 1.908364e-03 2.167579e-03 -6.000000e+00 8.472747e-03 226.86 -2.00 3.50 -2.00 316.15 0.00e+00 3.621561e-04 2.070569e-04 2.903455e-05 -6.000000e+00 3.687390e-04 277.89 -2.00 20.00 -2.00 315.56 0.00e+00 1.293 0.000 302.00 328.00 3 6.2120e+00 4.9457e-03 1.5798e-02 -6.0000e+00 2.1055e-02 -3.5120e-03 5.5133e-03 9.1508e-03 -6.0000e+00 2.2820e-02 8.3870e-03 3.2093e-03 4.5170e-03 -6.0000e+00 1.3554e-02 -1.1099e-02 1.5226e-03 1.3074e-03 -6.0000e+00 5.8381e-03 2.4562e-04 -2.1250e-04 1.0429e-04 1.4686e-05 -6.0000e+00 3.8957e-04 -4.8630e-03 0.0000e+00 11 8 0 10 0 0 99.83 23.81 0.92 -0.00486 -0.00646 14 2 1 8 0 3913.090 20.00 23.81 25.69 28.00 28.00 37.1 1052.39 -2546 -1459 -2399 -3386 3034 3181 6602 -843 1363 640 1452 -6225 -3825 -433 -144 1099 2351 -1757 -578 993 2204 3055 -224 -377 1850 355 -1048 -636 -2818 1174 623 1248 3131 -2314 -3318 2091 -2371 169 -312 -702 -416 -717 -1097 -163 -262 -1357 -1705 853 -1685 1229 1238 346 1048 1819 914 1055 1368 177 723 671 224 1479 558 854 -891 -381 -349 -1172 1213 283 -38 804 -359 681 111 864 -354 -934 -338 -1801 -1467 -1119 -2259 -1965 -358 -844 195 -276 416 -87 534 784 256 654 349 769 275 1201 487 -127 135 -913 -708 1207 -1093 -1259 -53 -931 600 -57 1098 -391 505 53 -101 495 164 -116 -214 -102 123 773 421 -462 1343 -19 -175 823 -97 -152 -647 -474 -545 164 -11 121 333 291 -339 -160 -273 -84 -509 -301 -503 -651 483 495 1056 -163 282 138 327 -1415 -950 -116 -43 347 739 -596 -218 346 847 1137 -89 -157 784 157 -459 -256 -1080 424 239 498 1320 -1026 -1348 820 -1080 88 -177 -455 -286 -511 -805 -118 -189 -984 -1193 564 -1106 863 838 251 784 1417 726 852 1117 145 576 538 188 1323 537 857 -871 -332 -286 -941 1044 278 -40 866 -384 695 105 720 -273 -760 -267 -1625 -1451 -1209 -2579 -2149 -418 -1053 254 -367 545 -109 605 880 262 661 380 839 331 1574 661 -165 164 -1037 -781 1409 -1418 -1693 -74 -1363 838 -85 1665 -591 713 74 -130 606 206 -153 -309 -144 174 1070 571 -645 1759 -25 -210 1011 -129 -211 -869 -640 -750 235 -17 192 538 449 -524 -256 -429 -127 SS 20250324T101519.2Z 9214.427306 258 1 54.23 2 39.27 172.45 86.46 230.87 0.00 1 0.00 1 0 17 1.018e-02 7.079e-03 3.563e-03 1.863e-03 1.799969e-01 9.538048e-04 2.217564e-03 -6.000000e+00 5.847692e-03 226.86 -2.00 3.50 -2.00 315.92 0.00e+00 1.416911e-04 9.769394e-05 2.501206e-05 -6.000000e+00 2.545376e-04 277.89 -2.00 20.00 -2.00 315.33 0.00e+00 1.291 0.000 302.00 328.00 3 4.9516e+00 2.4632e-03 1.5832e-02 -6.0000e+00 1.4531e-02 -7.4251e-03 2.7410e-03 9.2514e-03 -6.0000e+00 1.5751e-02 2.5757e-03 1.5889e-03 4.5721e-03 -6.0000e+00 9.3549e-03 -7.6547e-03 7.4418e-04 1.3037e-03 -6.0000e+00 4.0289e-03 8.7444e-04 -2.5573e-05 5.1662e-05 1.5268e-05 -6.0000e+00 2.6895e-04 -3.9327e-03 0.0000e+00 11 8 0 10 0 0 99.88 23.82 0.86 -0.00393 -0.00412 45 5 1 8 0 1204.687 20.01 23.82 26.00 27.75 28.00 37.0 1053.05 -1941 -3296 -1771 -2907 -2229 1606 -2423 34 -334 696 -2302 -815 -1730 -319 -144 -486 918 276 835 1616 1800 367 1246 1330 146 817 -325 209 735 1404 1458 365 1779 -1211 -3207 364 -1741 -512 -389 -1087 -991 -347 -860 -1365 -168 -295 -571 -134 -442 789 1002 517 629 1733 928 1224 475 531 682 568 1026 989 903 546 -727 -17 199 -488 1150 165 -97 93 -252 923 34 -4 -287 -1670 233 -820 -1677 -1440 -2620 -1242 -736 -1198 -35 -283 273 -130 609 531 562 963 975 363 307 876 -375 -273 264 -769 400 906 -1326 -972 -495 -704 268 397 397 -199 517 77 31 711 604 -28 78 26 -358 233 374 -450 796 520 375 1487 173 55 -165 -280 -224 271 -380 -195 -29 121 -220 -123 95 -684 -411 -735 -392 -588 -436 296 -496 8 -82 175 -571 -205 -491 -99 -45 -164 339 106 327 648 729 148 512 574 66 378 -149 87 285 531 582 154 796 -555 -1359 152 -826 -281 -232 -741 -717 -257 -658 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