File name: Pandora192s1_Tokyo-Sophia_20240609_L2Fit_fwvt1c4d20230711p1-8.txt File generation date: 20240911T123127.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240609_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0873 492.2090 492.3306 492.4523 492.5739 492.6955 492.8171 492.9386 493.0602 493.1817 493.3032 493.4247 493.5462 493.6677 493.7891 493.9106 494.0320 494.1534 494.2748 494.3961 494.5175 494.6388 494.7601 494.8815 495.0027 495.1240 495.2453 495.3665 495.4877 495.6089 495.7301 495.8513 495.9724 496.0936 496.2147 496.3358 496.4569 496.5780 496.6990 496.8201 496.9411 497.0621 497.1831 497.3041 497.4251 497.5460 497.6669 497.7878 497.9087 498.0296 498.1505 498.2713 498.3921 498.5130 498.6338 498.7545 498.8753 498.9960 499.1168 499.2375 499.3582 499.4789 499.5995 499.7202 499.8408 499.9614 500.0820 500.2026 500.3232 500.4437 500.5643 500.6848 500.8053 500.9258 501.0462 501.1667 501.2871 501.4075 501.5279 501.6483 501.7687 501.8890 502.0094 502.1297 502.2500 502.3703 502.4906 502.6108 502.7310 502.8513 502.9715 503.0917 503.2118 503.3320 503.4521 503.5722 503.6923 503.8124 503.9325 504.0526 504.1726 504.2926 504.4126 504.5326 504.6526 504.7726 504.8925 505.0124 505.1323 505.2522 505.3721 505.4920 505.6118 505.7316 505.8514 505.9712 506.0910 506.2108 506.3305 506.4502 506.5699 506.6896 506.8093 506.9290 507.0486 507.1682 507.2878 507.4074 507.5270 507.6466 507.7661 507.8856 508.0052 508.1246 508.2441 508.3636 508.4830 508.6025 508.7219 508.8413 508.9606 509.0800 509.1993 509.3187 509.4380 509.5573 509.6766 509.7958 509.9151 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240608T194400.5Z 8925.822228 54 1 48.03 2 87.40 63.40 105.46 39.61 0.00 1 0.00 1 0 22 6.233e-02 6.401e-02 4.893e-02 4.834e-02 1.717056e+04 3.813479e+03 9.571364e+02 -6.000000e+00 3.641935e+03 288.94 -2.00 20.00 -2.00 505.33 0.00e+00 1.028355e-03 1.359886e-03 9.341938e-05 -6.000000e+00 1.794847e-03 288.94 -2.00 20.00 -2.00 500.43 0.00e+00 -6.478944e-01 9.773807e-01 1.362496e-01 -6.000000e+00 1.258659e+00 232.50 -2.00 3.41 -2.00 502.02 0.00e+00 14.441 0.048 489.00 513.00 1 1.0620e+01 7.4913e-02 2.4503e-02 -6.0000e+00 9.6753e-02 8.5776e-02 1.8827e-02 3.1578e-03 -6.0000e+00 2.5003e-02 6.1401e-06 4.3410e-03 4.6053e-03 4.6594e-05 -6.0000e+00 6.7040e-03 -9.1743e-02 4.6844e-04 12 8 8 10 0 0 99.30 17.45 5.55 -0.09174 -0.06163 17 4 1 4 0 2824.610 21.48 15.00 17.45 27.64 10.4 1041.79 -629 -9040 -9699 909 627 1787 4489 4364 789 -1603 -8985 -8448 -1125 -3438 6118 -4818 7333 16492 -1056 279 11794 1030 -1854 -275 -5739 -5357 2857 526 3187 1685 -7247 2204 -4757 4798 5137 -3526 884 44 2783 -4867 6759 1027 8590 8188 -568 -948 10962 3769 -1877 9472 3675 -266 -2798 -7117 -4250 -5282 -1827 59 -3604 1119 -3404 -19 7298 5385 5554 -10803 -7188 -5999 9806 8714 7068 -1849 878 5863 -4460 5418 -955 1168 4289 -64 -4555 5312 -3783 -3465 2969 3995 -2552 7198 2753 765 1140 -3776 57 -2260 2888 -1789 -2845 6749 -7536 -4510 2614 13905 -6533 10608 -7677 -2129 4174 -4922 11338 1523 -7272 -6234 -862 8155 1830 7167 5521 -9053 2524 -2599 7797 169 8814 -10814 8644 -4170 -4710 11421 -3128 10201 -2448 2325 9179 -4129 2380 2957 10816 -1376 2544 8055 -45 -27003 -5044 1143 -5705 4376 2319 11259 5954 -576 -9200 -10269 893 634 1824 4526 4428 825 -1695 -10080 -9291 -1135 -3514 5672 -5030 6915 14545 -1132 298 11233 1093 -2031 -298 -6584 -6105 2974 550 3159 1655 -7726 2166 -5161 4878 5293 -3878 922 46 2790 -5256 6527 1061 8322 8051 -613 -1025 10417 3787 -1951 8562 3432 -254 -2751 -7460 -4458 -5743 -1947 62 -3926 1164 -3719 -20 7198 5383 5477 -12357 -7814 -6367 8793 7841 6462 -1863 873 5589 -4697 5093 -940 1111 3930 -61 -4577 4878 -3852 -3484 2824 3772 -2567 6677 2608 742 1112 -3889 56 -2216 2592 -1623 -2531 5345 -6804 -3958 2186 10844 -6570 9342 -8269 -2171 3970 -5108 10042 1502 -7907 -6740 -885 7659 1844 6926 5474 -10380 2546 -2703 7165 166 7931 -11888 7848 -4303 -4879 10047 -3168 8953 -2405 2151 7908 -4017 2252 2772 9732 -1390 2505 7590 -47 -36500 -5469 1159 -6136 4193 2231 9798 5470 SQ 20240608T195811.7Z 8925.832080 60 1 49.99 2 84.81 65.39 103.67 42.12 0.00 1 0.00 1 0 28 6.541e-02 6.650e-02 4.362e-02 4.303e-02 -2.018175e+03 2.595313e+03 1.816023e+02 -6.000000e+00 3.821616e+03 288.94 -2.00 20.00 -2.00 505.23 0.00e+00 -3.902784e-04 1.206939e-03 3.961441e-06 -6.000000e+00 1.883412e-03 288.94 -2.00 20.00 -2.00 500.21 0.00e+00 1.292758e+00 8.774613e-01 1.489449e-02 -6.000000e+00 1.320968e+00 232.50 -2.00 3.41 -2.00 501.84 0.00e+00 9.527 0.014 489.00 513.00 1 1.1068e+01 6.7352e-02 1.3788e-02 -6.0000e+00 1.0154e-01 6.6086e-02 1.7664e-02 8.2032e-04 -6.0000e+00 2.6250e-02 7.2162e-06 -1.0839e-02 4.5424e-03 2.7565e-05 -6.0000e+00 7.0345e-03 -2.3008e-02 3.6111e-05 12 8 8 10 0 0 99.43 17.45 -0.36 -0.02301 -0.09819 19 4 1 4 0 2629.540 21.48 15.00 17.45 28.24 10.2 1042.96 6190 -5889 3747 1146 -4258 4406 1486 13194 803 7958 -7236 8572 -156 -3265 1038 -115 10532 -2682 1764 4414 -678 5065 -470 9631 -1319 11159 -3113 -742 8173 -1970 -10569 -2361 -6083 9580 -11327 -10758 -1078 1134 -2994 -680 -3690 -7187 7244 -6686 10292 -1110 -7504 6005 -2715 8019 4670 5579 -3106 245 2487 -5797 4142 -544 -2487 5808 -6268 839 -3244 7342 544 -1468 693 -4889 57 -3251 7982 -1796 7562 -2786 -7614 -3911 -5261 2818 -1404 -6266 3170 -2197 8707 5 2522 -4933 12325 -4466 -3488 -5047 -3108 -3511 9696 9078 7384 9415 -28879 5609 20824 14405 4569 993 2606 -387 -11170 -2521 5863 -686 2676 2486 -1730 -3913 8337 3308 -328 2983 -2612 1546 78 -4796 715 -1033 13890 -4544 2799 -2241 -1780 6063 -3182 -2219 8924 3881 -1401 -5892 3105 -13016 11734 -5370 6758 -357 -8833 4657 344 8697 7184 4915 516 -1167 6557 5516 -5946 3519 1141 -4612 4483 1588 12701 877 8043 -8399 8369 -164 -3488 1053 -118 9829 -2919 1882 4664 -759 5362 -526 9762 -1496 11180 -3580 -825 8132 -2109 -12049 -2470 -6556 9307 -13629 -13037 -1182 1204 -3270 -718 -4005 -8104 7127 -7635 9998 -1211 -8684 5994 -2903 7513 4398 5072 -3035 232 2356 -6136 4060 -565 -2637 5659 -6887 861 -3475 7062 556 -1509 686 -5039 55 -3217 7004 -1738 6723 -2781 -8030 -3953 -5307 2581 -1328 -6213 2870 -2113 7574 5 2377 -4935 10662 -4480 -3473 -5129 -3127 -3591 8791 8325 6861 8466 -37412 5039 15722 11402 3976 909 2412 -378 -12336 -2546 5371 -662 2481 2322 -1708 -4014 7677 3238 -335 2959 -2740 1548 79 -4986 694 -1012 11710 -4618 2650 -2234 -1762 5537 -3180 -2189 7808 3519 -1318 -5745 2778 -13574 9947 -5378 6210 -348 -9405 4352 337 7866 6576 4549 489 -1101 5648 SQ 20240608T201003.6Z 8925.840319 63 1 49.32 2 82.60 67.01 102.10 44.16 0.00 1 0.00 1 0 22 4.117e-02 4.255e-02 2.267e-02 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