File name: Pandora192s1_Tokyo-Sophia_20230803_L2Fit_fout2c4d20230711p1-8.txt File generation date: 20240911T103209.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Hiroshi Tanimoto Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v2d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20230803_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20230803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0295 305.1706 305.3117 305.4528 305.5938 305.7349 305.8759 306.0169 306.1580 306.2990 306.4400 306.5810 306.7219 306.8629 307.0038 307.1448 307.2857 307.4266 307.5676 307.7085 307.8493 307.9902 308.1311 308.2720 308.4128 308.5536 308.6945 308.8353 308.9761 309.1169 309.2577 309.3984 309.5392 309.6800 309.8207 309.9614 310.1022 310.2429 310.3836 310.5243 310.6650 310.8056 310.9463 311.0869 311.2276 311.3682 311.5088 311.6494 311.7900 311.9306 312.0712 312.2117 312.3523 312.4928 312.6334 312.7739 312.9144 313.0549 313.1954 313.3359 313.4763 313.6168 313.7572 313.8977 314.0381 314.1785 314.3189 314.4593 314.5997 314.7401 314.8804 315.0208 315.1611 315.3014 315.4418 315.5821 315.7224 315.8627 316.0029 316.1432 316.2834 316.4237 316.5639 316.7041 316.8444 316.9846 317.1247 317.2649 317.4051 317.5453 317.6854 317.8255 317.9657 318.1058 318.2459 318.3860 318.5260 318.6661 318.8062 318.9462 319.0863 319.2263 319.3663 319.5063 319.6463 319.7863 319.9263 320.0662 320.2062 320.3461 320.4860 320.6260 320.7659 320.9058 321.0456 321.1855 321.3254 321.4652 321.6051 321.7449 321.8847 322.0245 322.1643 322.3041 322.4439 322.5837 322.7234 322.8632 323.0029 323.1426 323.2823 323.4220 323.5617 323.7014 323.8411 323.9807 324.1204 324.2600 324.3996 324.5392 324.6788 324.8184 324.9580 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230802T203830.0Z 8614.860070 215 1 24.49 2 81.55 74.29 86.27 244.98 0.00 1 0.00 1 0 17 6.928e-01 1.093e-02 3.543e-01 5.755e-03 7.442355e-01 3.409899e-03 8.529800e-03 -6.000000e+00 4.382552e-01 231.84 -2.00 3.41 -2.00 321.83 0.00e+00 2.796506e-03 2.192172e-03 7.935463e-03 -6.000000e+00 2.086147e-02 292.44 -2.00 20.00 -2.00 321.22 0.00e+00 6.397 0.004 302.00 328.00 3 1.1093e+00 1.4388e-02 8.5868e-02 -6.0000e+00 1.0944e+00 1.8167e-01 2.0619e-02 6.8154e-02 -6.0000e+00 1.1810e+00 -2.3204e-01 1.9251e-02 2.6847e-02 -6.0000e+00 7.0546e-01 8.6157e-02 8.6347e-03 5.9107e-03 -6.0000e+00 2.9140e-01 1.4962e-04 -3.2550e-04 1.8473e-04 1.4574e-04 -6.0000e+00 2.3776e-02 8.6895e-03 0.0000e+00 12 9 9 12 1 1 11.25 17.61 0.30 0.00869 0.00624 68 31 1 5 0 352.360 21.69 14.99 17.61 33.01 30.1 1030.45 -248908 -184717 -275283 -266305 -272876 -57075 -254188 -169223 -78768 -87018 900000 -170098 72631 57513 -164414 141325 -91994 237642 16447 13165 -76269 -69574 -5691 -98429 171035 -66115 -20253 -9977 -47494 62552 -47499 37364 -33838 9373 -7550 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-96 -375 -112 -347 -2836 -861 -1286 -1595 -1810 -1043 182 1030 1633 524 1285 -344 291 -85 -594 340 -318 1244 721 835 990 765 1208 -341 371 32 184 569 -828 -126 -538 -311 -280 -604 -257 586 1260 -171 377 -415 -804 -509 SS 20230802T205243.8Z 8614.869951 220 1 48.76 2 78.76 76.24 88.77 247.09 0.00 1 0.00 1 0 17 3.328e-01 5.501e-03 6.605e-02 1.290e-03 6.087668e-01 7.367256e-04 6.905410e-03 -6.000000e+00 2.105068e-01 231.84 -2.00 3.41 -2.00 321.18 0.00e+00 1.386482e-03 3.813072e-04 4.014688e-03 -6.000000e+00 9.606926e-03 292.44 -2.00 20.00 -2.00 320.47 0.00e+00 4.950 0.002 302.00 328.00 3 3.9246e-01 2.6507e-03 6.1691e-02 -6.0000e+00 5.2529e-01 4.2222e-02 3.5897e-03 4.1406e-02 -6.0000e+00 5.6660e-01 -1.8947e-02 3.2398e-03 1.7909e-02 -6.0000e+00 3.3886e-01 -7.1241e-03 1.5236e-03 4.2809e-03 -6.0000e+00 1.3966e-01 1.3725e-03 -1.4216e-04 4.3230e-05 8.0155e-05 -6.0000e+00 1.1391e-02 8.9120e-03 0.0000e+00 10 0 0 10 0 0 9.75 17.61 0.22 0.00891 0.00784 695 153 1 5 0 70.140 21.69 15.00 17.61 33.80 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273 409 466 196 489 94 273 66 367 558 570 894 285 599 18 138 454 739 809 338 418 107 -244 -183 -866 -731 -803 -609 -383 -530 -705 -879 -209 -213 601 632 700 673 94 -176 -544 -474 57 216 545 251 231 -461 -1181 -1165 -1288 -551 -1293 -901 -848 -501 566 723 1326 706 489 -213 -306 130 -75 777 482 700 423 541 669 104 118 -237 -51 204 -185 62 -853 -678 -787 -158 -106 -233 917 21 286 43 -84 -93 -233 SS 20230802T205821.7Z 8614.873862 223 1 48.63 2 77.65 77.00 89.77 247.91 0.00 1 0.00 1 0 17 2.441e-01 5.157e-03 3.950e-02 9.530e-04 5.654515e-01 5.437216e-04 6.386025e-03 -6.000000e+00 1.544214e-01 231.84 -2.00 3.41 -2.00 320.92 0.00e+00 1.090593e-03 2.538950e-04 3.076166e-03 -6.000000e+00 7.047193e-03 292.44 -2.00 20.00 -2.00 320.16 0.00e+00 4.538 0.001 302.00 328.00 3 3.5456e-01 1.8579e-03 5.5730e-02 -6.0000e+00 3.8534e-01 3.7956e-02 2.4214e-03 3.5396e-02 -6.0000e+00 4.1564e-01 -8.8581e-03 2.0987e-03 1.5796e-02 -6.0000e+00 2.4857e-01 -1.1320e-02 1.0107e-03 3.9458e-03 -6.0000e+00 1.0246e-01 2.1929e-03 -1.4159e-04 3.2566e-05 6.9931e-05 -6.0000e+00 8.3558e-03 8.6929e-03 0.0000e+00 10 0 0 10 0 0 6.76 17.62 0.22 0.00869 0.00763 881 193 1 5 0 55.190 21.69 15.00 17.62 34.28 30.1 1038.70 -93030 -78974 -103133 -63602 -96173 -78215 -79557 -90018 -57836 -83398 -41531 -51164 -34216 -42331 -36342 -22464 -20380 -10785 -10519 -8786 -10678 -12008 -8071 -10503 -10165 -7032 -8869 -10647 -13979 -8918 -10832 -2289 -3444 -4447 -8565 -10118 -4597 -4348 -1125 836 -202 886 34 -129 499 1438 401 -182 -564 -352 1663 1468 1971 2142 807 1416 1556 722 792 391 1328 2071 2947 2242 1380 537 120 203 806 1525 1426 1273 631 417 -304 -1740 -2222 -2246 -1625 -992 -887 -1206 -1614 -983 -563 166 771 786 903 375 348 -159 -800 -598 -173 390 497 403 139 -313 -748 -1165 -1050 -669 -870 -937 -736 -184 350 641 781 530 186 -140 -215 -70 158 507 403 406 222 194 264 142 148 -46 81 109 -63 -140 -294 -407 -425 -101 -187 4 289 86 143 168 -30 -184 -114 -597 -514 -924 -387 -788 -535 -592 -837 -484 -902 -355 -547 -372 -618 -611 -388 -392 -208 -220 -192 -248 -292 -199 -286 -299 -212 -278 -338 -463 -298 -416 -93 -160 -222 -454 -560 -264 -293 -88 76 -21 99 4 -16 62 181 52 -24 -79 -52 265 259 379 444 180 329 371 174 190 94 330 553 862 719 465 182 41 71 305 638 652 609 303 192 -131 -700 -848 -864 -677 -470 -482 -741 -1090 -709 -431 135 651 681 778 314 275 -119 -583 -446 -140 356 515 465 155 -353 -885 -1285 -1099 -702 -959 -1095 -910 -221 453 904 1184 838 294 -214 -314 -99 224 742 619 645 353 303 398 206 227 -69 120 166 -96 -235 -533 -782 -861 -215 -424 9 702 212 349 397 -67 -401 -245 SS 20230802T210340.7Z 8614.877555 226 1 48.66 2 76.60 77.73 90.73 248.68 0.00 1 0.00 1 0 17 1.510e-01 4.849e-03 2.781e-02 7.412e-04 5.294032e-01 4.231245e-04 5.957821e-03 -6.000000e+00 9.554128e-02 231.84 -2.00 3.41 -2.00 320.68 0.00e+00 8.881795e-04 1.798680e-04 2.248509e-03 -6.000000e+00 4.360102e-03 292.44 -2.00 20.00 -2.00 319.88 0.00e+00 4.206 0.001 302.00 328.00 3 3.1368e-01 1.3980e-03 5.1106e-02 -6.0000e+00 2.3841e-01 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