File name: Pandora192s1_Tokyo-Sophia_20230907_L2Fit_fwvt1c4d20230711p1-8.txt File generation date: 20240911T105533.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20230907_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20230907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0873 492.2090 492.3306 492.4523 492.5739 492.6955 492.8171 492.9386 493.0602 493.1817 493.3032 493.4247 493.5462 493.6677 493.7891 493.9106 494.0320 494.1534 494.2748 494.3961 494.5175 494.6388 494.7601 494.8815 495.0027 495.1240 495.2453 495.3665 495.4877 495.6089 495.7301 495.8513 495.9724 496.0936 496.2147 496.3358 496.4569 496.5780 496.6990 496.8201 496.9411 497.0621 497.1831 497.3041 497.4251 497.5460 497.6669 497.7878 497.9087 498.0296 498.1505 498.2713 498.3921 498.5130 498.6338 498.7545 498.8753 498.9960 499.1168 499.2375 499.3582 499.4789 499.5995 499.7202 499.8408 499.9614 500.0820 500.2026 500.3232 500.4437 500.5643 500.6848 500.8053 500.9258 501.0462 501.1667 501.2871 501.4075 501.5279 501.6483 501.7687 501.8890 502.0094 502.1297 502.2500 502.3703 502.4906 502.6108 502.7310 502.8513 502.9715 503.0917 503.2118 503.3320 503.4521 503.5722 503.6923 503.8124 503.9325 504.0526 504.1726 504.2926 504.4126 504.5326 504.6526 504.7726 504.8925 505.0124 505.1323 505.2522 505.3721 505.4920 505.6118 505.7316 505.8514 505.9712 506.0910 506.2108 506.3305 506.4502 506.5699 506.6896 506.8093 506.9290 507.0486 507.1682 507.2878 507.4074 507.5270 507.6466 507.7661 507.8856 508.0052 508.1246 508.2441 508.3636 508.4830 508.6025 508.7219 508.8413 508.9606 509.0800 509.1993 509.3187 509.4380 509.5573 509.6766 509.7958 509.9151 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230906T215139.3Z 8649.910871 259 1 14.15 2 71.70 95.50 20.92 248.89 0.00 1 0.00 1 0 22 4.094e-03 4.069e-03 8.920e-04 8.904e-04 7.483389e+03 6.202703e+01 5.047993e+02 -6.000000e+00 2.412483e+02 291.42 -2.00 20.00 -2.00 505.27 0.00e+00 6.321335e-04 2.526656e-05 4.456936e-05 -6.000000e+00 1.185955e-04 291.42 -2.00 20.00 -2.00 500.47 0.00e+00 2.561737e-01 1.783574e-02 4.524624e-02 -6.000000e+00 8.214305e-02 229.98 -2.00 3.41 -2.00 502.05 0.00e+00 3.142 0.000 489.00 513.00 1 6.6711e+00 1.3706e-03 6.0078e-03 -6.0000e+00 6.3240e-03 1.4360e-02 3.4892e-04 1.1290e-03 -6.0000e+00 1.6293e-03 1.5268e-03 6.3894e-04 9.0246e-05 4.4717e-05 -6.0000e+00 4.4002e-04 6.4102e-03 -2.2905e-05 12 9 1 12 1 1 92.99 17.23 0.77 0.00641 0.01084 10 9 1 4 0 1269.970 21.38 15.00 17.23 33.54 30.7 1012.91 -770 -585 -197 -183 74 603 639 526 469 277 190 -210 -508 -609 -611 -530 -237 247 151 6 205 337 392 537 788 551 513 66 -645 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225 431 734 730 509 321 132 -78 259 691 202 213 220 -4 224 475 -173 -195 -238 -624 -521 197 -103 -275 52 120 80 295 329 373 354 312 -349 -307 -434 -805 SQ 20230906T215552.1Z 8649.913798 262 1 15.65 2 70.85 96.15 21.70 250.25 0.00 1 0.00 1 0 22 3.880e-03 3.870e-03 1.536e-04 1.533e-04 7.367376e+03 1.068861e+01 4.902404e+02 -6.000000e+00 2.286813e+02 291.42 -2.00 20.00 -2.00 505.27 0.00e+00 6.753798e-04 4.365887e-06 4.665121e-05 -6.000000e+00 1.124223e-04 291.42 -2.00 20.00 -2.00 500.46 0.00e+00 2.032321e-01 3.075874e-03 4.632538e-02 -6.000000e+00 7.787760e-02 229.98 -2.00 3.41 -2.00 502.05 0.00e+00 3.011 0.000 489.00 513.00 1 3.3725e+00 2.3676e-04 5.9256e-03 -6.0000e+00 5.9954e-03 9.3822e-03 6.0161e-05 1.1310e-03 -6.0000e+00 1.5450e-03 4.2263e-02 7.3010e-04 1.5529e-05 4.4327e-05 -6.0000e+00 4.1713e-04 5.4759e-03 -3.0511e-05 12 9 1 12 1 1 67.70 17.23 0.76 0.00548 0.01054 320 122 1 4 0 48.050 21.38 15.00 17.23 33.80 30.8 1014.48 -834 -520 -197 -177 71 599 600 517 418 239 167 -224 -491 -451 -591 -561 -164 217 111 -27 261 274 361 663 562 442 454 96 -600 -555 -569 -587 128 508 -43 -23 162 -40 -184 -40 98 113 309 468 532 489 427 313 -46 -471 -635 -910 -854 -374 -58 -89 -124 -138 -34 265 443 377 399 363 225 110 22 -75 -382 -348 -238 -188 154 311 -94 -468 -347 -272 -340 -356 -413 -540 -246 28 -217 -288 -143 -78 20 170 526 811 536 411 446 87 -146 -270 -686 -909 -727 -276 209 -89 -413 -432 -527 -293 27 -32 -102 89 207 321 556 818 696 364 293 115 -9 299 572 224 235 274 95 294 469 -83 -271 -252 -553 -439 20 -171 -375 -109 72 24 229 318 237 255 59 -187 -425 -396 -363 -816 -518 -194 -180 74 609 619 536 432 245 168 -232 -502 -456 -597 -572 -169 221 115 -28 273 287 379 696 591 465 472 98 -603 -564 -574 -600 128 524 -46 -24 169 -42 -189 -40 100 116 321 490 559 513 443 320 -46 -480 -630 -891 -837 -372 -57 -90 -127 -142 -35 270 453 387 409 371 227 109 22 -75 -381 -344 -235 -187 154 303 -91 -469 -340 -264 -328 -344 -401 -530 -243 28 -210 -281 -139 -75 20 165 517 801 530 402 442 84 -138 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1015.92 -792 -535 -166 -176 57 541 621 516 431 265 174 -282 -429 -498 -586 -568 -141 226 175 -61 261 331 374 664 550 450 434 49 -616 -555 -526 -604 72 519 -129 -28 173 51 -43 -68 117 49 332 477 519 450 418 302 -82 -451 -668 -933 -867 -375 -78 -69 -109 -129 -25 255 420 339 379 418 161 104 39 -54 -444 -294 -169 -147 169 307 -105 -422 -382 -254 -355 -419 -428 -504 -274 21 -328 -387 -178 -88 -44 89 471 759 555 379 468 166 -129 -168 -792 -934 -768 -212 200 -71 -358 -443 -568 -325 82 -38 -37 122 230 379 586 812 685 440 338 138 86 348 604 230 275 272 94 170 496 -66 -225 -265 -508 -483 73 -238 -318 -69 84 0 198 289 210 294 43 -203 -457 -451 -332 -766 -527 -168 -177 58 566 658 529 440 278 180 -289 -434 -498 -586 -573 -144 236 180 -63 271 343 388 689 573 468 447 50 -636 -558 -525 -611 74 530 -134 -29 178 52 -43 -68 118 49 341 494 540 468 429 305 -84 -454 -656 -905 -840 -369 -79 -68 -110 -131 -25 257 425 345 385 422 161 106 40 -54 -439 -288 -165 -145 168 307 -105 -418 -372 -244 -340 -402 -412 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