File name: Pandora192s1_Tokyo-Sophia_20240923_L2Fit_fwvt1c4d20230711p1-8.txt File generation date: 20240923T144638.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20240923_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20240923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0873 492.2090 492.3306 492.4523 492.5739 492.6955 492.8171 492.9386 493.0602 493.1817 493.3032 493.4247 493.5462 493.6677 493.7891 493.9106 494.0320 494.1534 494.2748 494.3961 494.5175 494.6388 494.7601 494.8815 495.0027 495.1240 495.2453 495.3665 495.4877 495.6089 495.7301 495.8513 495.9724 496.0936 496.2147 496.3358 496.4569 496.5780 496.6990 496.8201 496.9411 497.0621 497.1831 497.3041 497.4251 497.5460 497.6669 497.7878 497.9087 498.0296 498.1505 498.2713 498.3921 498.5130 498.6338 498.7545 498.8753 498.9960 499.1168 499.2375 499.3582 499.4789 499.5995 499.7202 499.8408 499.9614 500.0820 500.2026 500.3232 500.4437 500.5643 500.6848 500.8053 500.9258 501.0462 501.1667 501.2871 501.4075 501.5279 501.6483 501.7687 501.8890 502.0094 502.1297 502.2500 502.3703 502.4906 502.6108 502.7310 502.8513 502.9715 503.0917 503.2118 503.3320 503.4521 503.5722 503.6923 503.8124 503.9325 504.0526 504.1726 504.2926 504.4126 504.5326 504.6526 504.7726 504.8925 505.0124 505.1323 505.2522 505.3721 505.4920 505.6118 505.7316 505.8514 505.9712 506.0910 506.2108 506.3305 506.4502 506.5699 506.6896 506.8093 506.9290 507.0486 507.1682 507.2878 507.4074 507.5270 507.6466 507.7661 507.8856 508.0052 508.1246 508.2441 508.3636 508.4830 508.6025 508.7219 508.8413 508.9606 509.0800 509.1993 509.3187 509.4380 509.5573 509.6766 509.7958 509.9151 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240922T233012.0Z 9031.979306 317 1 50.05 2 55.65 119.70 60.05 281.74 0.00 1 0.00 1 0 15 4.831e-03 4.858e-03 1.111e-03 1.108e-03 3.732454e+03 7.224518e+01 2.514924e+02 -6.000000e+00 2.832233e+02 290.04 -2.00 20.00 -2.00 505.24 0.00e+00 5.441408e-04 3.153380e-05 3.150233e-05 -6.000000e+00 1.397024e-04 290.04 -2.00 20.00 -2.00 500.31 0.00e+00 -2.647085e-02 2.235025e-02 2.630549e-02 -6.000000e+00 9.735287e-02 228.65 -2.00 3.41 -2.00 501.93 0.00e+00 1.767 0.000 489.00 513.00 1 8.2105e+00 1.7206e-03 3.4365e-03 -6.0000e+00 7.4841e-03 9.0062e-03 4.4043e-04 6.1889e-04 -6.0000e+00 1.9413e-03 4.0989e-04 1.3375e-03 1.1443e-04 2.3068e-05 -6.0000e+00 5.1954e-04 -7.5525e-02 6.8703e-05 12 8 8 10 0 0 99.88 16.14 0.85 -0.07552 -0.06625 19 4 1 4 0 2633.700 20.56 15.01 16.14 29.06 9.2 957.78 -1022 -1068 -776 -185 -194 335 652 652 617 339 326 141 -553 -628 -740 -622 -531 132 664 118 24 295 666 623 757 856 362 95 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-27 108 54 312 302 486 899 921 708 397 250 68 204 637 368 141 375 483 -9 218 185 -281 -363 -398 -635 -170 -162 -396 -465 109 28 -146 354 295 395 117 -99 -441 -637 -585 SQ 20240922T234057.3Z 9031.986775 321 1 6.04 2 53.78 122.07 62.11 283.01 0.00 1 0.00 1 0 15 4.488e-03 4.459e-03 9.650e-05 9.631e-05 2.937257e+03 6.141770e+00 1.960334e+02 -6.000000e+00 2.631010e+02 290.04 -2.00 20.00 -2.00 505.24 0.00e+00 4.690532e-04 2.722017e-06 2.690939e-05 -6.000000e+00 1.297468e-04 290.04 -2.00 20.00 -2.00 500.40 0.00e+00 -7.857197e-02 1.928634e-03 2.146971e-02 -6.000000e+00 9.038678e-02 228.65 -2.00 3.41 -2.00 501.99 0.00e+00 1.688 0.000 489.00 513.00 1 4.8432e-01 1.4817e-04 3.0725e-03 -6.0000e+00 6.9494e-03 5.1122e-03 3.8216e-05 5.0196e-04 -6.0000e+00 1.8012e-03 9.4580e-01 1.4741e-04 1.0013e-05 2.0273e-05 -6.0000e+00 4.8270e-04 -8.5342e-02 1.7413e-04 11 8 0 10 0 0 76.15 16.15 0.81 -0.08534 -0.08432 992 218 2 4 0 5.860 20.56 15.01 16.15 30.07 9.2 962.32 -1057 -829 -509 -203 -165 439 762 676 584 388 252 -12 -442 -522 -629 -730 -483 29 237 39 198 402 382 632 729 538 499 315 -375 -699 -599 -732 -373 434 162 -107 90 156 -80 -87 64 100 272 494 597 653 577 440 182 -305 -679 -924 -1083 -722 -271 -143 -130 -62 31 253 466 530 455 494 393 233 117 -17 -234 -363 -280 -256 -87 238 73 -341 -445 -384 -420 -510 -496 -590 -541 -169 -179 -362 -229 -119 -75 -10 294 707 689 518 560 348 -98 -224 -517 -823 -861 -565 -2 73 -371 -429 -451 -434 -140 36 -44 111 317 438 588 841 873 632 442 359 123 256 534 419 157 328 229 166 371 179 -246 -296 -545 -716 -326 -91 -362 -326 0 56 110 313 320 281 152 -155 -429 -521 -564 -1025 -811 -510 -200 -166 451 795 713 617 407 261 -12 -446 -521 -624 -727 -486 30 248 41 211 429 407 674 744 550 532 332 -388 -706 -593 -727 -377 449 164 -109 91 164 -83 -90 67 104 285 499 607 665 584 461 188 -307 -669 -892 -1038 -696 -267 -145 -134 -64 32 263 483 551 453 514 406 237 117 -16 -230 -354 -271 -249 -85 235 73 -338 -434 -369 -400 -486 -475 -569 -528 -166 -178 -361 -229 -119 -75 -11 298 689 677 509 568 347 -96 -215 -486 -768 -807 -540 -2 71 -366 -422 -438 -438 -141 35 -43 110 317 440 593 851 884 640 443 355 120 247 514 405 153 318 222 161 357 172 -234 -291 -529 -695 -318 -90 -349 -319 0 56 110 314 322 283 152 -154 -418 -498 -534 SQ 20240922T234103.7Z 9031.986848 321 2 6.14 2 53.76 122.09 62.13 283.02 0.00 1 0.00 1 0 15 4.497e-03 4.497e-03 1.002e-04 1.001e-04 2.909547e+03 6.353585e+00 1.963688e+02 -6.000000e+00 2.636369e+02 290.04 -2.00 20.00 -2.00 505.25 0.00e+00 4.657852e-04 2.836587e-06 2.727826e-05 -6.000000e+00 1.300101e-04 290.04 -2.00 20.00 -2.00 500.45 0.00e+00 -6.616463e-02 2.001357e-03 2.140699e-02 -6.000000e+00 9.056994e-02 228.65 -2.00 3.41 -2.00 502.05 0.00e+00 1.687 0.000 489.00 513.00 1 5.5065e-01 1.5377e-04 3.0715e-03 -6.0000e+00 6.9635e-03 5.1006e-03 3.9677e-05 5.0242e-04 -6.0000e+00 1.8049e-03 8.8444e-01 5.1108e-05 1.0418e-05 2.0236e-05 -6.0000e+00 4.8368e-04 -8.4493e-02 1.6983e-04 11 8 0 10 0 0 81.28 16.14 0.81 -0.08449 -0.08414 992 218 2 4 0 5.860 20.56 15.00 16.14 30.07 9.2 962.32 -1031 -844 -480 -190 -125 438 776 660 617 422 261 -17 -417 -517 -644 -729 -453 30 236 54 214 428 407 639 724 571 527 343 -364 -734 -607 -750 -411 413 173 -92 129 178 -74 -76 89 135 289 498 639 660 579 447 200 -297 -692 -894 -1080 -717 -247 -126 -142 -90 17 240 471 525 435 476 368 226 107 -35 -236 -369 -284 -258 -114 232 94 -316 -431 -350 -420 -512 -469 -579 -552 -168 -187 -352 -213 -106 -53 -2 285 684 660 497 569 382 -56 -215 -538 -851 -862 -567 6 62 -376 -464 -460 -444 -136 14 -80 82 289 413 561 812 855 627 460 365 115 244 557 447 194 352 272 186 380 210 -238 -300 -546 -737 -325 -81 -382 -305 24 26 106 292 317 292 148 -137 -402 -536 -561 -975 -805 -469 -191 -129 461 790 679 635 431 263 -18 -431 -528 -654 -743 -467 30 241 56 223 444 424 664 755 596 547 352 -367 -759 -615 -763 -405 416 179 -97 134 183 -75 -77 89 137 296 514 663 687 599 456 201 -293 -698 -883 -1060 -708 -249 -124 -143 -91 18 243 476 533 443 482 371 225 104 -34 -227 -368 -282 -257 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