File name: Pandora192s1_Tokyo-Sophia_20230927_L2Fit_fwvt1c2d20230711p1-8.txt File generation date: 20240415T134634.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20230927_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20230927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0047 492.1264 492.2480 492.3697 492.4913 492.6129 492.7344 492.8560 492.9776 493.0991 493.2206 493.3421 493.4636 493.5850 493.7065 493.8279 493.9493 494.0707 494.1921 494.3135 494.4348 494.5561 494.6775 494.7987 494.9200 495.0413 495.1625 495.2838 495.4050 495.5262 495.6473 495.7685 495.8897 496.0108 496.1319 496.2530 496.3741 496.4951 496.6162 496.7372 496.8582 496.9792 497.1002 497.2211 497.3421 497.4630 497.5839 497.7048 497.8257 497.9465 498.0674 498.1882 498.3090 498.4298 498.5506 498.6713 498.7921 498.9128 499.0335 499.1542 499.2749 499.3955 499.5162 499.6368 499.7574 499.8780 499.9985 500.1191 500.2396 500.3601 500.4807 500.6011 500.7216 500.8421 500.9625 501.0829 501.2033 501.3237 501.4441 501.5644 501.6847 501.8051 501.9254 502.0456 502.1659 502.2862 502.4064 502.5266 502.6468 502.7670 502.8871 503.0073 503.1274 503.2475 503.3676 503.4877 503.6078 503.7278 503.8478 503.9678 504.0878 504.2078 504.3278 504.4477 504.5676 504.6875 504.8074 504.9273 505.0471 505.1670 505.2868 505.4066 505.5264 505.6462 505.7659 505.8857 506.0054 506.1251 506.2448 506.3644 506.4841 506.6037 506.7233 506.8429 506.9625 507.0821 507.2016 507.3211 507.4407 507.5601 507.6796 507.7991 507.9185 508.0380 508.1574 508.2768 508.3961 508.5155 508.6348 508.7541 508.8735 508.9927 509.1120 509.2313 509.3505 509.4697 509.5889 509.7081 509.8273 509.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230926T212359.9Z 8669.891666 166 1 48.46 2 80.39 98.76 135.70 283.38 0.00 1 0.00 1 0 15 4.385e-02 3.623e-02 2.540e-02 2.507e-02 1.424415e+04 1.974992e+03 1.011489e+03 -6.000000e+00 2.519665e+03 289.74 -2.00 20.00 -2.00 505.31 0.00e+00 1.454384e-03 7.091753e-04 5.395881e-05 -6.000000e+00 1.257315e-03 289.74 -2.00 20.00 -2.00 500.13 0.00e+00 4.177431e-01 5.116888e-01 6.681530e-02 -6.000000e+00 8.722439e-01 228.39 -2.00 3.41 -2.00 501.77 0.00e+00 5.706 0.003 489.00 513.00 1 1.0421e+01 3.9259e-02 1.0149e-02 -6.0000e+00 6.7017e-02 3.7469e-02 9.9297e-03 1.9036e-03 -6.0000e+00 1.7404e-02 2.4026e-05 2.2879e-03 2.3330e-03 6.4679e-05 -6.0000e+00 4.5214e-03 -2.6922e-02 -1.8217e-05 12 8 8 10 0 0 98.20 17.01 1.24 -0.02692 -0.01105 22 5 1 4 0 2202.040 21.17 15.00 17.01 30.55 31.1 991.56 900000 -2351 -1022 440 -4935 -2717 202 -2176 3417 1522 1871 -2528 -6516 698 -1545 4825 8129 359 1620 1471 -879 347 1271 2372 4074 1474 -1309 2555 194 -676 2100 -10560 -1241 870 2219 -4882 3854 1624 -2975 -919 34 2334 -1287 1800 645 2590 -1070 -6187 2590 -2659 -2817 307 -3002 19 2446 502 -1036 -1929 -2985 -32 5137 1305 2283 765 8662 -141 -699 2287 -4286 4308 -1139 9669 3697 260 3041 -1929 3433 -566 -3499 -1327 -484 -960 -2841 -1904 2311 -60 -1714 797 -851 3882 -2190 388 13 -772 2483 -3434 1090 36410 -2551 -5279 4048 -5770 389 -274 -650 2746 -1244 605 -178 2091 3530 -3333 -1271 84 5177 -233 2757 243 -56 -1746 -4135 2076 2941 -4701 -4402 -4183 -2232 2254 968 7819 -3450 -901 -7467 1684 -518 -4043 -3178 -2944 -809 4794 504 1714 -1298 2 2873 17 340 -2700 -46 8036 900000 -2310 -1014 445 -5438 -2999 221 -2450 3650 1645 1986 -2764 -7296 716 -1604 4699 7736 376 1718 1591 -980 383 1391 2569 4356 1608 -1464 2725 208 -708 2103 -11849 -1285 907 2357 -5659 4084 1741 -3298 -989 36 2434 -1393 1913 700 2771 -1184 -7125 2685 -2837 -2923 301 -2993 19 2365 510 -1095 -2085 -3270 -34 5175 1371 2384 803 8421 -147 -718 2265 -4435 4036 -1117 8517 3485 256 2939 -1950 3239 -546 -3421 -1259 -455 -913 -2772 -1858 2169 -58 -1691 764 -825 3583 -2158 377 13 -757 2301 -3267 957 21936 -2198 -4605 3222 -5180 342 -254 -622 2578 -1213 574 -169 1948 3280 -3352 -1260 82 4837 -231 2685 244 -56 -1750 -4161 1941 2698 -4620 -4331 -4120 -2160 2083 904 6783 -3315 -831 -7265 1489 -470 -3866 -3075 -2891 -789 4479 492 1665 -1305 2 2759 17 325 -2615 -42 6910 SQ 20230926T212645.8Z 8669.893585 168 1 50.91 2 79.83 99.18 136.21 283.91 0.00 1 0.00 1 0 15 3.321e-02 3.529e-02 1.812e-02 1.796e-02 1.550311e+04 1.380344e+03 9.640826e+02 -6.000000e+00 1.908515e+03 289.74 -2.00 20.00 -2.00 505.27 0.00e+00 9.988322e-04 5.039951e-04 6.840404e-05 -6.000000e+00 9.516992e-04 289.74 -2.00 20.00 -2.00 500.16 0.00e+00 -2.366174e-01 3.603171e-01 9.812899e-02 -6.000000e+00 6.573300e-01 228.39 -2.00 3.41 -2.00 501.78 0.00e+00 5.425 0.002 489.00 513.00 1 1.0297e+01 2.7673e-02 1.1416e-02 -6.0000e+00 5.0571e-02 4.2075e-02 6.9698e-03 2.3303e-03 -6.0000e+00 1.3016e-02 2.9860e-05 2.4891e-03 1.6469e-03 6.9673e-05 -6.0000e+00 3.4097e-03 -3.9505e-02 2.4532e-04 12 8 8 10 0 0 98.52 17.01 2.60 -0.03950 -0.02224 14 3 1 4 0 3635.510 21.17 15.00 17.01 30.39 31.1 990.30 -3673 -2724 -1594 1323 -1219 759 486 -489 737 663 1254 2879 -1957 -2176 1479 -2644 219 -932 4044 3335 1403 214 358 -602 1952 3472 1742 2504 -2427 -4808 1634 -4477 -1034 -1150 -124 75 1062 4261 2391 111 -2019 1684 1424 235 246 1886 1141 -3113 -1934 -1581 -3387 -567 -706 -430 -2474 -2300 421 -1313 632 1410 -246 1281 802 1385 -1908 5940 -385 -2459 640 -2225 2938 634 2246 3911 2662 -1515 -1725 -3430 938 2377 -2359 -11695 13 -47 1014 4015 351 -497 819 5502 2590 3513 1260 -1788 -960 1662 -1679 -4308 111 -2011 -1952 -3322 -421 1969 2004 2326 -93 2090 1409 -20300 1316 2252 3555 1557 1051 766 802 3567 -3 680 3970 -3356 1190 3807 -694 3159 4092 964 106 3269 -1130 -2560 -1139 1939 2937 2569 1461 -1924 1792 7254 1941 -2090 2790 -751 -1999 4469 1591 1039 2263 -16580 -3633 -2686 -1595 1331 -1297 809 525 -540 805 717 1330 2960 -2078 -2281 1483 -2768 226 -992 4193 3538 1525 233 394 -663 2126 3697 1879 2650 -2635 -5183 1632 -4713 -1069 -1228 -135 82 1150 4417 2494 118 -2180 1763 1510 253 268 2020 1225 -3445 -2077 -1650 -3492 -555 -684 -418 -2517 -2406 439 -1406 665 1469 -261 1343 847 1452 -2032 5819 -395 -2519 633 -2215 2761 612 2153 3729 2585 -1522 -1708 -3392 876 2176 -2267 -12423 13 -46 979 3791 341 -484 790 5068 2450 3324 1224 -1767 -915 1489 -1501 -3835 93 -1695 -1657 -2941 -379 1814 1907 2233 -91 1966 1328 -23936 1264 2161 3379 1513 1029 758 803 3496 -3 671 3714 -3314 1114 3477 -666 2922 3754 903 100 2989 -1057 -2390 -1038 1711 2588 2314 1356 -1878 1710 6636 1889 -2131 2718 -751 -2011 4193 1496 966 2076 -18272 SQ 20230926T213710.0Z 8669.900810 174 1 50.93 2 77.75 100.77 138.13 285.98 0.00 1 0.00 1 0 15 1.424e-02 1.383e-02 7.422e-03 7.359e-03 1.216346e+04 5.549406e+02 7.916254e+02 -6.000000e+00 8.183768e+02 289.74 -2.00 20.00 -2.00 505.27 0.00e+00 2.817163e-03 2.069294e-04 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