File name: Pandora192s1_Tokyo-Sophia_20240818_L2Fit_fout2c2d20230711p1-8.txt File generation date: 20240818T145348.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240818_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0445 305.1857 305.3270 305.4682 305.6094 305.7505 305.8917 306.0329 306.1740 306.3152 306.4563 306.5974 306.7385 306.8796 307.0207 307.1618 307.3028 307.4439 307.5849 307.7260 307.8670 308.0080 308.1490 308.2900 308.4309 308.5719 308.7129 308.8538 308.9947 309.1357 309.2766 309.4175 309.5583 309.6992 309.8401 309.9809 310.1218 310.2626 310.4034 310.5442 310.6850 310.8258 310.9666 311.1074 311.2481 311.3888 311.5296 311.6703 311.8110 311.9517 312.0924 312.2331 312.3737 312.5144 312.6550 312.7956 312.9363 313.0769 313.2175 313.3581 313.4986 313.6392 313.7797 313.9203 314.0608 314.2013 314.3418 314.4823 314.6228 314.7633 314.9037 315.0442 315.1846 315.3251 315.4655 315.6059 315.7463 315.8867 316.0270 316.1674 316.3077 316.4481 316.5884 316.7287 316.8690 317.0093 317.1496 317.2899 317.4301 317.5704 317.7106 317.8508 317.9910 318.1312 318.2714 318.4116 318.5518 318.6919 318.8321 318.9722 319.1123 319.2524 319.3925 319.5326 319.6727 319.8128 319.9528 320.0929 320.2329 320.3729 320.5129 320.6529 320.7929 320.9329 321.0729 321.2128 321.3527 321.4927 321.6326 321.7725 321.9124 322.0523 322.1921 322.3320 322.4719 322.6117 322.7515 322.8913 323.0311 323.1709 323.3107 323.4505 323.5902 323.7300 323.8697 324.0094 324.1491 324.2888 324.4285 324.5682 324.7079 324.8475 324.9872 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240817T222726.3Z 8995.935721 210 1 12.36 2 61.74 94.08 144.31 276.26 0.00 1 0.00 1 0 17 1.053e-02 5.591e-03 3.950e-03 1.242e-03 2.640488e-01 6.926312e-04 3.082833e-03 -6.000000e+00 6.776492e-03 231.23 -2.00 3.41 -2.00 317.27 0.00e+00 6.716426e-04 1.031600e-04 2.849147e-04 -6.000000e+00 3.097652e-04 292.54 -2.00 20.00 -2.00 316.37 0.00e+00 2.101 0.000 302.00 328.00 3 2.2233e+00 1.8363e-03 2.4891e-02 -6.0000e+00 1.6888e-02 2.0869e-02 2.0580e-03 1.3471e-02 -6.0000e+00 1.8170e-02 5.1261e-03 1.2096e-03 6.4968e-03 -6.0000e+00 1.0866e-02 -9.0454e-03 5.7524e-04 1.7648e-03 -6.0000e+00 4.5421e-03 5.1307e-03 -7.7285e-04 4.4088e-05 2.6153e-05 -6.0000e+00 3.7031e-04 -8.7202e-02 0.0000e+00 12 1 1 12 1 1 99.89 16.73 0.20 -0.08720 -0.09301 52 46 1 5 0 232.980 21.17 15.01 16.73 37.39 3.5 970.41 900000 -2663 -2719 -4414 -2056 -3548 1296 318 -304 -1872 -3128 -2587 -1378 303 -878 -1350 -1252 -525 1636 529 1611 242 -59 555 518 1552 -192 19 -926 -726 1094 3 653 -272 -2369 -2172 -2773 -655 -711 -111 -501 -941 -229 -617 305 -63 -163 -55 -333 -134 -33 720 891 1116 510 470 619 210 624 513 1341 1888 1498 1504 522 498 261 287 681 811 653 159 167 75 -272 -308 -593 -521 -558 -627 -1126 -1729 -1715 -1614 -1118 -544 -25 135 45 -120 -68 298 -14 151 416 689 444 227 4 -347 -516 -786 -742 21 -741 -744 -802 -799 1 422 534 253 35 11 139 176 462 884 523 479 -25 28 145 74 311 308 452 791 590 331 -95 -233 -136 14 97 -54 -120 -32 -272 -112 -116 -377 -344 900000 -283 -308 -510 -222 -366 126 33 -35 -234 -413 -351 -197 47 -158 -272 -274 -120 383 130 404 63 -15 149 146 450 -58 5 -264 -200 298 1 201 -89 -795 -720 -953 -244 -280 -51 -259 -527 -133 -370 183 -38 -97 -32 -193 -77 -20 445 583 769 338 321 430 148 436 357 941 1378 1171 1248 449 420 209 221 530 678 597 143 154 69 -258 -271 -478 -393 -420 -503 -1005 -1586 -1708 -1715 -1257 -601 -29 163 55 -146 -79 342 -15 153 424 748 531 276 6 -465 -674 -970 -869 24 -896 -954 -1085 -1059 1 614 814 397 54 16 192 245 625 1211 753 681 -36 41 213 106 452 428 602 1036 799 475 -134 -344 -207 22 160 -87 -203 -55 -476 -194 -196 -616 -587 SS 20240817T223143.9Z 8995.938702 213 1 49.51 2 60.87 94.75 145.13 277.01 0.00 1 0.00 1 0 17 1.094e-02 5.300e-03 2.564e-03 5.978e-04 2.581838e-01 3.346367e-04 3.007761e-03 -6.000000e+00 7.036991e-03 231.23 -2.00 3.41 -2.00 317.97 0.00e+00 5.824758e-04 5.924028e-05 3.680205e-04 -6.000000e+00 3.216862e-04 292.54 -2.00 20.00 -2.00 317.03 0.00e+00 2.045 0.000 302.00 328.00 3 1.4850e+00 9.0238e-04 2.4297e-02 -6.0000e+00 1.7537e-02 1.7953e-02 1.0183e-03 1.3285e-02 -6.0000e+00 1.8869e-02 7.9976e-03 6.2279e-04 6.4131e-03 -6.0000e+00 1.1284e-02 -1.1791e-02 3.0444e-04 1.7490e-03 -6.0000e+00 4.7165e-03 1.1467e-02 -8.0994e-04 2.1676e-05 2.5314e-05 -6.0000e+00 3.8457e-04 -8.6910e-02 0.0000e+00 10 0 0 10 0 0 99.98 16.73 0.25 -0.08691 -0.09300 982 216 1 5 0 50.100 21.17 15.00 16.73 37.67 3.5 972.24 900000 -3038 -3160 -3683 -2604 -3179 -2763 -2544 -1250 -2182 -3276 -1752 -2627 -686 -1242 -356 -203 -389 539 -46 1015 324 1115 1017 -121 744 -575 -688 -523 86 759 473 682 -968 -2098 -2818 -1966 -1326 -804 -368 -1128 -563 -594 -660 -183 -312 -252 -684 -308 95 78 827 709 950 486 571 744 450 673 604 1308 1731 1827 1650 665 332 -12 375 736 1129 811 328 179 -21 -48 -224 -613 -618 -545 -407 -1043 -1544 -1762 -1624 -939 -673 27 70 61 75 190 219 3 242 339 587 522 277 -58 -439 -537 -825 -569 -121 -611 -923 -977 -650 -116 318 438 241 62 -162 32 199 550 886 591 310 21 50 178 99 312 276 513 647 539 349 -30 -247 -209 39 -22 -44 90 -30 -120 -122 -146 -392 -295 900000 -233 -259 -304 -203 -235 -200 -195 -103 -197 -311 -169 -272 -77 -160 -51 -31 -63 91 -8 182 59 206 212 -27 170 -135 -159 -116 18 161 106 163 -247 -544 -728 -519 -385 -270 -143 -498 -267 -295 -337 -94 -160 -128 -343 -151 46 39 431 393 554 296 358 476 291 432 387 845 1164 1309 1256 524 257 -9 264 524 861 677 293 164 -19 -42 -180 -452 -426 -374 -297 -848 -1395 -1733 -1703 -944 -720 31 82 73 88 211 248 3 241 340 628 613 324 -73 -566 -674 -979 -703 -148 -781 -1141 -1273 -886 -165 477 688 388 98 -248 45 266 711 1161 815 454 31 76 268 144 435 404 720 894 768 528 -43 -374 -326 63 -37 -78 166 -56 -229 -231 -269 -701 -517 SS 20240817T223609.5Z 8995.941777 216 1 49.81 2 59.97 95.44 145.96 277.81 0.00 1 0.00 1 0 25 1.012e-02 5.450e-03 9.060e-04 2.631e-04 2.510254e-01 1.463565e-04 2.949381e-03 -6.000000e+00 6.512657e-03 231.23 -2.00 3.41 -2.00 317.58 0.00e+00 5.627326e-04 2.345377e-05 3.052743e-04 -6.000000e+00 2.976889e-04 292.54 -2.00 20.00 -2.00 316.67 0.00e+00 1.990 0.000 302.00 328.00 3 3.7245e-01 3.9051e-04 2.3640e-02 -6.0000e+00 1.6231e-02 1.0707e-02 4.3832e-04 1.2899e-02 -6.0000e+00 1.7462e-02 6.1254e-03 2.6013e-04 6.2126e-03 -6.0000e+00 1.0443e-02 -1.0416e-02 1.2538e-04 1.6808e-03 -6.0000e+00 4.3655e-03 3.7389e-02 -6.9584e-04 9.4023e-06 2.5164e-05 -6.0000e+00 3.5587e-04 -8.7569e-02 0.0000e+00 10 0 0 10 0 0 96.78 16.73 0.29 -0.08757 -0.09280 1391 305 1 5 0 35.340 21.17 15.00 16.73 38.01 3.5 973.03 900000 -2058 -3089 -3377 -3249 -3309 -1972 -1092 -1180 -1071 -2864 -2267 -1885 -1239 -561 -770 -767 -393 320 476 971 582 928 962 524 358 -290 -661 -532 184 689 487 587 -624 -2202 -2161 -2264 -1360 -707 -349 -640 -595 -263 -463 -229 -150 -235 -297 -232 138 489 770 853 975 554 586 774 442 526 623 1216 1833 1711 1615 583 274 16 222 750 1047 817 277 91 -45 -123 -208 -596 -666 -559 -556 -928 -1533 -1771 -1646 -1107 -691 -51 71 80 97 62 150 12 319 482 610 552 340 -67 -398 -633 -813 -576 -104 -609 -879 -882 -666 -102 330 495 207 35 -72 3 334 574 842 638 294 33 24 189 108 334 381 497 739 598 417 18 -230 -194 65 26 -107 24 -36 -184 -182 -209 -351 -324 900000 -188 -303 -333 -335 -321 -186 -108 -128 -125 -354 -287 -252 -183 -93 -143 -154 -83 70 107 224 137 220 235 134 96 -79 -178 -137 46 170 126 162 -183 -659 -639 -690 -455 -273 -156 -323 -295 -136 -246 -122 -80 -125 -170 -131 77 278 458 489 588 350 380 511 295 350 412 813 1272 1268 1270 475 219 12 161 549 821 701 254 86 -42 -109 -171 -451 -519 -433 -417 -772 -1417 -1782 -1765 -1151 -763 -60 85 98 117 71 174 13 325 493 665 605 409 -87 -527 -817 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