File name: Pandora192s1_Tokyo-Sophia_20231214_L2Fit_fwvt1c2d20230711p1-8.txt File generation date: 20240415T124539.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20231214_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20231214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0047 492.1264 492.2480 492.3697 492.4913 492.6129 492.7344 492.8560 492.9776 493.0991 493.2206 493.3421 493.4636 493.5850 493.7065 493.8279 493.9493 494.0707 494.1921 494.3135 494.4348 494.5561 494.6775 494.7987 494.9200 495.0413 495.1625 495.2838 495.4050 495.5262 495.6473 495.7685 495.8897 496.0108 496.1319 496.2530 496.3741 496.4951 496.6162 496.7372 496.8582 496.9792 497.1002 497.2211 497.3421 497.4630 497.5839 497.7048 497.8257 497.9465 498.0674 498.1882 498.3090 498.4298 498.5506 498.6713 498.7921 498.9128 499.0335 499.1542 499.2749 499.3955 499.5162 499.6368 499.7574 499.8780 499.9985 500.1191 500.2396 500.3601 500.4807 500.6011 500.7216 500.8421 500.9625 501.0829 501.2033 501.3237 501.4441 501.5644 501.6847 501.8051 501.9254 502.0456 502.1659 502.2862 502.4064 502.5266 502.6468 502.7670 502.8871 503.0073 503.1274 503.2475 503.3676 503.4877 503.6078 503.7278 503.8478 503.9678 504.0878 504.2078 504.3278 504.4477 504.5676 504.6875 504.8074 504.9273 505.0471 505.1670 505.2868 505.4066 505.5264 505.6462 505.7659 505.8857 506.0054 506.1251 506.2448 506.3644 506.4841 506.6037 506.7233 506.8429 506.9625 507.0821 507.2016 507.3211 507.4407 507.5601 507.6796 507.7991 507.9185 508.0380 508.1574 508.2768 508.3961 508.5155 508.6348 508.7541 508.8735 508.9927 509.1120 509.2313 509.3505 509.4697 509.5889 509.7081 509.8273 509.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231213T220148.3Z 8747.917920 53 1 48.44 2 87.39 121.18 100.98 117.61 0.00 1 0.00 1 0 22 2.568e-02 2.544e-02 2.154e-02 2.143e-02 3.173318e+03 1.353891e+03 2.701982e+02 -6.000000e+00 1.429729e+03 281.54 -2.00 20.00 -2.00 505.30 0.00e+00 3.600550e-03 5.890252e-04 1.661655e-04 -6.000000e+00 7.216205e-04 281.54 -2.00 20.00 -2.00 500.36 0.00e+00 8.056244e-01 4.301860e-01 2.772288e-02 -6.000000e+00 5.099515e-01 223.80 -2.00 3.41 -2.00 501.97 0.00e+00 14.493 0.048 489.00 513.00 1 9.0483e+00 3.2923e-02 2.2319e-02 -6.0000e+00 3.9085e-02 9.9025e-02 8.4871e-03 1.2896e-03 -6.0000e+00 1.0153e-02 2.6159e-05 -2.3561e-03 2.1442e-03 6.9378e-05 -6.0000e+00 2.6455e-03 -1.8655e-02 -2.4394e-07 12 8 8 10 0 0 98.98 17.40 8.35 -0.01865 -0.03500 18 4 1 4 0 2690.500 21.17 15.02 17.40 12.71 30.1 923.97 900000 -2480 -918 -1787 -3322 156 -1515 2985 -2360 -1370 830 1751 1337 -5231 1072 378 -896 -2829 -2341 3465 -2203 -2313 2129 1947 2100 -660 2521 2888 453 -1833 -2837 -1913 -3164 -896 3594 -1421 -736 2349 -1121 -938 -802 1877 -1026 1710 2669 4272 3209 4498 1941 4225 1053 -2286 -3377 -4778 -938 4453 -577 746 -1464 2280 -1531 1571 2315 1244 668 -988 -3329 150 -120 189 -4353 -1645 -320 6468 -676 -475 2343 -5478 -1352 1868 785 2232 -1712 1990 -542 3523 795 2701 -1571 4049 5720 1502 5253 319 -2204 3398 -1665 2950 -599 2882 -517 -3859 1947 -1988 -2995 -3789 3429 -1146 -377 -1279 -1390 -559 1323 707 4158 -900 5357 1611 1022 -4102 -912 -5413 902 4355 -1356 -2372 2193 907 -3828 602 -897 -1462 -1684 -848 -3771 1574 -3727 -2637 -2281 -2070 -979 -56 1393 172 4690 -1610 -932 1788 -1193 4737 900000 -2380 -885 -1797 -3508 163 -1645 3145 -2609 -1490 870 1790 1351 -5553 1056 374 -905 -2963 -2496 3554 -2411 -2537 2236 2052 2220 -714 2640 2992 472 -1897 -2885 -1912 -3234 -920 3643 -1545 -795 2437 -1189 -984 -839 1921 -1093 1796 2811 4459 3382 4639 2004 4171 1043 -2280 -3348 -4804 -924 4285 -600 778 -1567 2350 -1639 1636 2403 1306 701 -1042 -3536 152 -120 186 -4386 -1611 -311 5999 -673 -471 2229 -5538 -1293 1719 731 2059 -1654 1864 -525 3304 767 2554 -1547 3775 5279 1451 4958 318 -2242 3219 -1623 2677 -549 2497 -459 -3584 1750 -1920 -2992 -3840 3207 -1108 -359 -1234 -1350 -548 1293 703 4031 -923 5190 1622 1028 -4284 -908 -5563 866 4048 -1341 -2377 2103 880 -3888 583 -875 -1413 -1607 -794 -3597 1452 -3664 -2611 -2281 -2087 -982 -56 1376 172 4487 -1624 -916 1670 -1129 4214 SQ 20231213T221358.7Z 8747.926374 59 1 50.02 2 85.30 123.04 98.90 119.14 0.00 1 0.00 1 0 15 1.992e-02 1.986e-02 1.113e-02 1.108e-02 3.230565e+03 6.965793e+02 2.399094e+02 -6.000000e+00 1.109051e+03 281.54 -2.00 20.00 -2.00 505.32 0.00e+00 1.985548e-03 3.050714e-04 1.047193e-04 -6.000000e+00 5.596374e-04 281.54 -2.00 20.00 -2.00 500.46 0.00e+00 1.083829e+00 2.199830e-01 2.718659e-02 -6.000000e+00 3.949592e-01 223.80 -2.00 3.41 -2.00 502.06 0.00e+00 10.271 0.017 489.00 513.00 1 8.9954e+00 1.6835e-02 1.5257e-02 -6.0000e+00 3.0281e-02 4.3482e-02 4.3200e-03 9.9657e-04 -6.0000e+00 7.8492e-03 5.0395e-05 -2.7251e-04 1.1123e-03 4.6222e-05 -6.0000e+00 2.0510e-03 -5.0124e-02 3.0853e-04 12 8 8 10 0 0 64.59 17.38 1.04 -0.05012 -0.05201 15 3 1 4 0 3334.080 21.17 14.96 17.38 12.80 29.8 923.44 900000 -1766 -415 625 832 -1550 -2170 1947 1739 2440 -616 -370 -347 -3780 -1027 938 327 1011 -735 859 -2248 -718 1402 -830 1841 -194 25 -2297 -117 -1707 995 1429 -1874 472 -680 1907 1872 1507 770 543 -894 -955 822 422 2240 818 -1037 15 1736 1226 130 -3099 -2557 -1641 -733 541 -2709 205 1328 359 1094 -460 2113 1547 -239 -633 1193 863 -557 184 -51 1149 1378 -1027 -1666 -773 -1289 1432 242 -2034 -256 948 -523 2100 2273 1884 -515 743 -28 -2256 -1020 637 1085 169 1069 759 166 -193 -1169 163 -128 -1351 2238 -296 57 -628 -1712 1235 -1247 1131 -1342 705 -1076 -214 2138 787 727 -1239 1813 -178 107 -565 1119 920 -1945 -1552 1457 -2296 -324 -1066 11106 2910 -1541 -13473 -1780 2352 2327 34 -925 1235 -1861 819 762 753 2326 513 676 -974 -121 -599 900000 -1666 -392 605 830 -1624 -2334 2037 1828 2528 -649 -383 -354 -3892 -1028 921 327 1014 -769 901 -2448 -771 1476 -895 1943 -208 26 -2483 -123 -1757 975 1389 -1909 480 -722 2003 1961 1568 798 558 -932 -1002 856 447 2355 869 -1118 16 1771 1238 129 -3093 -2483 -1599 -718 539 -2856 212 1367 372 1127 -484 2171 1598 -250 -655 1192 853 -551 178 -49 1095 1322 -1011 -1664 -762 -1258 1337 226 -1933 -239 884 -499 1965 2145 1798 -505 718 -27 -2253 -1005 626 1074 169 1050 735 158 -180 -1072 145 -114 -1238 2040 -286 56 -624 -1704 1179 -1213 1082 -1325 693 -1091 -217 2137 802 745 -1295 1821 -180 106 -558 1083 896 -1957 -1560 1422 -2304 -318 -1052 9688 2712 -1469 -14367 -1693 2180 2202 34 -934 1232 -1927 830 777 763 2333 513 662 -948 -116 -574 SQ 20231213T224218.4Z 8747.946047 69 1 49.88 2 80.61 127.58 94.18 122.82 0.00 1 0.00 1 0 15 6.768e-03 6.742e-03 3.759e-03 3.750e-03 2.514615e+03 2.284265e+02 1.869422e+02 -6.000000e+00 3.767371e+02 281.53 -2.00 20.00 -2.00 505.30 0.00e+00 1.728821e-03 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