File name: Pandora192s1_Tokyo-Sophia_20250620_L2Fit_fout2c4d20230711p1-8.txt File generation date: 20250620T145740.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v4d20230711.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250620_L1_smca1c4d20230711p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on Labanal session 3 for fieldcal First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0295 305.1706 305.3117 305.4528 305.5938 305.7349 305.8759 306.0169 306.1580 306.2990 306.4400 306.5810 306.7219 306.8629 307.0038 307.1448 307.2857 307.4266 307.5676 307.7085 307.8493 307.9902 308.1311 308.2720 308.4128 308.5536 308.6945 308.8353 308.9761 309.1169 309.2577 309.3984 309.5392 309.6800 309.8207 309.9614 310.1022 310.2429 310.3836 310.5243 310.6650 310.8056 310.9463 311.0869 311.2276 311.3682 311.5088 311.6494 311.7900 311.9306 312.0712 312.2117 312.3523 312.4928 312.6334 312.7739 312.9144 313.0549 313.1954 313.3359 313.4763 313.6168 313.7572 313.8977 314.0381 314.1785 314.3189 314.4593 314.5997 314.7401 314.8804 315.0208 315.1611 315.3014 315.4418 315.5821 315.7224 315.8627 316.0029 316.1432 316.2834 316.4237 316.5639 316.7041 316.8444 316.9846 317.1247 317.2649 317.4051 317.5453 317.6854 317.8255 317.9657 318.1058 318.2459 318.3860 318.5260 318.6661 318.8062 318.9462 319.0863 319.2263 319.3663 319.5063 319.6463 319.7863 319.9263 320.0662 320.2062 320.3461 320.4860 320.6260 320.7659 320.9058 321.0456 321.1855 321.3254 321.4652 321.6051 321.7449 321.8847 322.0245 322.1643 322.3041 322.4439 322.5837 322.7234 322.8632 323.0029 323.1426 323.2823 323.4220 323.5617 323.7014 323.8411 323.9807 324.1204 324.2600 324.3996 324.5392 324.6788 324.8184 324.9580 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250619T220915.4Z 9301.923095 263 1 49.17 2 59.54 81.63 30.29 197.73 0.00 1 0.00 1 0 17 2.586e-02 1.133e-02 3.639e-03 7.723e-04 2.748855e-01 4.324988e-04 3.404755e-03 -6.000000e+00 1.665811e-02 232.71 -2.00 3.41 -2.00 318.19 0.00e+00 1.725467e-03 7.964459e-05 1.171056e-03 -6.000000e+00 7.429455e-04 289.85 -2.00 20.00 -2.00 317.32 0.00e+00 1.964 0.000 302.00 328.00 3 2.9101e+00 1.1712e-03 2.4462e-02 -6.0000e+00 4.1712e-02 1.7432e-02 1.3207e-03 1.4976e-02 -6.0000e+00 4.4791e-02 -8.3500e-03 8.2358e-04 7.0382e-03 -6.0000e+00 2.6706e-02 -5.4026e-03 4.0896e-04 1.8532e-03 -6.0000e+00 1.1195e-02 2.8673e-03 -2.7296e-03 2.7368e-05 2.4690e-05 -6.0000e+00 8.8947e-04 -9.2345e-02 0.0000e+00 12 8 8 10 0 0 99.87 18.21 0.46 -0.09234 -0.11286 615 135 1 5 0 79.930 22.61 15.00 18.21 35.78 34.4 1036.76 900000 -2154 -1206 -3282 -4894 -9747 -8971 -8088 -5653 -4696 -7743 -7850 -7474 -4638 -2106 140 1183 246 1564 2785 2294 2256 1201 1401 592 1109 -1288 -2137 -3162 -3553 -3125 -2986 -1620 -2439 -4030 -5191 -5865 -3863 -1930 298 609 999 1346 1587 1487 1449 980 651 20 -3 -76 694 1010 1394 1139 1130 1178 497 144 -62 371 1584 2563 3080 2194 1082 -192 -791 -558 470 1321 1313 1106 681 -91 -1123 -2794 -3883 -4512 -3768 -2939 -2487 -2089 -1835 -894 -172 844 1471 1856 1705 1040 287 -935 -1735 -1956 -1159 -326 295 765 339 -101 -1045 -1614 -1561 -1308 -1140 -903 -381 422 1270 1772 1816 1375 654 -22 -545 -668 -196 277 643 851 1038 1111 756 543 -162 -640 -938 -895 -652 -588 -737 -858 -565 -215 18 434 500 501 434 106 -358 -682 900000 -142 -86 -243 -354 -693 -612 -568 -421 -376 -670 -700 -700 -470 -237 17 161 36 236 433 370 371 202 263 117 227 -276 -458 -661 -719 -630 -630 -363 -584 -1000 -1284 -1476 -1034 -584 103 239 428 607 736 700 686 465 305 9 -2 -36 339 523 761 653 669 712 306 89 -38 228 1000 1710 2186 1638 812 -139 -548 -385 340 1038 1112 974 600 -77 -904 -2091 -2718 -3100 -2697 -2303 -2156 -1975 -1855 -951 -194 909 1651 2125 1941 1146 327 -995 -1748 -1955 -1212 -370 367 934 432 -127 -1262 -2030 -1909 -1639 -1510 -1147 -507 584 1844 2702 2873 2188 1011 -32 -749 -969 -284 378 926 1281 1586 1679 1115 770 -243 -922 -1321 -1283 -984 -941 -1125 -1354 -917 -363 32 798 946 963 831 198 -654 -1217 SS 20250620T000152.4Z 9302.001301 341 1 12.59 2 36.75 98.25 43.99 238.18 0.00 1 0.00 1 0 33 1.601e-02 1.219e-02 1.372e-03 8.391e-04 1.839261e-01 4.766337e-04 2.236712e-03 -6.000000e+00 1.031298e-02 232.71 -2.00 3.41 -2.00 315.46 0.00e+00 9.852252e-04 4.522991e-05 2.628673e-04 -6.000000e+00 4.598669e-04 289.86 -2.00 20.00 -2.00 314.72 0.00e+00 1.247 0.000 302.00 328.00 3 3.4481e+00 1.2343e-03 1.5592e-02 -6.0000e+00 2.5824e-02 4.2861e-02 1.3605e-03 9.2490e-03 -6.0000e+00 2.7727e-02 -1.1613e-02 7.7785e-04 4.4628e-03 -6.0000e+00 1.6532e-02 -3.1913e-03 3.4072e-04 1.2120e-03 -6.0000e+00 6.9325e-03 3.9450e-03 -2.8653e-03 2.8867e-05 2.2280e-05 -6.0000e+00 5.5053e-04 -9.4450e-02 0.0000e+00 12 9 9 12 1 1 98.59 18.25 0.52 -0.09445 -0.11598 53 46 1 5 0 232.950 22.61 15.00 18.25 36.14 34.7 1038.69 900000 1420 849 -577 -2273 -3247 -2993 -2352 -1391 -1737 -2713 -3422 -2725 -951 274 1413 1417 1600 1992 2751 2449 2380 2173 1624 1515 1086 406 -644 -1773 -2013 -2256 -1265 -944 -1196 -3295 -4697 -4620 -3580 -1535 260 801 721 1141 924 1102 904 779 264 -239 -509 -373 267 852 1319 713 905 825 453 299 172 461 1390 2043 2433 1812 820 -233 -843 -740 465 1077 1151 947 707 310 -787 -2231 -3529 -4112 -3649 -2925 -2502 -2334 -2106 -1000 -237 787 1361 1589 1456 1035 274 -797 -1427 -1735 -998 -395 413 737 450 -48 -716 -1533 -1503 -1307 -1125 -929 -454 320 1075 1682 1855 1505 955 294 -358 -502 -171 355 590 908 1007 1181 748 494 180 -449 -607 -895 -708 -723 -743 -827 -586 -178 -59 336 489 319 365 67 -342 -758 900000 384 224 -155 -648 -863 -758 -608 -384 -518 -847 -1087 -882 -326 93 525 565 664 847 1192 1088 1072 984 748 720 536 205 -323 -859 -927 -1015 -575 -448 -593 -1678 -2368 -2331 -1923 -923 163 567 512 846 702 843 691 589 196 -187 -390 -286 210 644 1039 587 761 706 392 258 148 397 1226 1894 2377 1705 765 -222 -758 -652 425 1064 1134 970 726 309 -797 -2091 -3073 -3456 -3147 -2725 -2554 -2399 -2304 -1145 -268 935 1687 2013 1836 1260 313 -903 -1508 -1792 -1063 -452 478 915 580 -62 -873 -1779 -1825 -1523 -1387 -1207 -615 422 1470 2389 2700 2184 1333 385 -467 -626 -212 457 803 1215 1378 1605 994 672 234 -559 -733 -1092 -899 -964 -1027 -1171 -795 -250 -87 514 724 480 550 106 -527 -1143 SS 20250620T000652.3Z 9302.004772 344 1 49.16 2 35.75 99.19 44.82 239.44 0.00 1 0.00 1 0 25 1.614e-02 1.147e-02 1.521e-03 6.840e-04 1.825165e-01 3.826624e-04 2.263077e-03 -6.000000e+00 1.040060e-02 232.71 -2.00 3.41 -2.00 316.54 0.00e+00 1.142020e-03 4.631159e-05 4.846607e-04 -6.000000e+00 4.637627e-04 289.86 -2.00 20.00 -2.00 315.72 0.00e+00 1.231 0.000 302.00 328.00 3 3.5829e+00 1.0047e-03 1.5443e-02 -6.0000e+00 2.6044e-02 4.5767e-02 1.1139e-03 9.2443e-03 -6.0000e+00 2.7963e-02 -1.1032e-02 6.4328e-04 4.4345e-03 -6.0000e+00 1.6673e-02 -5.1959e-03 2.9426e-04 1.1947e-03 -6.0000e+00 6.9917e-03 3.5068e-03 -2.7410e-03 2.3868e-05 2.0597e-05 -6.0000e+00 5.5518e-04 -9.4839e-02 0.0000e+00 12 8 8 10 0 0 99.98 18.26 0.57 -0.09484 -0.11544 608 133 1 5 0 80.840 22.61 15.00 18.26 36.34 34.8 1039.88 900000 1311 433 -21 -1949 -3229 -2652 -2380 -766 -1864 -2657 -3638 -3118 -1364 -151 1035 881 1670 2028 2361 2662 1474 1871 1525 1209 1043 -137 -862 -2382 -2364 -2633 -1581 -1135 -1241 -3260 -5121 -5109 -3603 -1549 97 616 858 864 1033 1013 1080 718 71 -423 -650 -223 399 992 1092 921 836 896 471 225 99 516 1296 2086 2521 1916 919 -113 -877 -797 537 1041 1190 1070 731 160 -856 -2426 -3561 -3971 -3490 -2858 -2552 -2268 -1786 -1162 -150 885 1366 1729 1479 967 153 -797 -1507 -1792 -1095 -465 435 704 522 9 -851 -1519 -1429 -1264 -1192 -965 -458 229 1056 1549 1798 1403 849 236 -434 -512 -255 268 633 814 1023 1101 769 440 80 -427 -855 -778 -795 -555 -801 -724 -623 -149 -51 423 465 452 489 156 -362 -782 900000 231 82 -4 -360 -557 -434 -399 -136 -360 -537 -749 -656 -304 -37 275 252 493 614 732 841 477 605 501 410 366 -49 -339 -908 -854 -930 -564 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