File name: Pandora192s1_Tokyo-Sophia_20240428_L2Fit_fout2c4d20230711p1-8.txt File generation date: 20240911T121147.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240428_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0295 305.1706 305.3117 305.4528 305.5938 305.7349 305.8759 306.0169 306.1580 306.2990 306.4400 306.5810 306.7219 306.8629 307.0038 307.1448 307.2857 307.4266 307.5676 307.7085 307.8493 307.9902 308.1311 308.2720 308.4128 308.5536 308.6945 308.8353 308.9761 309.1169 309.2577 309.3984 309.5392 309.6800 309.8207 309.9614 310.1022 310.2429 310.3836 310.5243 310.6650 310.8056 310.9463 311.0869 311.2276 311.3682 311.5088 311.6494 311.7900 311.9306 312.0712 312.2117 312.3523 312.4928 312.6334 312.7739 312.9144 313.0549 313.1954 313.3359 313.4763 313.6168 313.7572 313.8977 314.0381 314.1785 314.3189 314.4593 314.5997 314.7401 314.8804 315.0208 315.1611 315.3014 315.4418 315.5821 315.7224 315.8627 316.0029 316.1432 316.2834 316.4237 316.5639 316.7041 316.8444 316.9846 317.1247 317.2649 317.4051 317.5453 317.6854 317.8255 317.9657 318.1058 318.2459 318.3860 318.5260 318.6661 318.8062 318.9462 319.0863 319.2263 319.3663 319.5063 319.6463 319.7863 319.9263 320.0662 320.2062 320.3461 320.4860 320.6260 320.7659 320.9058 321.0456 321.1855 321.3254 321.4652 321.6051 321.7449 321.8847 322.0245 322.1643 322.3041 322.4439 322.5837 322.7234 322.8632 323.0029 323.1426 323.2823 323.4220 323.5617 323.7014 323.8411 323.9807 324.1204 324.2600 324.3996 324.5392 324.6788 324.8184 324.9580 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240427T205323.0Z 8883.870406 225 1 49.08 2 78.83 80.44 78.71 221.49 0.00 1 0.00 1 0 25 5.301e-01 1.840e-02 2.771e-01 5.288e-03 6.984028e-01 3.157488e-03 7.916176e-03 -6.000000e+00 3.361484e-01 230.12 -2.00 3.41 -2.00 321.65 0.00e+00 7.607547e-03 1.790594e-03 3.909612e-03 -6.000000e+00 1.576989e-02 284.97 -2.00 20.00 -2.00 321.10 0.00e+00 4.980 0.002 302.00 328.00 3 2.6256e+00 1.1936e-02 6.3760e-02 -6.0000e+00 8.3761e-01 2.7384e-01 1.6248e-02 4.1694e-02 -6.0000e+00 9.0610e-01 -4.4001e-01 1.4910e-02 2.2908e-02 -6.0000e+00 5.4015e-01 1.8546e-01 6.8143e-03 7.8508e-03 -6.0000e+00 2.2228e-01 1.2395e-04 -1.1863e-03 1.7841e-04 1.7897e-04 -6.0000e+00 1.8488e-02 -1.0606e-02 0.0000e+00 12 8 8 10 0 0 47.76 18.64 0.44 -0.01061 -0.01952 96 21 1 5 0 511.070 22.50 15.01 18.64 25.56 7.6 1053.27 -145815 -216505 -179841 900000 900000 -65408 -36157 -54290 -249182 -139112 -42443 -114536 900000 121577 -67549 -48601 900000 181601 86324 34353 -139703 -46885 118810 900000 -28145 -23188 -16269 -18059 -40909 97484 32362 48423 88593 137314 43911 62965 -22267 57584 32226 11519 23921 16252 25090 9013 23997 38813 24024 21899 17090 28496 26766 23309 23838 15976 11265 11001 14240 10227 14154 8938 7969 9705 374 6533 7155 11690 8600 5205 2558 2690 7125 3942 5781 2286 -2381 8120 1769 -1232 356 -1992 -530 -9 -1523 -5517 -911 -354 321 2286 -1983 850 42 -883 -2820 -1404 -2822 -2736 -2349 52 589 -1221 -813 -1859 -2690 52 -2615 -2171 -2095 -1646 -1129 412 1151 260 229 1545 96 337 -2462 -463 610 893 629 1285 824 926 695 84 1451 -170 419 2039 844 298 -56 -31 -352 103 -67 -76 -288 -218 -349 48 -850 -1522 -5292 -3390 900000 900000 -364 -186 -295 -9663 -1957 -249 -1557 900000 626 -1131 -814 900000 936 534 374 -8385 -1147 612 900000 -642 -519 -342 -385 -1114 739 544 822 1155 1222 978 1164 -996 1361 1157 594 1225 975 1456 637 1495 2135 1576 1523 1313 2094 2194 2190 2446 1915 1499 1524 1947 1452 1903 1258 1169 1518 72 1308 1519 2416 1843 1194 654 766 2125 1272 1828 715 -721 2087 457 -332 104 -670 -205 -4 -752 -3056 -514 -211 199 1432 -1297 525 25 -515 -1631 -826 -1860 -2010 -1987 48 595 -1281 -814 -1741 -2439 45 -2424 -2122 -2113 -1783 -1338 535 1630 395 354 2313 140 479 -3603 -687 937 1411 995 1967 1221 1363 988 117 1963 -244 659 3429 1580 605 -121 -72 -860 255 -171 -196 -738 -554 -844 110 -1915 SS 20240427T205904.1Z 8883.874353 228 1 49.32 2 77.69 81.23 79.46 222.46 0.00 1 0.00 1 0 25 4.346e-01 8.312e-03 2.230e-01 3.262e-03 6.473663e-01 1.907106e-03 7.124383e-03 -6.000000e+00 2.760942e-01 230.12 -2.00 3.41 -2.00 321.38 0.00e+00 2.646952e-03 1.012568e-03 2.800111e-03 -6.000000e+00 1.246366e-02 284.97 -2.00 20.00 -2.00 320.80 0.00e+00 4.553 0.001 302.00 328.00 3 2.4305e+00 6.8898e-03 5.7984e-02 -6.0000e+00 6.8725e-01 2.5428e-02 9.4808e-03 3.7847e-02 -6.0000e+00 7.4276e-01 -4.0408e-02 9.1969e-03 1.9756e-02 -6.0000e+00 4.4135e-01 -7.3015e-04 4.2659e-03 5.8342e-03 -6.0000e+00 1.8106e-01 2.4816e-04 -8.1655e-04 1.1117e-04 1.1575e-04 -6.0000e+00 1.5045e-02 -1.0780e-02 0.0000e+00 11 8 0 10 0 0 52.92 18.65 0.22 -0.01078 -0.01692 141 31 1 5 0 349.710 22.50 15.01 18.65 25.94 7.6 1054.78 -189859 -213159 -162268 -172335 900000 -154212 900000 73362 -61033 -33860 -67547 -13279 -154259 -56762 -64826 -38002 -17908 97951 36685 -54867 -67879 1836 -64456 -7501 -27416 -42198 90268 -23327 -75919 -24038 -23921 -2516 -2081 -29298 -2421 4097 -2905 -2188 6510 341 -6266 -2741 -1097 473 8485 -688 33862 -9520 -7559 9978 7324 12262 5172 2194 775 1524 4138 3500 6392 707 -583 2752 2560 5239 4459 1738 3030 2108 -820 1921 1030 1214 1090 -841 651 -357 -2619 -1014 -1006 -579 -1345 -1928 -2604 -360 -530 124 1313 278 -1 1335 1672 1046 -420 -1221 -1499 -923 289 502 838 -159 -1130 -1330 -2278 -384 -997 -1033 -1223 -936 420 520 675 571 394 110 -460 -292 -107 304 831 231 32 316 91 311 536 -133 -163 831 -3 -2 -55 27 -356 -290 -189 30 208 165 17 274 39 -366 -306 -1403 -2392 -1251 -1511 900000 -1100 900000 233 -237 -111 -342 -46 -2542 -463 -722 -393 -176 352 267 -1036 -1531 22 -1524 -108 -523 -994 622 -473 -2648 -552 -611 -63 -60 -1170 -78 127 -105 -89 292 19 -435 -202 -85 37 636 -58 2147 -937 -768 945 784 1392 675 322 123 253 713 612 1077 126 -109 537 558 1230 1122 456 788 572 -249 636 378 469 423 -319 226 -115 -813 -312 -338 -223 -606 -995 -1495 -218 -344 82 905 199 -1 949 1125 669 -264 -794 -1070 -747 257 501 900 -175 -1202 -1357 -2196 -360 -978 -1073 -1351 -1072 519 708 1003 895 627 171 -691 -424 -154 454 1288 372 51 497 139 455 778 -188 -228 1195 -5 -3 -102 54 -760 -637 -439 74 521 420 44 671 91 -844 -693 SS 20240427T210426.4Z 8883.878083 231 1 49.15 2 76.61 81.98 80.18 223.36 0.00 1 0.00 1 0 25 3.484e-01 7.432e-03 1.115e-01 2.356e-03 5.989599e-01 1.351371e-03 6.845400e-03 -6.000000e+00 2.195789e-01 230.12 -2.00 3.41 -2.00 321.15 0.00e+00 2.532081e-03 6.659332e-04 3.750475e-03 -6.000000e+00 9.761792e-03 284.97 -2.00 20.00 -2.00 320.54 0.00e+00 4.211 0.001 302.00 328.00 3 2.3040e+00 4.6740e-03 5.5153e-02 -6.0000e+00 5.4706e-01 -3.2664e-03 6.2220e-03 3.8871e-02 -6.0000e+00 5.9106e-01 -3.3454e-02 5.8302e-03 1.8802e-02 -6.0000e+00 3.5238e-01 4.9562e-03 2.7546e-03 4.8234e-03 -6.0000e+00 1.4502e-01 4.1414e-04 -6.3772e-04 8.0881e-05 1.1071e-04 -6.0000e+00 1.1913e-02 -1.1004e-02 0.0000e+00 11 8 0 10 0 0 45.68 18.66 0.23 -0.01100 -0.01580 193 42 1 5 0 254.630 22.50 15.01 18.66 26.33 7.5 1056.56 -131542 -106364 -72197 -112547 -63325 -126273 -65517 -172439 -102821 -82445 -49561 -120620 -62737 -122483 -46324 -51724 -11604 -24732 -46037 -3811 672 -23852 -18782 -28792 -3419 -6424 -8348 -9330 -13369 -15938 -10671 -10881 -6594 -1264 -22322 -379 -4074 -1689 -2644 -4221 -4067 1300 2169 4521 5232 6548 246 7266 184 2448 2117 2002 4196 3210 4144 -1758 2216 777 -1673 1547 1653 2192 3058 1815 4102 634 1735 1087 3235 1948 1504 373 776 1925 362 -521 -2195 -2492 -2244 -1277 -1221 -1626 -693 -716 -547 -591 -184 283 1124 1564 679 187 -1428 -1288 890 402 -297 669 -29 -317 -743 -1572 -1964 -1245 -1073 -1108 -1053 -640 -177 810 694 1023 416 166 -290 -581 435 384 150 611 368 339 147 116 328 343 -247 106 156 154 -14 -422 -24 -307 -360 -74 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