File name: Pandora192s1_Tokyo-Sophia_20240910_L2Fit_fout2c2d20230711p1-8.txt File generation date: 20240910T144642.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v2d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240910_L1_smca1c2d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for OoB CF First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0445 305.1857 305.3270 305.4682 305.6094 305.7505 305.8917 306.0329 306.1740 306.3152 306.4563 306.5974 306.7385 306.8796 307.0207 307.1618 307.3028 307.4439 307.5849 307.7260 307.8670 308.0080 308.1490 308.2900 308.4309 308.5719 308.7129 308.8538 308.9947 309.1357 309.2766 309.4175 309.5583 309.6992 309.8401 309.9809 310.1218 310.2626 310.4034 310.5442 310.6850 310.8258 310.9666 311.1074 311.2481 311.3888 311.5296 311.6703 311.8110 311.9517 312.0924 312.2331 312.3737 312.5144 312.6550 312.7956 312.9363 313.0769 313.2175 313.3581 313.4986 313.6392 313.7797 313.9203 314.0608 314.2013 314.3418 314.4823 314.6228 314.7633 314.9037 315.0442 315.1846 315.3251 315.4655 315.6059 315.7463 315.8867 316.0270 316.1674 316.3077 316.4481 316.5884 316.7287 316.8690 317.0093 317.1496 317.2899 317.4301 317.5704 317.7106 317.8508 317.9910 318.1312 318.2714 318.4116 318.5518 318.6919 318.8321 318.9722 319.1123 319.2524 319.3925 319.5326 319.6727 319.8128 319.9528 320.0929 320.2329 320.3729 320.5129 320.6529 320.7929 320.9329 321.0729 321.2128 321.3527 321.4927 321.6326 321.7725 321.9124 322.0523 322.1921 322.3320 322.4719 322.6117 322.7515 322.8913 323.0311 323.1709 323.3107 323.4505 323.5902 323.7300 323.8697 324.0094 324.1491 324.2888 324.4285 324.5682 324.7079 324.8475 324.9872 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240909T215450.7Z 9018.913087 85 1 50.06 2 71.62 97.40 145.70 82.78 0.00 1 0.00 1 0 17 6.378e-02 1.270e-02 3.594e-03 3.864e-04 3.539517e-01 2.155993e-04 4.682694e-03 -6.000000e+00 4.096730e-02 229.71 -2.00 3.41 -2.00 319.32 0.00e+00 3.229350e-03 5.722010e-05 2.606100e-03 -6.000000e+00 1.866176e-03 291.18 -2.00 20.00 -2.00 318.47 0.00e+00 3.130 0.000 302.00 328.00 3 -3.3324e-01 6.0927e-04 3.7385e-02 -6.0000e+00 1.0177e-01 -1.0041e-03 7.0958e-04 2.2971e-02 -6.0000e+00 1.0951e-01 -1.5734e-02 4.9368e-04 1.0209e-02 -6.0000e+00 6.5527e-02 -2.8517e-03 2.5259e-04 2.4181e-03 -6.0000e+00 2.7551e-02 2.1910e-02 -3.2812e-03 1.3879e-05 4.8972e-05 -6.0000e+00 2.2391e-03 -1.1280e-01 0.0000e+00 12 8 8 10 0 0 16.16 16.40 0.46 -0.11280 -0.13746 1649 362 1 5 0 29.790 20.87 15.00 16.40 34.88 7.5 973.16 900000 -20808 -18225 -14108 -18279 -18954 -23066 -23476 -21192 -20085 -18192 -19821 -17949 -12585 -7922 -3961 -2489 60 -160 1498 1188 503 1063 -138 96 -1320 -2405 -4094 -5374 -5669 -5854 -4014 -3822 -3372 -5278 -6557 -6724 -5353 -2361 -172 999 1676 2255 2657 2585 2835 2156 1545 743 445 477 1060 1625 2027 1616 1524 1433 774 266 208 721 1841 2964 3455 2678 1476 344 -526 -455 895 1422 1524 1370 780 -104 -1564 -3285 -4917 -5372 -4654 -3739 -3073 -2480 -1886 -827 109 1321 1852 2082 1808 1229 226 -1214 -2090 -2331 -1427 -595 353 564 166 -435 -1397 -1953 -1664 -1455 -1333 -877 -158 883 1775 2275 2112 1461 687 -97 -655 -650 -183 276 529 819 978 1155 729 238 -479 -1159 -1265 -1218 -1026 -861 -969 -1008 -633 -129 50 526 779 657 519 151 -343 -585 900000 -630 -599 -464 -614 -610 -751 -796 -764 -857 -807 -936 -900 -683 -482 -270 -188 5 -14 133 111 48 103 -14 10 -147 -279 -483 -630 -656 -695 -502 -525 -498 -822 -1033 -1080 -922 -456 -38 251 461 658 803 800 887 684 493 239 145 161 376 615 816 690 677 654 361 124 97 339 892 1526 1912 1577 887 202 -302 -263 547 950 1097 1025 586 -76 -1077 -2115 -3009 -3270 -2996 -2662 -2439 -2158 -1600 -741 103 1314 1921 2206 1909 1257 219 -1112 -2019 -2268 -1338 -612 399 695 214 -560 -1725 -2279 -1879 -1680 -1625 -1127 -213 1247 2648 3604 3216 2264 1140 -154 -984 -943 -266 416 840 1350 1630 1896 1167 369 -716 -1676 -1801 -1783 -1600 -1437 -1711 -1698 -1106 -235 95 1047 1593 1363 1074 305 -676 -1122 SS 20240909T220013.7Z 9018.916825 88 1 50.13 2 70.54 98.24 144.67 83.74 0.00 1 0.00 1 0 17 5.368e-02 1.245e-02 4.187e-03 4.791e-04 3.386132e-01 2.683898e-04 4.446649e-03 -6.000000e+00 3.447627e-02 229.71 -2.00 3.41 -2.00 319.20 0.00e+00 3.102911e-03 6.816916e-05 2.328664e-03 -6.000000e+00 1.570643e-03 291.18 -2.00 20.00 -2.00 318.33 0.00e+00 2.967 0.000 302.00 328.00 3 1.2376e-01 7.5545e-04 3.5344e-02 -6.0000e+00 8.5648e-02 3.0034e-03 8.7515e-04 2.1300e-02 -6.0000e+00 9.2167e-02 -5.8584e-03 5.9557e-04 9.6234e-03 -6.0000e+00 5.5147e-02 -8.5512e-03 3.0405e-04 2.3346e-03 -6.0000e+00 2.3182e-02 1.6468e-02 -3.3717e-03 1.7369e-05 4.2961e-05 -6.0000e+00 1.8846e-03 -1.1174e-01 0.0000e+00 12 8 8 10 0 0 95.81 16.41 0.49 -0.11174 -0.13708 1510 331 1 5 0 32.540 20.87 15.00 16.41 35.48 7.6 976.59 900000 -13158 -12208 -13688 -13074 -19173 -19155 -18668 -16974 -16740 -16147 -17755 -15684 -10488 -7252 -3228 -1714 -653 1135 305 2408 841 949 564 -586 -1169 -2207 -3901 -5127 -5045 -5258 -4173 -3222 -3605 -5052 -6229 -6648 -4973 -2601 107 808 1394 2237 2272 2353 2354 1757 1201 922 227 536 1017 1191 1915 1613 1375 1469 634 188 223 735 1965 2936 3183 2592 1455 179 -305 -460 820 1408 1390 1243 757 -149 -1420 -3136 -4765 -5267 -4539 -3612 -2942 -2449 -1774 -866 138 1384 1885 2160 1842 1151 166 -1195 -2083 -2270 -1412 -526 393 630 171 -344 -1398 -1930 -1606 -1455 -1346 -801 -192 847 1743 2244 2037 1459 677 -86 -664 -726 -214 217 540 772 935 1145 656 148 -476 -1134 -1305 -1175 -999 -860 -989 -1023 -597 -119 64 563 754 655 518 200 -281 -531 900000 -422 -431 -510 -474 -701 -680 -683 -664 -711 -721 -842 -785 -567 -444 -220 -129 -53 106 30 243 88 101 62 -68 -142 -279 -501 -653 -630 -671 -564 -472 -572 -839 -1044 -1137 -909 -536 25 216 408 692 730 772 782 590 405 311 78 188 376 471 802 714 634 694 306 91 108 357 983 1561 1820 1571 898 108 -178 -271 510 955 1016 945 577 -110 -991 -2045 -2949 -3236 -2941 -2582 -2340 -2134 -1655 -853 130 1375 1954 2285 1943 1177 177 -1199 -2001 -2190 -1440 -587 439 764 217 -435 -1696 -2212 -1782 -1653 -1614 -1011 -255 1174 2550 3476 3305 2402 1093 -131 -967 -1020 -302 317 830 1233 1511 1823 1020 222 -690 -1589 -1798 -1661 -1501 -1381 -1676 -1803 -1088 -227 128 1169 1474 1299 1025 423 -578 -1064 SS 20240909T220549.1Z 9018.920707 91 1 49.33 2 69.42 99.12 143.60 84.69 0.00 1 0.00 1 0 25 4.876e-02 1.258e-02 9.512e-03 1.306e-03 3.222537e-01 7.309628e-04 4.223251e-03 -6.000000e+00 3.131879e-02 229.71 -2.00 3.41 -2.00 318.94 0.00e+00 3.144425e-03 1.712883e-04 2.073318e-03 -6.000000e+00 1.426663e-03 291.18 -2.00 20.00 -2.00 318.06 0.00e+00 2.815 0.000 302.00 328.00 3 2.3206e+00 2.0290e-03 3.3304e-02 -6.0000e+00 7.7804e-02 1.8881e-02 2.3330e-03 1.9419e-02 -6.0000e+00 8.3722e-02 -9.6869e-03 1.5418e-03 8.9805e-03 -6.0000e+00 5.0095e-02 -5.8146e-03 7.8332e-04 2.2475e-03 -6.0000e+00 2.1062e-02 2.1467e-03 -3.2887e-03 4.7276e-05 3.8995e-05 -6.0000e+00 1.7118e-03 -1.1278e-01 0.0000e+00 12 8 8 10 0 0 86.28 16.41 0.43 -0.11278 -0.13749 149 33 1 5 0 331.010 20.87 15.00 16.41 36.22 7.5 978.11 900000 -18576 -7888 -12204 -12868 -10834 -17094 -14681 -18499 -16301 -17029 -16978 -7983 -8464 -1054 -4982 -1447 -46 -12 2699 1742 2742 536 -92 -729 -1687 185 -3030 -4124 -5003 -6143 -2977 -2817 -2137 -5210 -5336 -5881 -4839 -2917 -607 1459 876 1830 2081 1707 2767 1815 1772 902 489 155 487 1671 1590 2175 1031 1221 529 101 942 642 1899 2250 2993 2441 1275 695 -473 -302 664 1419 1412 1059 1030 -226 -1294 -3379 -4906 -5274 -4321 -3232 -3061 -2404 -1774 -801 183 1235 1867 2065 1744 1027 62 -965 -2041 -1902 -1534 -575 269 376 218 -397 -1255 -2073 -1790 -1486 -1301 -669 -236 998 1645 2188 2029 1278 839 -49 -564 -787 -426 285 547 902 1026 1141 658 236 -404 -1029 -1048 -1320 -1043 -954 -1163 -895 -622 25 174 545 701 623 682 71 -244 -725 900000 -789 -333 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