File name: Pandora192s1_Tokyo-Sophia_20240819_L2Fit_fout2c2d20230711p1-8.txt File generation date: 20240819T145403.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240819_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0445 305.1857 305.3270 305.4682 305.6094 305.7505 305.8917 306.0329 306.1740 306.3152 306.4563 306.5974 306.7385 306.8796 307.0207 307.1618 307.3028 307.4439 307.5849 307.7260 307.8670 308.0080 308.1490 308.2900 308.4309 308.5719 308.7129 308.8538 308.9947 309.1357 309.2766 309.4175 309.5583 309.6992 309.8401 309.9809 310.1218 310.2626 310.4034 310.5442 310.6850 310.8258 310.9666 311.1074 311.2481 311.3888 311.5296 311.6703 311.8110 311.9517 312.0924 312.2331 312.3737 312.5144 312.6550 312.7956 312.9363 313.0769 313.2175 313.3581 313.4986 313.6392 313.7797 313.9203 314.0608 314.2013 314.3418 314.4823 314.6228 314.7633 314.9037 315.0442 315.1846 315.3251 315.4655 315.6059 315.7463 315.8867 316.0270 316.1674 316.3077 316.4481 316.5884 316.7287 316.8690 317.0093 317.1496 317.2899 317.4301 317.5704 317.7106 317.8508 317.9910 318.1312 318.2714 318.4116 318.5518 318.6919 318.8321 318.9722 319.1123 319.2524 319.3925 319.5326 319.6727 319.8128 319.9528 320.0929 320.2329 320.3729 320.5129 320.6529 320.7929 320.9329 321.0729 321.2128 321.3527 321.4927 321.6326 321.7725 321.9124 322.0523 322.1921 322.3320 322.4719 322.6117 322.7515 322.8913 323.0311 323.1709 323.3107 323.4505 323.5902 323.7300 323.8697 324.0094 324.1491 324.2888 324.4285 324.5682 324.7079 324.8475 324.9872 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240818T210237.4Z 8996.876822 204 1 49.04 2 79.05 82.13 114.86 261.12 0.00 1 0.00 1 0 17 3.760e-01 1.636e-02 3.872e-01 1.510e-02 6.098135e-01 9.048912e-03 7.163948e-03 -6.000000e+00 2.424762e-01 231.17 -2.00 3.41 -2.00 321.32 0.00e+00 2.701334e-03 4.584289e-03 4.058983e-03 -6.000000e+00 1.151859e-02 292.48 -2.00 20.00 -2.00 320.64 0.00e+00 5.068 0.002 302.00 328.00 3 2.9947e+00 3.2780e-02 6.2798e-02 -6.0000e+00 6.0598e-01 2.3346e-01 4.3131e-02 4.1665e-02 -6.0000e+00 6.5332e-01 -2.6492e-01 3.5704e-02 1.8902e-02 -6.0000e+00 3.8933e-01 9.5581e-02 1.6823e-02 4.5329e-03 -6.0000e+00 1.6238e-01 8.7046e-05 -2.1097e-03 5.3099e-04 1.0266e-04 -6.0000e+00 1.3231e-02 -8.6230e-02 0.0000e+00 12 8 8 10 0 0 99.94 16.80 0.62 -0.08623 -0.10208 52 11 1 5 0 942.920 21.17 15.01 16.80 36.36 3.7 967.36 900000 -144205 -148944 -47139 -107761 62699 -35634 -178015 -26788 -92746 900000 -139228 3703 -66972 -47746 12219 -106256 62318 7246 900000 91230 101065 -13034 -7598 57885 -62866 26980 -57100 -52710 13850 -31533 -29647 46175 16069 41682 -16873 14002 -1074 29880 13952 5147 5552 -611 6316 -3344 2633 7957 19465 14470 -2189 -11142 -3841 22200 -1709 14123 16688 739 7868 16670 8574 6763 -4733 1935 7264 5409 -3602 4198 221 1722 6226 2527 9220 1534 5085 -1542 106 -4739 -4989 518 -4700 -1009 1085 -893 2622 -2301 -570 -1814 268 1885 -287 3845 -1226 1546 -2803 801 -272 -2178 -1890 -710 -752 -1955 -1360 1358 -2360 -1167 -4004 -2030 -936 -1428 565 632 482 557 162 306 -968 1432 -27 1954 1209 -899 984 1484 177 -1362 1217 43 1853 3086 -928 -302 330 139 -457 -646 460 45 29 -590 167 -139 -1364 867 900000 -2268 -2751 -694 -1586 923 -524 -4592 -394 -1365 900000 -3519 54 -1179 -864 180 -4660 917 129 900000 1343 1488 -329 -190 852 -3036 564 -2707 -2376 339 -1294 -1365 1167 598 1260 -904 578 -58 1401 899 412 489 -61 612 -365 275 810 1802 1454 -273 -1635 -574 2814 -299 2253 2726 146 1469 2864 1580 1283 -1063 440 1747 1408 -1053 1144 63 512 1951 909 3320 610 1908 -582 36 -1589 -1625 167 -1792 -428 510 -477 1469 -1450 -376 -1280 193 1364 -209 2568 -812 960 -1807 528 -200 -1869 -1830 -746 -824 -2127 -1380 1262 -2203 -1103 -4108 -2165 -1053 -1747 743 910 742 878 253 459 -1416 2015 -40 2947 1917 -1464 1574 2291 267 -2013 1710 60 2553 4496 -1554 -547 637 285 -998 -1501 1115 114 74 -1534 422 -340 -3238 1948 SS 20240818T211744.1Z 8996.887316 213 1 11.76 2 76.00 84.26 117.73 263.10 0.00 1 0.00 1 0 25 3.201e-01 1.531e-02 2.773e-01 1.243e-02 4.891832e-01 7.096219e-03 5.643727e-03 -6.000000e+00 2.053594e-01 231.17 -2.00 3.41 -2.00 320.38 0.00e+00 -8.989063e-04 2.722882e-03 1.567655e-03 -6.000000e+00 9.405266e-03 292.48 -2.00 20.00 -2.00 319.59 0.00e+00 4.039 0.001 302.00 328.00 3 3.7541e+00 2.2260e-02 4.8290e-02 -6.0000e+00 5.1168e-01 2.9669e-02 2.7533e-02 2.8464e-02 -6.0000e+00 5.5108e-01 -6.5670e-02 2.1609e-02 1.2335e-02 -6.0000e+00 3.2954e-01 2.3324e-02 1.0762e-02 4.6268e-03 -6.0000e+00 1.3729e-01 1.3115e-04 -3.9520e-03 4.4011e-04 5.3196e-05 -6.0000e+00 1.1256e-02 -6.7241e-02 0.0000e+00 12 9 9 12 1 1 92.46 16.75 0.41 -0.06724 -0.09694 3 4 1 5 0 2937.080 21.17 15.00 16.75 36.90 3.7 969.12 900000 -137042 83907 -119744 2724 -81325 -90193 -106823 -90300 13174 -47804 12389 141038 -83430 87929 -64433 63447 -23128 -36738 22728 7204 79976 -25176 48465 23536 -11528 25052 28171 -12550 23589 24222 17669 10097 3568 -8207 27460 17482 -905 -12392 -5148 8752 -7464 10594 -15013 4629 12824 -1351 2437 2839 14019 1084 4285 12219 -6010 -824 -546 1854 6818 2947 1984 -5831 854 1356 6125 3965 2958 -1861 -2657 1173 7191 4152 3047 -2447 2687 4099 1074 1657 -2935 -2569 -3768 -1724 -2200 817 -2942 -172 435 -1690 1225 -732 455 362 -928 1765 -1369 475 -810 -2455 -21 510 1133 -1351 -2385 -1647 -274 -3139 -54 -312 -2797 664 518 667 765 581 604 -905 -235 109 233 1066 -205 637 1161 478 775 -746 2072 60 -60 220 1925 -381 -950 -116 -99 25 124 -177 392 452 -272 -476 -208 -805 900000 -4107 1017 -3475 33 -1562 -1918 -2892 -2354 160 -997 156 1709 -3534 1066 -3161 1020 -943 -1849 683 264 1493 -1348 1351 898 -662 1043 1147 -747 989 1076 921 636 261 -697 1664 1224 -85 -1530 -703 1197 -1325 1687 -3167 825 2126 -260 456 538 2485 232 966 2779 -1756 -243 -169 581 2066 926 625 -2013 290 497 2331 1616 1243 -798 -1153 513 3249 2115 1665 -1449 1501 2139 539 771 -1371 -1231 -1997 -1009 -1449 578 -2293 -139 374 -1558 1142 -699 426 327 -800 1425 -1119 394 -742 -2526 -23 609 1390 -1661 -2810 -1826 -296 -3569 -63 -383 -3663 899 754 1027 1228 947 970 -1405 -353 160 347 1650 -331 1045 1885 770 1214 -1152 3017 87 -87 333 3091 -666 -1745 -221 -196 52 267 -394 880 1019 -613 -1045 -442 -1684 SS 20240818T221557.1Z 8996.927744 244 1 49.18 2 64.20 92.67 128.87 271.14 0.00 1 0.00 1 0 17 1.517e-02 5.302e-03 4.821e-03 8.325e-04 2.912538e-01 4.664306e-04 3.378453e-03 -6.000000e+00 9.759332e-03 231.17 -2.00 3.41 -2.00 318.50 0.00e+00 7.437434e-04 9.577830e-05 4.430179e-04 -6.000000e+00 4.460704e-04 292.48 -2.00 20.00 -2.00 317.56 0.00e+00 2.283 0.000 302.00 328.00 3 1.8319e+00 1.2781e-03 2.7241e-02 -6.0000e+00 2.4318e-02 8.0469e-03 1.4560e-03 1.5047e-02 -6.0000e+00 2.6165e-02 6.5481e-03 9.2683e-04 7.2823e-03 -6.0000e+00 1.5648e-02 -1.2655e-02 4.6305e-04 1.9893e-03 -6.0000e+00 6.5420e-03 6.1311e-03 -9.2803e-04 3.0330e-05 2.8581e-05 -6.0000e+00 5.3336e-04 -8.7867e-02 0.0000e+00 10 0 0 10 0 0 99.78 16.72 0.28 -0.08787 -0.09484 566 124 1 5 0 86.880 21.17 15.00 16.72 36.69 3.8 968.79 900000 -4937 -2316 -6506 -5102 -7234 -3506 -50 -3673 -385 -5532 -3715 -2425 -1190 506 -1364 583 -2263 213 -1532 210 1281 682 1611 -268 210 -195 -1037 -53 -654 494 -329 460 -618 -1838 -1807 -2934 -1122 -1289 -751 -706 -1050 -159 -982 -247 -570 -457 -379 -203 326 285 727 676 994 842 419 962 194 404 520 1116 1926 1740 1943 553 395 54 350 812 1297 1044 192 221 166 -23 -156 -772 -775 -1013 -754 -978 -1748 -1592 -1576 -985 -639 112 270 350 376 100 244 -175 172 437 566 750 382 -87 -489 -571 -758 -617 -35 -798 -1029 -993 -690 -26 366 551 293 40 -59 -27 386 468 767 373 122 -35 -11 261 -41 321 315 308 672 475 354 -58 -321 -304 11 63 -45 146 -1 -184 -114 -198 -180 -212 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