File name: Pandora192s1_Tokyo-Sophia_20241015_L2Fit_fwvt1c4d20230711p1-8.txt File generation date: 20241015T145037.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20241015_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20241015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0873 492.2090 492.3306 492.4523 492.5739 492.6955 492.8171 492.9386 493.0602 493.1817 493.3032 493.4247 493.5462 493.6677 493.7891 493.9106 494.0320 494.1534 494.2748 494.3961 494.5175 494.6388 494.7601 494.8815 495.0027 495.1240 495.2453 495.3665 495.4877 495.6089 495.7301 495.8513 495.9724 496.0936 496.2147 496.3358 496.4569 496.5780 496.6990 496.8201 496.9411 497.0621 497.1831 497.3041 497.4251 497.5460 497.6669 497.7878 497.9087 498.0296 498.1505 498.2713 498.3921 498.5130 498.6338 498.7545 498.8753 498.9960 499.1168 499.2375 499.3582 499.4789 499.5995 499.7202 499.8408 499.9614 500.0820 500.2026 500.3232 500.4437 500.5643 500.6848 500.8053 500.9258 501.0462 501.1667 501.2871 501.4075 501.5279 501.6483 501.7687 501.8890 502.0094 502.1297 502.2500 502.3703 502.4906 502.6108 502.7310 502.8513 502.9715 503.0917 503.2118 503.3320 503.4521 503.5722 503.6923 503.8124 503.9325 504.0526 504.1726 504.2926 504.4126 504.5326 504.6526 504.7726 504.8925 505.0124 505.1323 505.2522 505.3721 505.4920 505.6118 505.7316 505.8514 505.9712 506.0910 506.2108 506.3305 506.4502 506.5699 506.6896 506.8093 506.9290 507.0486 507.1682 507.2878 507.4074 507.5270 507.6466 507.7661 507.8856 508.0052 508.1246 508.2441 508.3636 508.4830 508.6025 508.7219 508.8413 508.9606 509.0800 509.1993 509.3187 509.4380 509.5573 509.6766 509.7958 509.9151 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241014T205323.0Z 9053.870405 142 1 49.36 2 89.68 100.81 127.13 289.06 0.00 1 0.00 1 0 40 2.312e-01 1.927e-01 1.549e-01 1.390e-01 6.017530e+03 1.008918e+04 1.851409e+02 -6.000000e+00 1.343931e+04 287.77 -2.00 20.00 -2.00 505.25 0.00e+00 -7.247541e-03 3.992702e-03 4.112256e-04 -6.000000e+00 6.671602e-03 287.77 -2.00 20.00 -2.00 500.03 0.00e+00 4.571022e+00 2.886065e+00 1.687070e-01 -6.000000e+00 4.715420e+00 226.70 -2.00 3.41 -2.00 501.73 0.00e+00 19.909 0.126 489.00 513.00 1 1.0538e+01 2.2089e-01 3.7239e-02 -6.0000e+00 3.6130e-01 4.8569e-02 5.7275e-02 3.0151e-03 -6.0000e+00 9.5293e-02 2.2574e-06 -7.1326e-03 1.3512e-02 2.0963e-04 -6.0000e+00 2.4932e-02 2.4226e-02 -1.2631e-03 12 8 8 10 0 0 99.74 15.63 13.56 0.02423 -0.02525 25 5 1 4 0 1974.190 20.56 15.00 15.63 25.62 11.2 959.26 900000 13523 -19430 23799 1420 -2424 1912 -1011 8169 -5963 7772 542 104 15244 -17400 20594 14818 -6716 8684 6056 12258 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28635 -26882 900000 12826 2621 -12620 -18722 33528 6573 24004 18220 2642 27670 5499 14965 15226 6769 4846 -3929 -3127 -5625 20515 -1424 19908 -48347 -10578 11063 -9210 33410 18903 -3483 1757 -2150 -2975 -13915 13407 36125 20399 2777 -25382 12563 -5043 4327 -7880 -5234 -4422 8381 24139 4415 14647 20816 -37318 -333 -25839 3459 -293 -9300 13340 12902 -6552 5527 28762 -1359 12062 -11819 819 27205 -6532 6157 -10475 2971 1363 -6636 24428 -5510 -21331 -11327 16875 7587 -168 23519 438 25876 6059 14181 1408 -23161 23850 -12078 14576 -10072 -9575 10563 -9893 25798 -6709 31249 9954 14159 -77730 -27880 28327 -4906 29194 28675 16673 22907 10854 SQ 20241014T205921.8Z 9053.874558 150 1 49.75 2 88.49 101.69 128.20 290.23 0.00 1 0.00 1 0 15 1.568e-01 9.293e-02 7.210e-02 6.687e-02 6.403757e+03 4.954885e+03 2.752271e+02 -6.000000e+00 9.114943e+03 287.77 -2.00 20.00 -2.00 505.33 0.00e+00 3.882852e-03 1.882992e-03 1.855968e-04 -6.000000e+00 4.508927e-03 287.77 -2.00 20.00 -2.00 500.12 0.00e+00 1.829082e+00 1.378016e+00 7.705479e-02 -6.000000e+00 3.153542e+00 226.70 -2.00 3.41 -2.00 501.77 0.00e+00 17.283 0.082 489.00 513.00 1 1.0290e+01 1.0573e-01 2.8345e-02 -6.0000e+00 2.4234e-01 1.0793e-01 2.6700e-02 2.0187e-03 -6.0000e+00 6.2769e-02 4.5934e-06 2.9821e-03 6.8363e-03 6.7149e-05 -6.0000e+00 1.6866e-02 -1.2612e-01 4.7287e-04 12 8 8 10 0 0 99.29 15.64 6.55 -0.12612 -0.10543 23 5 1 4 0 2162.500 20.56 15.00 15.64 25.67 11.2 959.32 2320 -3642 7405 8 1916 7801 -3340 -3660 -1323 8339 2897 -1520 -20328 1210 -3973 -4671 2423 4814 11402 -960 6605 2419 3040 3920 -4569 1843 12687 -3191 1703 2359 -3949 11994 -573 -1053 -9982 -21352 4973 -881 1146 8015 -17269 1643 16002 6269 6232 7615 14783 -5630 -4937 -983 12442 11913 1690 -68 8268 -12141 -1173 2662 -7428 2883 -883 -1867 -6697 10680 8351 -3733 -1003 -10424 11237 18465 -699 9204 2387 -2382 -565 -1399 -4079 -3244 -6956 8737 -4397 -8084 -11223 31118 15487 550 4871 -5879 336 4401 -1973 -8196 30009 -2544 4651 -8878 -8961 8457 128614 13181 14718 -3335 -193 6604 -3020 4054 -10376 1624 -4704 2166 8795 8792 92037 -1728 -11381 -3187 1148 7226 5097 6061 1676 -23750 689 126 -7241 -3199 1817 -6606 5453 2830 5520 -3487 893 -2964 6417 -9436 -19029 -7039 5681 2354 18808 612 2684 3827 4341 4741 -804 7809 2921 2187 -3617 6950 8 1974 7746 -3769 -4175 -1469 8306 2998 -1619 -25725 1220 -4193 -4986 2446 4853 10983 -1058 6766 2586 3237 4156 -5299 2005 12315 -3577 1773 2371 -4162 10840 -602 -1146 -12142 -28597 5198 -966 1219 7923 -21570 1753 14985 6552 6570 7925 14219 -6401 -5462 -1019 11226 10589 1619 -67 7727 -14298 -1260 2770 -8554 2992 -954 -2044 -7702 10277 8133 -4038 -1038 -11685 10012 15134 -689 8253 2314 -2445 -569 -1403 -4127 -3206 -7078 7580 -4359 -8356 -12058 22062 12919 534 4524 -6059 325 4100 -1979 -8661 22236 -2593 4326 -9015 -8870 7017 32170 10113 11184 -3044 -176 5812 -2963 3695 -10816 1492 -4616 2008 7753 7863 36980 -1747 -12755 -3313 1148 6781 4834 5602 1595 -28919 657 121 -7548 -3208 1732 -6840 4993 2644 4960 -3377 819 -2828 5639 -9877 -22303 -7428 5339 2306 15723 617 2653 3733 4179 4476 -787 6895 2696 SQ 20241014T210156.6Z 9053.876350 154 1 49.90 2 87.97 102.07 128.67 290.74 0.00 1 0.00 1 0 22 8.603e-02 7.112e-02 5.062e-02 4.967e-02 5.744889e+03 3.406242e+03 3.426621e+02 -6.000000e+00 5.000494e+03 287.77 -2.00 20.00 -2.00 505.22 0.00e+00 -5.895247e-06 1.400261e-03 5.604594e-05 -6.000000e+00 2.473214e-03 287.77 -2.00 20.00 -2.00 500.18 0.00e+00 4.087914e-02 1.010746e+00 6.839056e-02 -6.000000e+00 1.729155e+00 226.70 -2.00 3.41 -2.00 501.80 0.00e+00 15.928 0.064 489.00 513.00 1 1.0485e+01 7.7327e-02 2.5157e-02 -6.0000e+00 1.3290e-01 1.3485e-01 2.0001e-02 1.8914e-03 -6.0000e+00 3.4394e-02 5.5877e-06 -1.4096e-02 5.0140e-03 1.9165e-05 -6.0000e+00 9.2543e-03 -1.3512e-01 5.7670e-04 12 8 8 10 0 0 99.41 15.64 5.54 -0.13512 -0.23290 17 4 1 4 0 2934.430 20.56 15.00 15.64 25.70 11.2 959.34 -63 15831 -5361 -5498 -4124 1114 -3301 -384 2163 -584 -4925 -9066 1673 -5603 8376 3394 -450 -440 8497 -358 10632 -5937 3309 2388 -7451 32 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