File name: Pandora192s1_Tokyo-Sophia_20240728_L2Fit_fout2c2d20230711p1-8.txt File generation date: 20240728T145710.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240728_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0445 305.1857 305.3270 305.4682 305.6094 305.7505 305.8917 306.0329 306.1740 306.3152 306.4563 306.5974 306.7385 306.8796 307.0207 307.1618 307.3028 307.4439 307.5849 307.7260 307.8670 308.0080 308.1490 308.2900 308.4309 308.5719 308.7129 308.8538 308.9947 309.1357 309.2766 309.4175 309.5583 309.6992 309.8401 309.9809 310.1218 310.2626 310.4034 310.5442 310.6850 310.8258 310.9666 311.1074 311.2481 311.3888 311.5296 311.6703 311.8110 311.9517 312.0924 312.2331 312.3737 312.5144 312.6550 312.7956 312.9363 313.0769 313.2175 313.3581 313.4986 313.6392 313.7797 313.9203 314.0608 314.2013 314.3418 314.4823 314.6228 314.7633 314.9037 315.0442 315.1846 315.3251 315.4655 315.6059 315.7463 315.8867 316.0270 316.1674 316.3077 316.4481 316.5884 316.7287 316.8690 317.0093 317.1496 317.2899 317.4301 317.5704 317.7106 317.8508 317.9910 318.1312 318.2714 318.4116 318.5518 318.6919 318.8321 318.9722 319.1123 319.2524 319.3925 319.5326 319.6727 319.8128 319.9528 320.0929 320.2329 320.3729 320.5129 320.6529 320.7929 320.9329 321.0729 321.2128 321.3527 321.4927 321.6326 321.7725 321.9124 322.0523 322.1921 322.3320 322.4719 322.6117 322.7515 322.8913 323.0311 323.1709 323.3107 323.4505 323.5902 323.7300 323.8697 324.0094 324.1491 324.2888 324.4285 324.5682 324.7079 324.8475 324.9872 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240727T203615.5Z 8974.858513 210 1 49.27 2 81.30 72.88 22.69 194.98 0.00 1 0.00 1 0 17 4.515e-01 2.725e-02 4.183e-01 2.184e-02 6.928390e-01 1.339825e-02 8.110052e-03 -6.000000e+00 2.915161e-01 232.00 -2.00 3.41 -2.00 321.86 0.00e+00 1.486724e-03 7.968137e-03 9.296063e-03 -6.000000e+00 1.539461e-02 292.34 -2.00 20.00 -2.00 321.24 0.00e+00 6.236 0.004 302.00 328.00 3 2.4681e+00 5.4647e-02 8.9378e-02 -6.0000e+00 7.2731e-01 5.2663e-01 7.0995e-02 7.9372e-02 -6.0000e+00 7.8629e-01 -7.5610e-01 5.1941e-02 2.6677e-02 -6.0000e+00 4.6952e-01 3.0292e-01 2.3778e-02 6.5338e-03 -6.0000e+00 1.9439e-01 4.5222e-05 -9.6234e-04 7.7192e-04 1.2808e-04 -6.0000e+00 1.6472e-02 -3.0431e-02 0.0000e+00 12 8 8 10 0 0 97.90 17.19 0.43 -0.03043 -0.03766 28 6 1 5 0 1759.270 21.38 15.00 17.19 35.67 10.5 999.41 900000 -19475 -124600 900000 83944 -6167 -56116 34874 -36621 -170662 -152006 900000 900000 32397 106512 -131755 -79690 -43486 900000 103830 900000 -62487 43912 34580 900000 -21026 900000 63771 -61454 41903 -7471 151040 26239 173271 -41364 21285 27537 -37367 900000 50008 2354 52592 4106 -1105 10107 111314 115115 50840 -2852 359 3813 28129 45995 28847 67707 16984 10961 67159 18814 22855 49368 -3429 23483 -3590 23148 7803 21347 11705 2545 15926 5611 27351 7470 22473 2483 -4270 6425 -5587 5922 -3058 1673 8708 -8464 805 -270 -192 -1457 -4287 640 -732 -3147 4802 -7271 -2582 -5598 -5075 1074 657 -3274 -1572 -1023 -3224 -4149 -1460 -1876 -3394 -450 -409 -2865 -264 -1386 1048 -858 -538 1173 825 577 -2120 995 1511 3162 1138 1591 2054 -767 3523 1254 2375 2306 -2901 1861 -1399 -639 797 603 814 111 175 -177 -733 -2021 -189 114 900000 -414 -3323 900000 1784 -131 -1193 741 -778 -7450 -5799 900000 900000 689 2264 -8778 -3573 -1489 900000 2207 900000 -2792 933 735 900000 -719 900000 1356 -2998 891 -250 3211 809 3683 -2613 732 941 -2727 900000 2137 176 2598 339 -98 809 3346 3396 2853 -279 36 402 2581 3853 3084 5239 2223 1569 5566 2427 2818 4813 -595 3430 -753 3927 1563 3743 2338 605 3680 1568 6494 2135 5327 664 -1118 1439 -1425 1475 -952 577 3182 -4021 380 -138 -104 -837 -2602 369 -416 -1741 2354 -3930 -1380 -3408 -3524 807 554 -3103 -1491 -935 -2797 -3417 -1174 -1582 -3083 -424 -416 -3282 -324 -1891 1481 -1257 -772 1618 1114 786 -3079 1467 2288 4713 1690 2298 2855 -1060 4538 1661 3264 3464 -5131 3449 -2883 -1393 1825 1455 2058 292 465 -473 -1898 -5034 -444 262 SS 20240727T204925.9Z 8974.867661 215 1 49.25 2 78.74 74.67 23.49 202.72 0.00 1 0.00 1 0 17 3.336e-01 5.676e-03 1.483e-01 2.316e-03 5.803431e-01 1.330131e-03 6.739059e-03 -6.000000e+00 2.134532e-01 232.00 -2.00 3.41 -2.00 321.16 0.00e+00 2.752067e-03 6.840346e-04 4.324437e-03 -6.000000e+00 9.764229e-03 292.34 -2.00 20.00 -2.00 320.47 0.00e+00 4.940 0.002 302.00 328.00 3 5.6363e-01 4.8169e-03 6.1305e-02 -6.0000e+00 5.3293e-01 4.6874e-02 6.4198e-03 4.1175e-02 -6.0000e+00 5.7427e-01 -5.9287e-02 5.5928e-03 1.8263e-02 -6.0000e+00 3.4346e-01 9.3875e-03 2.6312e-03 4.0968e-03 -6.0000e+00 1.4138e-01 1.2194e-03 1.2119e-04 7.9896e-05 1.0971e-04 -6.0000e+00 1.1672e-02 -3.1718e-02 0.0000e+00 10 0 0 10 0 0 22.88 17.18 0.27 -0.03172 -0.03081 294 65 1 5 0 167.470 21.38 15.00 17.18 36.53 10.5 1003.36 -52657 178164 -93029 -117412 -132628 -113504 -3650 -69584 -105232 -101810 -120325 -91903 21658 -44485 -32375 -46955 -36902 -38657 -32240 -10087 -9223 -24235 -31199 -19270 -21577 -20989 -14507 -17418 -13827 -22652 -14969 -11239 -3404 7029 -4487 -13427 -3314 -7960 -4813 189 2818 593 1434 -2240 59 1431 2039 1513 -647 -196 1308 1775 3685 3865 1564 3756 -47 646 1423 3170 1597 3364 2143 2871 2573 2051 1800 2081 1307 1399 858 882 733 517 50 -1133 -1498 -2017 -1798 -1410 -1269 -1102 -926 -1487 -288 -27 661 774 688 719 -206 -155 -126 188 -167 226 114 36 -331 -522 -896 -753 -802 -894 -1503 -911 -938 -87 585 346 366 108 -232 229 -132 355 298 489 511 181 392 328 402 85 14 -232 132 412 24 76 -442 -276 -260 24 43 -135 277 -44 -39 34 -144 -58 -11 -184 402 -630 -1036 -1334 -932 -12 -429 -1037 -1066 -1655 -1075 108 -532 -424 -771 -629 -746 -699 -187 -177 -558 -803 -470 -580 -592 -393 -488 -378 -716 -494 -414 -131 264 -194 -649 -157 -460 -323 14 234 55 140 -235 6 152 220 169 -77 -25 178 265 593 672 296 728 -10 134 291 639 339 760 541 788 744 601 526 625 429 510 345 372 311 211 19 -404 -505 -687 -663 -593 -613 -601 -555 -964 -197 -20 502 604 538 545 -150 -106 -84 127 -123 188 108 38 -378 -603 -993 -776 -782 -874 -1547 -988 -1082 -107 774 503 575 177 -385 366 -203 526 443 753 824 303 659 541 642 131 20 -336 188 608 38 136 -857 -570 -515 50 95 -313 663 -108 -93 79 -324 -125 -27 SS 20240727T205524.5Z 8974.871811 218 1 49.15 2 77.56 75.47 23.96 206.06 0.00 1 0.00 1 0 17 2.267e-01 5.335e-03 6.132e-02 1.587e-03 5.345428e-01 9.011487e-04 6.325303e-03 -6.000000e+00 1.450329e-01 232.00 -2.00 3.41 -2.00 320.89 0.00e+00 5.748966e-03 4.205447e-04 3.507799e-03 -6.000000e+00 6.634449e-03 292.34 -2.00 20.00 -2.00 320.14 0.00e+00 4.509 0.001 302.00 328.00 3 4.0325e-01 3.0625e-03 5.4307e-02 -6.0000e+00 3.6211e-01 2.8879e-02 3.9816e-03 3.2733e-02 -6.0000e+00 3.9020e-01 -2.3498e-02 3.4227e-03 1.7889e-02 -6.0000e+00 2.3337e-01 -6.5710e-03 1.6501e-03 5.8777e-03 -6.0000e+00 9.6058e-02 2.2299e-03 6.9438e-06 5.5604e-05 1.1577e-04 -6.0000e+00 7.9307e-03 -3.1601e-02 0.0000e+00 10 0 0 10 0 0 52.17 17.19 0.23 -0.03160 -0.03155 423 93 1 5 0 116.160 21.38 15.00 17.19 37.23 10.4 1005.98 -108937 -65109 -70893 -90724 -56070 -96577 -29263 -97553 -42125 -44822 -50049 -45813 -61897 -30500 -40107 -18336 11751 -11732 3235 -19627 -4095 -13793 -10638 1374 -16818 -1382 -22865 -8250 -14566 -9117 -2063 -9232 3442 -8331 -4724 -3557 -6296 -3764 -3608 1388 -3913 778 581 172 4191 -977 1619 -1935 2303 1441 1271 2933 260 3669 894 1131 1425 -581 1535 -468 1560 1910 2229 2809 111 1846 -627 1708 768 1490 1568 532 1048 -590 400 -135 -2059 -1129 -2065 -374 -1511 -1395 -1608 -1185 -129 -404 798 214 927 800 369 619 -562 -287 -312 209 447 -16 22 -457 -523 -1049 -775 -78 -1260 -639 -998 -288 92 697 691 265 116 -373 -35 20 434 879 221 278 130 177 286 26 247 -284 332 162 10 -61 -394 -339 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