File name: Pandora192s1_Tokyo-Sophia_20240730_L2Fit_fout2c4d20230711p1-8.txt File generation date: 20240911T155913.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240730_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0295 305.1706 305.3117 305.4528 305.5938 305.7349 305.8759 306.0169 306.1580 306.2990 306.4400 306.5810 306.7219 306.8629 307.0038 307.1448 307.2857 307.4266 307.5676 307.7085 307.8493 307.9902 308.1311 308.2720 308.4128 308.5536 308.6945 308.8353 308.9761 309.1169 309.2577 309.3984 309.5392 309.6800 309.8207 309.9614 310.1022 310.2429 310.3836 310.5243 310.6650 310.8056 310.9463 311.0869 311.2276 311.3682 311.5088 311.6494 311.7900 311.9306 312.0712 312.2117 312.3523 312.4928 312.6334 312.7739 312.9144 313.0549 313.1954 313.3359 313.4763 313.6168 313.7572 313.8977 314.0381 314.1785 314.3189 314.4593 314.5997 314.7401 314.8804 315.0208 315.1611 315.3014 315.4418 315.5821 315.7224 315.8627 316.0029 316.1432 316.2834 316.4237 316.5639 316.7041 316.8444 316.9846 317.1247 317.2649 317.4051 317.5453 317.6854 317.8255 317.9657 318.1058 318.2459 318.3860 318.5260 318.6661 318.8062 318.9462 319.0863 319.2263 319.3663 319.5063 319.6463 319.7863 319.9263 320.0662 320.2062 320.3461 320.4860 320.6260 320.7659 320.9058 321.0456 321.1855 321.3254 321.4652 321.6051 321.7449 321.8847 322.0245 322.1643 322.3041 322.4439 322.5837 322.7234 322.8632 323.0029 323.1426 323.2823 323.4220 323.5617 323.7014 323.8411 323.9807 324.1204 324.2600 324.3996 324.5392 324.6788 324.8184 324.9580 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240729T203655.9Z 8976.858980 218 1 49.31 2 81.43 73.37 20.87 119.78 0.00 1 0.00 1 0 25 5.373e-01 1.517e-02 4.223e-01 1.197e-02 7.212384e-01 7.266233e-03 7.864279e-03 -6.000000e+00 3.435680e-01 231.94 -2.00 3.41 -2.00 321.90 0.00e+00 1.544192e-03 4.593966e-03 3.931189e-03 -6.000000e+00 1.758709e-02 292.38 -2.00 20.00 -2.00 321.30 0.00e+00 6.318 0.004 302.00 328.00 3 2.4804e+00 3.0829e-02 7.6311e-02 -6.0000e+00 8.5747e-01 2.6391e-01 4.3460e-02 4.7897e-02 -6.0000e+00 9.2530e-01 -3.7287e-01 3.8212e-02 2.2111e-02 -6.0000e+00 5.5033e-01 1.4608e-01 1.7037e-02 5.4932e-03 -6.0000e+00 2.2797e-01 4.1681e-05 -7.8868e-04 4.0721e-04 1.0657e-04 -6.0000e+00 1.8847e-02 -3.3829e-03 0.0000e+00 12 8 8 10 0 0 78.57 16.96 0.49 -0.00338 -0.00931 47 10 1 5 0 1048.910 21.27 15.00 16.96 37.51 10.7 1005.23 -242118 -65237 -142287 900000 900000 -183969 900000 -118176 71719 -252506 900000 900000 -125422 -131079 -80398 -102891 -7960 -72779 -11720 -32647 -43826 -100505 25065 170577 17078 22252 -54878 -82974 -9171 -21548 96804 44075 196227 -32887 -48230 12895 61569 57477 -46903 17580 10243 21110 -11726 14413 29043 -45 9385 24540 28176 7180 10209 19895 6071 3580 15208 18122 12580 12969 -2704 9050 5245 6947 7693 8048 5917 13885 -901 3140 1989 4090 4762 12781 7495 5980 7757 -3915 -369 -6442 -4045 -1070 -3441 2052 -299 -36 -2163 -3243 -2589 1249 -2071 3041 2113 1789 71 -3455 -490 118 -1067 502 558 -76 -2208 -2361 -6537 679 -1882 -1643 -1023 577 -1049 852 684 -205 443 1333 -110 84 -231 -518 -523 955 -197 -56 1467 689 1257 1102 -827 560 -545 1000 235 601 -480 -754 777 -473 349 -104 309 102 -306 -380 -543 -3530 -761 -1660 900000 900000 -2146 900000 -1378 836 -6872 900000 900000 -1463 -2038 -938 -1800 -93 -1203 -137 -450 -697 -2637 292 1989 199 260 -1280 -2551 -136 -388 1129 561 2289 -1116 -1943 287 914 1036 -2884 671 478 962 -783 764 1355 -3 557 1301 1524 518 790 1561 605 399 1612 1960 1481 1526 -367 1084 673 950 1166 1348 1079 2385 -181 636 447 1010 1283 3334 2058 1592 1875 -976 -84 -1591 -1081 -323 -1244 803 -133 -17 -1133 -1826 -1521 725 -1243 1683 1122 907 36 -1886 -289 80 -843 442 531 -74 -2100 -2083 -5635 540 -1603 -1481 -977 587 -1195 1064 941 -303 661 1939 -157 117 -324 -756 -798 1481 -308 -85 2118 968 1699 1449 -1103 775 -845 1714 447 1228 -1059 -1780 1920 -1242 936 -283 832 265 -758 -896 -1262 SS 20240729T205114.5Z 8976.868918 223 1 49.29 2 78.64 75.32 18.45 126.04 0.00 1 0.00 1 0 17 2.970e-01 5.328e-03 6.536e-02 1.281e-03 5.871767e-01 7.309035e-04 6.676971e-03 -6.000000e+00 1.882322e-01 231.94 -2.00 3.41 -2.00 321.11 0.00e+00 1.465255e-03 3.684542e-04 3.850122e-03 -6.000000e+00 8.576373e-03 292.38 -2.00 20.00 -2.00 320.40 0.00e+00 4.900 0.002 302.00 328.00 3 4.7308e-01 2.5876e-03 6.0409e-02 -6.0000e+00 4.6986e-01 2.3116e-02 3.4756e-03 3.9782e-02 -6.0000e+00 5.0646e-01 -6.3739e-03 3.1160e-03 1.7318e-02 -6.0000e+00 3.0288e-01 -1.1026e-02 1.4760e-03 4.2302e-03 -6.0000e+00 1.2508e-01 1.3685e-03 -1.8351e-04 4.3332e-05 7.5631e-05 -6.0000e+00 1.0163e-02 -3.9115e-03 0.0000e+00 10 0 0 10 0 0 21.38 16.97 0.25 -0.00391 -0.00529 682 150 1 5 0 72.150 21.27 15.00 16.97 38.58 10.7 1010.23 -135089 -64491 -89152 -91340 -99387 -108512 -74895 -108712 -85919 -99305 -69557 -74702 -55626 -45431 -54092 -22147 -36735 -27376 -22148 -16278 -14989 -13409 -15883 -19076 -8141 -12076 -22576 -9233 -24505 -6734 -13046 -6680 -2320 -6551 -5220 -10328 -7731 -1106 -1518 -2038 -1214 1207 -1062 2379 2054 -22 -597 -2315 679 -356 1576 1387 1595 2028 1239 3148 1180 908 1181 273 1509 2102 3473 3537 1977 1021 267 1234 875 2090 1225 1184 340 -325 -132 -1228 -1383 -2433 -1706 -642 -1391 -1346 -1736 -913 -487 159 748 755 794 599 454 -80 -566 -476 -433 392 485 451 102 -540 -801 -1139 -968 -808 -1152 -1004 -980 -138 176 753 775 528 261 -38 -79 -116 307 505 331 320 193 327 249 272 61 -227 99 42 72 -122 -215 -446 -427 -78 -245 8 245 157 86 83 -64 -187 28 -921 -256 -496 -529 -610 -727 -383 -877 -625 -914 -574 -737 -549 -505 -811 -288 -633 -479 -401 -297 -283 -258 -329 -441 -183 -300 -640 -230 -717 -175 -409 -229 -86 -274 -220 -471 -376 -59 -98 -157 -105 112 -107 239 212 -2 -66 -269 80 -45 216 211 266 365 240 627 247 192 248 58 328 492 888 990 591 310 81 384 297 783 508 516 150 -139 -52 -451 -480 -857 -649 -277 -697 -763 -1087 -610 -347 120 589 612 643 471 338 -56 -389 -334 -331 338 476 495 120 -646 -918 -1217 -975 -812 -1217 -1122 -1163 -174 241 1021 1137 812 403 -57 -114 -177 470 799 500 500 304 502 408 429 93 -335 144 63 118 -221 -386 -855 -866 -168 -556 18 599 388 212 198 -148 -411 61 SS 20240729T205727.5Z 8976.873235 226 1 49.42 2 77.41 76.16 17.46 129.21 0.00 1 0.00 1 0 17 2.095e-01 5.044e-03 3.476e-02 9.177e-04 5.394801e-01 5.213090e-04 6.111696e-03 -6.000000e+00 1.328098e-01 231.94 -2.00 3.41 -2.00 320.81 0.00e+00 1.215190e-03 2.347534e-04 2.712747e-03 -6.000000e+00 6.051103e-03 292.38 -2.00 20.00 -2.00 320.05 0.00e+00 4.459 0.001 302.00 328.00 3 4.1882e-01 1.7518e-03 5.3891e-02 -6.0000e+00 3.3151e-01 1.9816e-02 2.2562e-03 3.2832e-02 -6.0000e+00 3.5733e-01 2.7762e-03 1.9283e-03 1.4913e-02 -6.0000e+00 2.1370e-01 -1.4806e-02 9.3669e-04 3.7672e-03 -6.0000e+00 8.8254e-02 2.2964e-03 -2.0417e-04 3.1785e-05 6.5289e-05 -6.0000e+00 7.1703e-03 -4.3467e-03 0.0000e+00 10 0 0 10 0 0 3.25 16.97 0.20 -0.00435 -0.00588 897 197 1 5 0 54.830 21.38 15.00 16.97 39.14 10.6 1012.13 -73850 -87831 -78602 -69361 -50165 -74068 -69075 -77113 -64235 -55447 -52789 -39662 -37062 -19135 -29296 -24100 -16179 -16322 -5475 -6199 -7904 -12324 -14230 -7653 -10107 -7278 -6519 -12374 -13481 -10381 -7081 -3409 1561 -1429 -8612 -9121 -7430 -2421 -883 2195 509 -431 379 31 775 286 734 121 -847 678 125 1027 1904 1616 1678 1042 1311 571 913 923 1559 2602 1932 2900 1420 1249 153 47 850 874 1081 1102 826 187 -926 -1212 -2255 -1886 -1942 -670 -952 -1325 -1779 -1265 -380 123 747 791 669 455 300 -113 -431 -334 -19 377 474 447 235 -268 -720 -1076 -1057 -642 -948 -816 -772 -404 282 633 796 466 217 -118 -122 -4 185 581 303 277 304 202 232 61 124 -67 127 167 -67 -23 -322 -363 -334 -84 -171 -133 264 45 79 179 0 -63 -149 -469 -750 -665 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