File name: Pandora192s1_Tokyo-Sophia_20230830_L2Fit_fwvt1c2d20230711p1-8.txt File generation date: 20240415T140606.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20230830_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20230830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0047 492.1264 492.2480 492.3697 492.4913 492.6129 492.7344 492.8560 492.9776 493.0991 493.2206 493.3421 493.4636 493.5850 493.7065 493.8279 493.9493 494.0707 494.1921 494.3135 494.4348 494.5561 494.6775 494.7987 494.9200 495.0413 495.1625 495.2838 495.4050 495.5262 495.6473 495.7685 495.8897 496.0108 496.1319 496.2530 496.3741 496.4951 496.6162 496.7372 496.8582 496.9792 497.1002 497.2211 497.3421 497.4630 497.5839 497.7048 497.8257 497.9465 498.0674 498.1882 498.3090 498.4298 498.5506 498.6713 498.7921 498.9128 499.0335 499.1542 499.2749 499.3955 499.5162 499.6368 499.7574 499.8780 499.9985 500.1191 500.2396 500.3601 500.4807 500.6011 500.7216 500.8421 500.9625 501.0829 501.2033 501.3237 501.4441 501.5644 501.6847 501.8051 501.9254 502.0456 502.1659 502.2862 502.4064 502.5266 502.6468 502.7670 502.8871 503.0073 503.1274 503.2475 503.3676 503.4877 503.6078 503.7278 503.8478 503.9678 504.0878 504.2078 504.3278 504.4477 504.5676 504.6875 504.8074 504.9273 505.0471 505.1670 505.2868 505.4066 505.5264 505.6462 505.7659 505.8857 506.0054 506.1251 506.2448 506.3644 506.4841 506.6037 506.7233 506.8429 506.9625 507.0821 507.2016 507.3211 507.4407 507.5601 507.6796 507.7991 507.9185 508.0380 508.1574 508.2768 508.3961 508.5155 508.6348 508.7541 508.8735 508.9927 509.1120 509.2313 509.3505 509.4697 509.5889 509.7081 509.8273 509.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230829T215148.1Z 8641.910973 227 1 13.42 2 70.51 92.61 127.47 271.50 0.00 1 0.00 1 0 22 5.170e-03 5.133e-03 1.398e-03 1.395e-03 7.621631e+03 9.558576e+01 5.098226e+02 -6.000000e+00 2.996374e+02 291.89 -2.00 20.00 -2.00 505.27 0.00e+00 6.720307e-04 3.943318e-05 4.647557e-05 -6.000000e+00 1.489960e-04 291.89 -2.00 20.00 -2.00 500.43 0.00e+00 2.214208e-01 2.777440e-02 4.622212e-02 -6.000000e+00 1.028808e-01 230.51 -2.00 3.41 -2.00 502.02 0.00e+00 2.962 0.000 489.00 513.00 1 6.7433e+00 2.1320e-03 5.8759e-03 -6.0000e+00 7.9113e-03 2.3553e-02 5.4765e-04 1.1389e-03 -6.0000e+00 2.0511e-03 1.4601e-03 -4.9347e-04 1.3559e-04 4.6969e-05 -6.0000e+00 5.3298e-04 -1.4433e-02 -1.2565e-05 12 9 9 12 1 1 59.72 17.34 0.70 -0.01443 -0.01786 5 5 1 4 0 2207.300 21.48 15.00 17.34 34.44 30.6 1020.72 900000 -1023 -704 -229 8 -85 671 661 546 552 356 310 -520 -641 -525 -756 -276 -252 265 223 -50 420 214 534 447 670 554 738 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329 160 179 -223 -568 -697 -234 -146 -220 10 318 274 555 1123 999 548 571 133 -46 271 492 154 38 173 261 378 739 -105 -278 -380 -556 -568 -287 -167 -386 -132 79 -90 429 367 313 572 489 -355 -707 -614 -424 SQ 20230829T220151.3Z 8641.917955 230 1 5.63 2 68.47 94.12 129.39 273.01 0.00 1 0.00 1 0 22 4.818e-03 4.773e-03 9.446e-05 9.426e-05 6.889542e+03 6.394913e+00 4.708049e+02 -6.000000e+00 2.792324e+02 291.89 -2.00 20.00 -2.00 505.28 0.00e+00 6.427657e-04 2.659683e-06 4.294743e-05 -6.000000e+00 1.388474e-04 291.89 -2.00 20.00 -2.00 500.49 0.00e+00 1.533967e-01 1.873392e-03 4.098259e-02 -6.000000e+00 9.585103e-02 230.50 -2.00 3.41 -2.00 502.07 0.00e+00 2.700 0.000 489.00 513.00 1 -4.8232e-01 1.4378e-04 5.3025e-03 -6.0000e+00 7.3712e-03 2.5892e-03 3.6939e-05 1.0296e-03 -6.0000e+00 1.9104e-03 2.0968e+00 -7.9029e-04 9.2396e-06 4.5082e-05 -6.0000e+00 4.9668e-04 -1.6666e-02 2.0136e-05 12 8 8 10 0 0 6.84 17.35 0.81 -0.01667 -0.02215 1042 229 2 4 0 5.180 21.48 15.00 17.35 35.20 30.7 1026.28 900000 -969 -682 -197 -71 120 720 742 625 399 207 193 -252 -673 -646 -669 -576 -205 291 228 53 307 292 356 681 645 574 560 40 -883 -795 -605 -692 16 575 100 24 114 -43 -261 -98 11 87 364 570 595 594 518 415 -13 -659 -901 -1151 -1055 -470 -122 -45 10 -18 -6 180 442 445 434 397 224 111 35 -85 -494 -476 -212 -121 145 316 -49 -316 -294 -402 -618 -599 -460 -590 -436 -34 -156 -234 -180 -157 -26 150 597 982 798 582 707 391 -62 -515 -1066 -1124 -884 -405 211 91 -218 -284 -552 -556 -214 -122 -132 98 213 313 596 935 890 481 329 176 -65 163 485 215 157 390 277 392 655 0 -385 -257 -581 -782 -301 -220 -351 -29 186 113 256 417 485 514 264 -281 -646 -616 -551 900000 -930 -667 -198 -71 121 741 774 656 417 214 196 -254 -670 -637 -659 -573 -207 299 240 56 326 309 378 723 688 610 590 42 -898 -788 -596 -690 16 602 103 24 120 -45 -271 -101 12 91 383 579 606 604 546 431 -13 -656 -874 -1103 -1011 -457 -122 -46 10 -19 -6 186 459 464 452 411 229 112 35 -84 -482 -460 -205 -118 142 313 -49 -309 -283 -383 -586 -568 -439 -568 -424 -34 -154 -232 -178 -156 -26 149 598 991 807 582 690 373 -58 -492 -1009 -1063 -811 -383 206 91 -213 -275 -555 -554 -213 -123 -129 96 211 311 595 936 894 483 326 172 -62 162 483 216 151 375 266 392 651 0 -377 -248 -558 -755 -293 -219 -340 -29 184 113 257 419 488 516 263 -277 -625 -587 -525 SQ 20230829T220157.4Z 8641.918026 230 2 5.67 2 68.45 94.14 129.41 273.03 0.00 1 0.00 1 0 22 4.807e-03 4.759e-03 9.449e-05 9.429e-05 6.848677e+03 6.387648e+00 4.680137e+02 -6.000000e+00 2.785772e+02 291.89 -2.00 20.00 -2.00 505.28 0.00e+00 6.400477e-04 2.656381e-06 4.287662e-05 -6.000000e+00 1.385215e-04 291.89 -2.00 20.00 -2.00 500.49 0.00e+00 1.564630e-01 1.870896e-03 4.084879e-02 -6.000000e+00 9.562573e-02 230.50 -2.00 3.41 -2.00 502.08 0.00e+00 2.697 0.000 489.00 513.00 1 -4.8147e-01 1.4350e-04 5.2917e-03 -6.0000e+00 7.3538e-03 2.5725e-03 3.6924e-05 1.0254e-03 -6.0000e+00 1.9059e-03 2.0955e+00 -7.4330e-04 9.2416e-06 4.4688e-05 -6.0000e+00 4.9551e-04 -1.6987e-02 2.2435e-05 12 8 8 10 0 0 -4.82 17.35 0.81 -0.01699 -0.02214 1042 229 2 4 0 5.180 21.48 15.00 17.35 35.20 30.7 1026.28 900000 -976 -695 -189 -74 138 748 771 634 416 180 194 -236 -646 -628 -666 -572 -213 267 226 59 331 283 309 628 600 559 579 34 -880 -769 -598 -684 35 602 122 26 158 -19 -253 -151 8 98 361 571 576 565 496 391 -56 -689 -919 -1160 -1025 -423 -106 -33 5 -6 -10 181 445 441 461 417 218 106 71 -78 -518 -496 -223 -160 120 308 -42 -292 -277 -407 -624 -607 -464 -599 -457 -46 -169 -212 -202 -157 -16 133 569 958 789 585 743 399 -97 -524 -1066 -1138 -881 -420 225 87 -215 -299 -560 -533 -168 -126 -115 110 263 340 602 909 864 464 328 200 -42 173 484 186 165 385 277 413 658 22 -368 -261 -594 -803 -276 -206 -368 -44 181 105 260 421 458 502 272 -236 -637 -617 -566 900000 -936 -679 -190 -73 140 769 804 665 435 186 197 -238 -643 -619 -657 -569 -215 275 238 63 351 300 328 667 639 595 610 35 -895 -762 -588 -682 35 630 124 26 167 -20 -262 -156 9 102 380 580 588 574 523 406 -57 -685 -891 -1110 -982 -411 -105 -34 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