File name: Pandora192s1_Tokyo-Sophia_20240530_L2Fit_fwvt1c2d20230711p1-8.txt File generation date: 20240530T145143.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240530_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0047 492.1264 492.2480 492.3697 492.4913 492.6129 492.7344 492.8560 492.9776 493.0991 493.2206 493.3421 493.4636 493.5850 493.7065 493.8279 493.9493 494.0707 494.1921 494.3135 494.4348 494.5561 494.6775 494.7987 494.9200 495.0413 495.1625 495.2838 495.4050 495.5262 495.6473 495.7685 495.8897 496.0108 496.1319 496.2530 496.3741 496.4951 496.6162 496.7372 496.8582 496.9792 497.1002 497.2211 497.3421 497.4630 497.5839 497.7048 497.8257 497.9465 498.0674 498.1882 498.3090 498.4298 498.5506 498.6713 498.7921 498.9128 499.0335 499.1542 499.2749 499.3955 499.5162 499.6368 499.7574 499.8780 499.9985 500.1191 500.2396 500.3601 500.4807 500.6011 500.7216 500.8421 500.9625 501.0829 501.2033 501.3237 501.4441 501.5644 501.6847 501.8051 501.9254 502.0456 502.1659 502.2862 502.4064 502.5266 502.6468 502.7670 502.8871 503.0073 503.1274 503.2475 503.3676 503.4877 503.6078 503.7278 503.8478 503.9678 504.0878 504.2078 504.3278 504.4477 504.5676 504.6875 504.8074 504.9273 505.0471 505.1670 505.2868 505.4066 505.5264 505.6462 505.7659 505.8857 506.0054 506.1251 506.2448 506.3644 506.4841 506.6037 506.7233 506.8429 506.9625 507.0821 507.2016 507.3211 507.4407 507.5601 507.6796 507.7991 507.9185 508.0380 508.1574 508.2768 508.3961 508.5155 508.6348 508.7541 508.8735 508.9927 509.1120 509.2313 509.3505 509.4697 509.5889 509.7081 509.8273 509.9464 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240529T193530.0Z 8915.816320 168 1 49.50 2 89.35 63.33 53.18 168.80 0.00 1 0.00 1 0 63 4.068e-01 2.875e-01 2.227e-01 1.689e-01 -1.132580e+04 9.582270e+03 9.909885e+02 -6.000000e+00 2.324366e+04 288.01 -2.00 20.00 -2.00 505.22 0.00e+00 8.198472e-03 4.880643e-03 2.545427e-04 -6.000000e+00 1.165075e-02 288.01 -2.00 20.00 -2.00 500.09 0.00e+00 -7.869769e+00 3.532090e+00 4.411163e-01 -6.000000e+00 8.099964e+00 232.03 -2.00 3.41 -2.00 501.75 0.00e+00 19.311 0.115 489.00 513.00 1 1.0856e+01 2.7239e-01 4.6178e-02 -6.0000e+00 6.2203e-01 3.8136e-01 7.2061e-02 6.5747e-03 -6.0000e+00 1.6023e-01 3.5480e-06 -6.2401e-02 1.5184e-02 1.4486e-04 -6.0000e+00 4.1934e-02 1.8438e-03 8.2412e-05 12 8 8 10 0 0 99.74 17.41 13.81 0.00184 -0.43099 25 5 1 4 0 1979.690 21.38 15.00 17.41 27.00 9.7 1043.37 28957 38413 6133 22361 -9212 -28425 11617 -21242 -14312 30170 -46510 35910 -8455 20548 35437 1486 48558 12747 -1641 -16884 6909 -7013 20175 7254 28130 4385 -10170 655 -12167 1048 45007 10684 24985 1254 -2705 -22931 24941 6334 900000 78500 -21256 -25929 -7453 21356 21603 -11428 23482 -18853 1676 18732 40604 24787 9920 7979 2685 -8649 23356 12402 26873 -15807 32225 13444 982 16189 -1645 -6997 -28906 61492 41643 402 6437 24150 11696 1504 26328 29697 8084 20056 -9241 7405 31039 20692 -7060 21371 -4653 -13010 60387 -13443 -11237 7141 27331 -1512 -1410 27209 29785 72663 122426 266232 41730 -43402 22847 47618 35116 23432 31111 23206 12928 25908 70096 7349 39664 35388 15371 20757 -681 28931 10117 69602 26732 -16676 -78043 193685 -7331 28936 38784 16521 3463 19139 37376 42789 28326 41246 29600 -11292 17528 46225 13279 650 14820 -19286 -3189 -17358 10279 32035 -17941 16333 -18250 59354 64963 -29049 26741 31215 6493 19395 -10746 -40390 11597 -29883 -19223 26864 -87827 30528 -10890 19574 28699 1640 33329 12089 -1781 -21175 6956 -8181 18356 7477 23668 4625 -12395 719 -15242 1150 32112 10363 20523 1254 -2773 -28674 20096 6287 900000 39754 -27921 -34963 -8349 18057 18357 -13586 20186 -24714 1823 17227 30082 21238 9596 7674 2653 -9421 18625 11144 21733 -19842 25971 13080 1075 15387 -1863 -8423 -43115 38321 31088 440 6541 20483 11007 1551 21333 23439 7945 17676 -10854 7360 24237 17603 -7845 18092 -5113 -15528 35945 -16284 -13396 7166 22644 -1649 -1548 22881 24841 41154 44379 44041 33538 -80027 21833 35216 28367 20834 25432 20602 12726 22421 39405 7364 28378 26099 13786 17963 -744 24364 10453 41314 24084 -22696 -190140 34043 -8638 23538 28550 14897 3568 16895 27644 30083 22694 28871 23147 -12924 14854 29121 11145 608 11957 -21892 -3118 -19679 8906 22380 -20009 13088 -20305 31256 31881 -34374 SQ 20240529T193942.6Z 8915.819243 172 1 48.85 2 88.59 63.94 53.01 170.02 0.00 1 0.00 1 0 15 2.725e-01 1.253e-01 1.302e-01 9.588e-02 -4.041013e+03 5.788907e+03 2.088933e+02 -6.000000e+00 1.556855e+04 288.01 -2.00 20.00 -2.00 505.22 0.00e+00 4.154049e-03 2.766900e-03 2.064226e-04 -6.000000e+00 7.796493e-03 288.01 -2.00 20.00 -2.00 499.99 0.00e+00 4.024041e+00 1.992460e+00 5.370732e-02 -6.000000e+00 5.491398e+00 232.03 -2.00 3.41 -2.00 501.65 0.00e+00 17.525 0.086 489.00 513.00 1 9.9438e+00 1.5447e-01 2.8606e-02 -6.0000e+00 4.2071e-01 9.6120e-02 3.9577e-02 1.8009e-03 -6.0000e+00 1.1057e-01 5.3410e-06 4.1222e-03 9.4905e-03 6.4345e-05 -6.0000e+00 2.8036e-02 -4.4203e-02 -5.7521e-04 12 8 8 10 0 0 99.57 17.41 11.61 -0.04420 -0.01561 13 3 1 4 0 3757.140 21.38 15.00 17.41 27.11 9.7 1043.63 900000 10489 -7869 6133 -10681 5378 17263 2627 12658 14549 -5391 -13477 -4436 12420 12889 5138 7072 -2306 -10953 -14452 -4015 16910 52392 1498 527 -11237 -376 13606 42479 -7229 15782 16486 13479 -7606 -5720 3971 7328 -19338 -18393 -13664 71 10139 12861 516 -3375 -2720 1704 830 -10083 -11441 -2294 5901 5000 -9997 276237 25335 -2994 70 6790 -5935 15280 31036 -639 326 -4587 -3340 26530 -8839 3773 -2292 -967 -17128 11747 15368 23869 2428 -12154 14063 -19789 -8247 -3606 12462 8064 -9529 -7808 9087 -2378 15566 -520 -6448 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-12252 16167 -13188 10580 -13121 2200 -12167 3454 22910 -10546 -5687 -13390 1457 -16206 11942 3969 13835 2901 238 -3415 5811 6646 10715 -14054 -1831 -6326 4208 -12905 928 21959 -1652 -1933 7798 -14729 16298 -1218 3063 18773 SQ 20240529T194436.2Z 8915.822641 180 1 50.14 2 87.69 64.64 52.83 171.44 0.00 1 0.00 1 0 28 1.332e-01 9.508e-02 7.418e-02 7.057e-02 6.707511e+03 4.963469e+03 2.920677e+01 -6.000000e+00 7.609502e+03 288.01 -2.00 20.00 -2.00 505.14 0.00e+00 2.283891e-03 1.979924e-03 1.629171e-04 -6.000000e+00 3.798715e-03 288.01 -2.00 20.00 -2.00 499.85 0.00e+00 -1.756160e-01 1.467526e+00 1.166710e-01 -6.000000e+00 2.652669e+00 232.03 -2.00 3.41 -2.00 501.50 0.00e+00 15.179 0.056 489.00 513.00 1 1.0257e+01 1.1293e-01 2.5000e-02 -6.0000e+00 2.0382e-01 1.7119e-01 2.8853e-02 2.2009e-03 -6.0000e+00 5.2586e-02 7.6088e-06 -1.5013e-02 6.8637e-03 7.2867e-05 -6.0000e+00 1.3680e-02 3.1955e-02 -2.3733e-04 12 8 8 10 0 0 99.50 17.41 14.30 0.03195 -0.07218 17 4 1 4 0 2948.760 21.38 15.00 17.41 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