File name: Pandora192s1_Tokyo-Sophia_20240707_L2Fit_fout2c4d20230711p1-8.txt File generation date: 20240911T154511.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240707_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0295 305.1706 305.3117 305.4528 305.5938 305.7349 305.8759 306.0169 306.1580 306.2990 306.4400 306.5810 306.7219 306.8629 307.0038 307.1448 307.2857 307.4266 307.5676 307.7085 307.8493 307.9902 308.1311 308.2720 308.4128 308.5536 308.6945 308.8353 308.9761 309.1169 309.2577 309.3984 309.5392 309.6800 309.8207 309.9614 310.1022 310.2429 310.3836 310.5243 310.6650 310.8056 310.9463 311.0869 311.2276 311.3682 311.5088 311.6494 311.7900 311.9306 312.0712 312.2117 312.3523 312.4928 312.6334 312.7739 312.9144 313.0549 313.1954 313.3359 313.4763 313.6168 313.7572 313.8977 314.0381 314.1785 314.3189 314.4593 314.5997 314.7401 314.8804 315.0208 315.1611 315.3014 315.4418 315.5821 315.7224 315.8627 316.0029 316.1432 316.2834 316.4237 316.5639 316.7041 316.8444 316.9846 317.1247 317.2649 317.4051 317.5453 317.6854 317.8255 317.9657 318.1058 318.2459 318.3860 318.5260 318.6661 318.8062 318.9462 319.0863 319.2263 319.3663 319.5063 319.6463 319.7863 319.9263 320.0662 320.2062 320.3461 320.4860 320.6260 320.7659 320.9058 321.0456 321.1855 321.3254 321.4652 321.6051 321.7449 321.8847 322.0245 322.1643 322.3041 322.4439 322.5837 322.7234 322.8632 323.0029 323.1426 323.2823 323.4220 323.5617 323.7014 323.8411 323.9807 324.1204 324.2600 324.3996 324.5392 324.6788 324.8184 324.9580 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240706T203646.8Z 8953.858875 71 1 48.74 2 78.84 70.13 87.23 60.81 0.00 1 0.00 1 0 25 4.701e-01 1.486e-02 3.158e-01 8.743e-03 6.157987e-01 5.113540e-03 7.370472e-03 -6.000000e+00 2.987299e-01 232.50 -2.00 3.41 -2.00 321.35 0.00e+00 3.885619e-03 2.666765e-03 5.723543e-03 -6.000000e+00 1.358508e-02 291.39 -2.00 20.00 -2.00 320.67 0.00e+00 4.984 0.002 302.00 328.00 3 3.5341e+00 1.8770e-02 6.5341e-02 -6.0000e+00 7.4686e-01 2.1109e-01 2.4837e-02 4.8402e-02 -6.0000e+00 8.0476e-01 -2.4503e-01 2.1307e-02 2.1031e-02 -6.0000e+00 4.8095e-01 8.7477e-02 9.9827e-03 4.5095e-03 -6.0000e+00 1.9835e-01 5.4508e-05 -7.5735e-04 3.0132e-04 1.3524e-04 -6.0000e+00 1.6129e-02 -6.3339e-03 0.0000e+00 12 8 8 10 0 0 79.01 17.42 0.64 -0.00633 -0.01202 33 7 1 5 0 1476.660 21.48 15.00 17.42 33.66 7.5 995.91 -221415 -118019 -47365 -161000 46725 -186464 -22191 -212857 105806 -138976 -4366 201668 -109484 900000 -14240 60545 -46778 26016 6476 -59968 79486 -57395 60021 11498 -49633 35281 -61367 7343 15230 3402 -14525 -22752 10641 44086 23763 20241 34816 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-2517 -1091 782 -246 -267 -2064 -1289 -875 -142 -672 -1746 -1326 -2640 -381 1324 1425 -166 -1413 -528 -440 -365 530 269 1670 718 1685 993 2248 1156 1667 574 -1265 1613 -1319 1998 1007 -725 1137 -1485 -894 -806 1016 578 1456 -50 -1714 -69 -929 -1060 SS 20240706T204244.0Z 8953.863009 74 1 48.81 2 77.70 70.92 86.22 61.61 0.00 1 0.00 1 0 17 3.050e-01 9.600e-03 2.477e-01 6.607e-03 5.633034e-01 3.862020e-03 6.461326e-03 -6.000000e+00 1.961018e-01 232.50 -2.00 3.41 -2.00 321.15 0.00e+00 3.815638e-03 1.927507e-03 3.463777e-03 -6.000000e+00 9.674418e-03 291.39 -2.00 20.00 -2.00 320.44 0.00e+00 4.557 0.001 302.00 328.00 3 3.6143e+00 1.3779e-02 5.6052e-02 -6.0000e+00 4.9005e-01 4.7237e-02 1.8156e-02 3.5337e-02 -6.0000e+00 5.2850e-01 -3.1827e-02 1.5943e-02 1.7736e-02 -6.0000e+00 3.1380e-01 -2.4543e-03 7.5697e-03 4.8882e-03 -6.0000e+00 1.2934e-01 8.2148e-05 -1.3738e-04 2.3388e-04 1.1161e-04 -6.0000e+00 1.0593e-02 -6.2430e-03 0.0000e+00 12 8 8 10 0 0 62.08 17.43 0.33 -0.00624 -0.00728 43 9 1 5 0 1134.560 21.48 15.00 17.43 34.04 7.5 997.47 -53871 -8394 -140893 900000 -45076 900000 900000 -165517 -42856 -126148 900000 -111400 900000 93796 -81871 -22583 -46024 26766 -12162 24747 6143 -62336 13958 -62129 4991 -2982 6775 79385 -43016 16262 11703 18179 12542 3503 5800 -29109 -7459 -6621 13156 22635 -3675 11970 -9694 -5839 13573 8569 6004 -2760 1167 -1049 -4485 1728 7686 6314 -6510 9242 -336 543 4177 2362 5075 3334 5804 209 2196 2613 3370 3920 -4384 775 -1557 3763 2692 -1248 -1498 -3608 -3742 -2249 -46 3167 -1009 -1247 -3360 -695 -23 1823 1276 600 722 -80 807 1449 -593 179 -1819 -585 -636 659 571 -1071 156 -1953 -1444 -920 -1461 -223 -555 72 -159 633 385 221 120 -249 -312 -358 -356 111 672 494 -23 669 661 658 327 -87 241 -35 -319 -370 -338 77 -288 93 -78 544 -166 420 311 -90 83 -958 -147 -347 -54 -1766 900000 -290 900000 900000 -3000 -276 -1880 900000 -1802 900000 604 -1837 -334 -985 316 -231 345 108 -2169 242 -2389 108 -74 155 905 -1638 374 310 538 433 142 234 -1702 -381 -391 762 1404 -336 1019 -1085 -653 1281 870 640 -330 140 -140 -658 270 1241 1116 -1349 1756 -72 116 857 495 1074 778 1462 61 658 781 990 1176 -1545 289 -650 1566 1135 -526 -589 -1331 -1299 -793 -17 1273 -486 -680 -2055 -445 -16 1293 957 466 560 -61 575 965 -399 122 -1333 -479 -593 677 630 -1211 166 -1976 -1414 -895 -1498 -239 -616 84 -203 882 580 348 189 -382 -456 -507 -505 163 1024 782 -37 1042 1027 985 473 -122 332 -51 -497 -635 -609 148 -582 197 -175 1282 -406 1034 764 -217 190 -2122 -319 SS 20240706T204756.3Z 8953.866623 77 1 14.31 2 76.70 71.60 85.32 62.31 0.00 1 0.00 1 0 17 2.686e-01 1.439e-02 2.684e-01 1.006e-02 5.285671e-01 5.677104e-03 6.133282e-03 -6.000000e+00 1.706214e-01 232.50 -2.00 3.41 -2.00 320.55 0.00e+00 3.050590e-03 2.281339e-03 2.509827e-03 -6.000000e+00 7.725372e-03 291.39 -2.00 20.00 -2.00 319.78 0.00e+00 4.238 0.001 302.00 328.00 3 4.1915e+00 1.8156e-02 5.1404e-02 -6.0000e+00 4.2666e-01 1.3516e-01 2.2549e-02 3.0657e-02 -6.0000e+00 4.5976e-01 -1.1163e-01 1.8013e-02 1.4664e-02 -6.0000e+00 2.7465e-01 2.9300e-02 8.8938e-03 3.7983e-03 -6.0000e+00 1.1318e-01 6.2929e-05 -1.3786e-03 3.4583e-04 7.9629e-05 -6.0000e+00 9.1934e-03 -4.7875e-03 0.0000e+00 12 9 9 12 1 1 66.35 17.43 0.24 -0.00479 -0.01515 5 5 1 5 0 2383.310 21.48 15.00 17.43 34.33 7.5 997.93 -42791 -5872 -58475 -117390 -52148 -125279 127804 61477 25330 -19931 -95687 3559 -82638 17264 -92161 -22746 19630 -44458 -33642 5438 -27722 -36383 -5251 -16023 -51495 -5787 -11357 -8406 4724 -18278 -26032 1087 17292 -4694 30561 -6619 -14944 18714 -5622 26080 16191 4806 15510 -8133 13640 -2594 20914 1237 3459 4981 -5532 5476 -1232 7887 6850 6676 2122 -1481 -512 1942 6166 1102 194 8159 -1513 2976 -2592 2411 2878 -1440 4523 1964 3094 183 -60 -3 -1691 -2429 -1502 -1774 -4819 1795 829 -2690 -36 -1729 1492 -2025 1400 -106 -1569 -1582 -2671 -2120 -1712 799 1151 -229 495 -1867 422 -1217 -1174 280 -1248 -359 -2301 -444 2517 337 1643 -332 810 26 -658 1080 161 -911 -772 -75 75 831 1407 393 -58 1529 -300 960 -162 392 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