File name: Pandora192s1_Tokyo-Sophia_20231224_L2Fit_fwvt1c4d20230711p1-8.txt File generation date: 20240911T114309.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20231224_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20231224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0873 492.2090 492.3306 492.4523 492.5739 492.6955 492.8171 492.9386 493.0602 493.1817 493.3032 493.4247 493.5462 493.6677 493.7891 493.9106 494.0320 494.1534 494.2748 494.3961 494.5175 494.6388 494.7601 494.8815 495.0027 495.1240 495.2453 495.3665 495.4877 495.6089 495.7301 495.8513 495.9724 496.0936 496.2147 496.3358 496.4569 496.5780 496.6990 496.8201 496.9411 497.0621 497.1831 497.3041 497.4251 497.5460 497.6669 497.7878 497.9087 498.0296 498.1505 498.2713 498.3921 498.5130 498.6338 498.7545 498.8753 498.9960 499.1168 499.2375 499.3582 499.4789 499.5995 499.7202 499.8408 499.9614 500.0820 500.2026 500.3232 500.4437 500.5643 500.6848 500.8053 500.9258 501.0462 501.1667 501.2871 501.4075 501.5279 501.6483 501.7687 501.8890 502.0094 502.1297 502.2500 502.3703 502.4906 502.6108 502.7310 502.8513 502.9715 503.0917 503.2118 503.3320 503.4521 503.5722 503.6923 503.8124 503.9325 504.0526 504.1726 504.2926 504.4126 504.5326 504.6526 504.7726 504.8925 505.0124 505.1323 505.2522 505.3721 505.4920 505.6118 505.7316 505.8514 505.9712 506.0910 506.2108 506.3305 506.4502 506.5699 506.6896 506.8093 506.9290 507.0486 507.1682 507.2878 507.4074 507.5270 507.6466 507.7661 507.8856 508.0052 508.1246 508.2441 508.3636 508.4830 508.6025 508.7219 508.8413 508.9606 509.0800 509.1993 509.3187 509.4380 509.5573 509.6766 509.7958 509.9151 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231223T230007.7Z 8757.958423 226 1 50.08 2 78.74 129.94 121.84 343.90 0.00 1 0.00 1 0 15 4.732e-03 4.710e-03 1.868e-03 1.865e-03 1.990769e+03 1.126751e+02 1.354915e+02 -6.000000e+00 2.677733e+02 280.93 -2.00 20.00 -2.00 505.31 0.00e+00 1.553596e-03 5.163090e-05 8.472741e-05 -6.000000e+00 1.336202e-04 280.93 -2.00 20.00 -2.00 500.61 0.00e+00 3.377192e-01 3.697775e-02 2.150345e-02 -6.000000e+00 9.479922e-02 223.89 -2.00 3.41 -2.00 502.18 0.00e+00 4.947 0.002 489.00 513.00 1 8.5442e+00 2.8322e-03 7.5623e-03 -6.0000e+00 7.2742e-03 2.2856e-03 7.2639e-04 5.6452e-04 -6.0000e+00 1.8768e-03 1.7993e-04 -1.3594e-04 1.9573e-04 3.5230e-05 -6.0000e+00 5.0812e-04 6.0702e-04 3.7080e-05 12 8 8 10 0 0 -2.72 17.09 1.02 0.00061 -0.00034 13 3 1 4 0 3851.500 20.87 15.00 17.09 10.99 29.5 919.42 -693 -506 -490 -40 -44 449 488 439 927 459 130 -402 -177 -369 -930 -182 -444 -170 312 -128 306 532 811 632 606 830 345 249 -897 -787 -952 -961 432 304 55 239 184 -10 44 -475 -19 -181 527 622 148 193 1027 10 28 -633 -784 -1049 -1218 -554 -75 -482 115 62 133 349 402 288 535 514 -153 114 212 -3 -157 -333 -345 -104 377 354 -323 -326 -247 205 -951 -637 -295 -424 -174 -45 139 -165 -316 -210 174 -244 414 490 256 511 510 -213 -336 -192 -492 -730 -909 222 40 189 -717 -641 -405 -245 -220 45 43 -224 399 406 558 824 833 446 268 -190 271 514 1081 -103 61 278 294 406 543 -201 -120 -391 -791 -804 274 -205 -503 -208 3 306 53 241 10 719 -4 -321 -357 -292 -181 -639 -476 -476 -40 -45 458 505 456 954 468 131 -401 -174 -360 -909 -178 -444 -174 324 -135 320 557 848 651 628 855 354 256 -909 -777 -934 -955 435 310 58 249 190 -10 45 -482 -20 -185 542 647 155 202 1058 10 28 -633 -766 -1011 -1178 -544 -74 -489 118 64 137 358 414 297 552 527 -157 114 209 -3 -152 -320 -331 -101 367 347 -318 -317 -237 194 -904 -605 -281 -408 -169 -44 136 -163 -314 -209 173 -245 410 491 258 511 502 -207 -326 -182 -460 -680 -859 213 39 188 -723 -640 -399 -240 -216 44 43 -230 411 422 571 844 853 455 275 -193 271 512 1073 -103 61 279 296 407 542 -201 -118 -379 -765 -779 267 -204 -500 -209 3 311 54 247 11 736 -4 -323 -352 -283 -175 SQ 20231223T230437.2Z 8757.961542 229 1 48.99 2 78.05 130.72 122.06 345.04 0.00 1 0.00 1 0 15 4.996e-03 4.990e-03 1.660e-03 1.657e-03 1.777172e+03 9.934130e+01 1.087843e+02 -6.000000e+00 2.826906e+02 280.92 -2.00 20.00 -2.00 505.29 0.00e+00 1.615894e-03 4.584534e-05 8.714881e-05 -6.000000e+00 1.410668e-04 280.92 -2.00 20.00 -2.00 500.58 0.00e+00 4.069949e-01 3.285796e-02 2.238741e-02 -6.000000e+00 1.001065e-01 223.89 -2.00 3.41 -2.00 502.15 0.00e+00 4.681 0.002 489.00 513.00 1 8.4086e+00 2.5181e-03 7.2356e-03 -6.0000e+00 7.6811e-03 1.8015e-03 6.4501e-04 5.4503e-04 -6.0000e+00 1.9825e-03 2.1278e-04 7.5982e-04 1.7437e-04 3.4689e-05 -6.0000e+00 5.3650e-04 -8.5575e-04 2.4931e-05 12 8 8 10 0 0 59.52 17.10 0.82 -0.00086 0.00441 13 3 1 4 0 3767.710 20.87 15.01 17.10 11.25 29.5 920.45 -803 -668 -336 -522 47 273 1006 417 291 -97 314 -366 -523 -399 -998 -703 -118 100 686 249 471 375 532 722 676 829 475 268 -944 -887 -897 -926 637 712 172 -57 -309 153 -70 -219 47 -42 -756 448 460 446 1132 254 -389 702 -975 -908 -959 204 109 -389 127 245 98 624 764 377 462 402 8 193 62 -60 -342 -396 -97 -592 341 287 -576 -613 -695 116 -397 -394 -569 -607 -120 -271 -593 -522 25 -579 -736 -216 234 314 444 713 383 169 -543 -542 -87 -564 -691 -168 -73 -78 -107 -384 788 -218 -6 -7 -261 194 477 587 533 530 888 919 384 199 198 278 704 -34 9 434 183 263 381 -325 -427 -315 -589 -386 281 -245 -203 -475 254 247 235 501 -224 327 200 -316 -601 -855 -434 -746 -633 -328 -516 47 280 1041 436 303 -100 318 -368 -518 -390 -982 -696 -118 103 699 257 485 388 550 748 703 859 489 272 -961 -880 -883 -925 645 728 180 -60 -322 157 -71 -222 47 -43 -793 469 484 468 1169 260 -392 682 -959 -878 -930 199 108 -396 131 253 101 641 786 391 470 415 9 194 62 -59 -333 -383 -94 -577 334 283 -571 -599 -670 110 -376 -375 -544 -586 -117 -265 -588 -509 25 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113 25 1 4 0 435.360 20.87 15.01 17.11 11.39 29.5 921.54 -858 -518 -201 -174 84 680 706 745 490 226 187 -208 -483 -510 -515 -716 -242 210 234 23 262 301 425 613 690 483 525 132 -555 -583 -628 -718 -83 472 -85 5 137 -45 -65 -108 -52 76 324 534 526 543 373 284 -167 -440 -683 -940 -772 -380 -84 -180 -137 -65 -10 307 222 392 381 331 202 163 10 -134 -349 -438 -229 -266 124 332 -178 -418 -323 -247 -412 -399 -314 -601 -231 -67 -287 -293 -136 -145 -115 20 396 601 398 352 407 51 -235 -366 -564 -826 -742 -248 157 -101 -343 -377 -414 -319 11 -66 -35 103 362 384 569 738 727 474 481 185 116 301 445 197 274 464 123 255 436 -89 -143 -210 -571 -503 68 -182 -291 -56 56 1 174 318 174 242 36 -168 -396 -390 -398 -808 -497 -199 -178 88 688 724 768 503 230 187 -215 -494 -517 -520 -730 -251 212 241 24 272 312 442 639 720 504 542 135 -553 -593 -635 -703 -83 484 -89 6 143 -46 -66 -110 -53 78 336 558 553 570 388 290 -168 -432 -655 -930 -764 -365 -83 -182 -141 -67 -11 315 229 405 394 340 206 163 10 -131 -338 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