File name: Pandora194s1_Tokyo-TMU_20230809_L2Fit_fwvt1c10d20220901p1-8.txt File generation date: 20230809T172159.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20230809_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20230809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0590 492.1806 492.3022 492.4238 492.5453 492.6669 492.7884 492.9099 493.0314 493.1529 493.2743 493.3957 493.5172 493.6386 493.7600 493.8813 494.0027 494.1240 494.2454 494.3667 494.4880 494.6092 494.7305 494.8517 494.9730 495.0942 495.2154 495.3365 495.4577 495.5788 495.7000 495.8211 495.9422 496.0632 496.1843 496.3053 496.4264 496.5474 496.6684 496.7893 496.9103 497.0312 497.1521 497.2731 497.3939 497.5148 497.6357 497.7565 497.8773 497.9981 498.1189 498.2397 498.3605 498.4812 498.6019 498.7226 498.8433 498.9640 499.0846 499.2053 499.3259 499.4465 499.5671 499.6876 499.8082 499.9287 500.0493 500.1698 500.2902 500.4107 500.5312 500.6516 500.7720 500.8924 501.0128 501.1332 501.2535 501.3738 501.4941 501.6144 501.7347 501.8550 501.9752 502.0955 502.2157 502.3359 502.4560 502.5762 502.6964 502.8165 502.9366 503.0567 503.1768 503.2968 503.4169 503.5369 503.6569 503.7769 503.8968 504.0168 504.1367 504.2567 504.3766 504.4964 504.6163 504.7362 504.8560 504.9758 505.0956 505.2154 505.3352 505.4549 505.5746 505.6944 505.8141 505.9337 506.0534 506.1730 506.2927 506.4123 506.5319 506.6514 506.7710 506.8905 507.0101 507.1296 507.2491 507.3685 507.4880 507.6074 507.7268 507.8462 507.9656 508.0850 508.2043 508.3237 508.4430 508.5623 508.6815 508.8008 508.9201 509.0393 509.1585 509.2777 509.3969 509.5160 509.6351 509.7543 509.8734 509.9925 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230808T201236.5Z 8620.842089 209 1 48.85 2 87.70 71.87 17.62 152.72 0.00 1 0.00 1 0 22 5.072e-03 4.971e-03 4.271e-04 4.243e-04 4.202038e+04 3.972299e+01 2.544706e+03 -6.000000e+00 3.068786e+02 292.12 -2.00 20.00 -2.00 505.41 0.00e+00 3.806311e-03 1.237833e-05 2.442067e-04 -6.000000e+00 1.490186e-04 292.12 -2.00 20.00 -2.00 500.48 0.00e+00 1.974628e+00 8.739388e-03 1.985923e-01 -6.000000e+00 1.035808e-01 231.58 -2.00 3.40 -2.00 502.07 0.00e+00 15.162 0.055 489.00 513.00 1 3.6881e+00 6.7138e-04 2.9029e-02 -6.0000e+00 7.9825e-03 -1.3044e-02 1.6384e-04 5.3533e-03 -6.0000e+00 2.0502e-03 4.4392e-03 1.0743e-03 3.5440e-05 1.4136e-04 -6.0000e+00 6.0048e-04 5.5360e-04 4.6259e-05 12 8 8 10 0 0 99.81 17.34 1.38 0.00055 0.00801 77 17 1 4 0 634.180 21.48 15.00 17.34 33.91 30.8 996.21 -1165 -671 -336 -45 410 627 800 673 611 428 137 -186 -396 -399 -510 -551 -165 49 76 96 135 237 360 571 567 383 216 -187 -468 -651 -741 -569 -154 130 -160 -45 -160 -92 -330 -61 1 160 375 397 605 492 395 80 -230 -677 -905 -1036 -912 -563 -261 12 93 177 210 396 555 581 427 302 168 -80 -314 -341 -573 -385 -481 -363 -68 150 -45 -209 -250 -187 113 281 431 459 586 362 119 -115 -137 181 521 858 1073 1055 1037 772 383 258 377 -16 -550 -957 -1085 -838 -463 -161 -77 -159 -235 -256 -283 -448 -700 -759 -481 -183 447 866 777 394 -289 -801 -1009 -655 75 651 835 717 362 -25 -190 -584 -826 -882 -783 -504 -274 -170 -76 313 371 421 418 363 349 510 591 326 -75 -384 -335 900000 -1083 -631 -324 -45 418 624 807 685 622 432 137 -184 -389 -388 -495 -539 -163 50 78 100 141 249 380 605 603 408 229 -197 -484 -660 -744 -575 -159 137 -166 -47 -167 -95 -339 -62 1 166 393 421 646 527 421 84 -239 -690 -903 -1063 -932 -581 -264 13 98 188 224 421 591 621 458 323 178 -84 -325 -348 -579 -384 -479 -362 -68 151 -45 -208 -244 -187 111 274 418 446 575 360 115 -111 -132 179 507 826 1031 1011 976 700 345 219 306 -14 -455 -762 -886 -717 -404 -149 -75 -151 -226 -247 -274 -438 -690 -748 -471 -178 435 855 786 406 -288 -821 -1009 -639 72 623 804 695 354 -24 -187 -573 -803 -852 -756 -492 -272 -172 -75 314 379 439 442 387 372 539 620 340 -78 -399 -349 900000 SQ 20230808T205259.5Z 8620.870133 225 1 1.38 2 79.79 77.53 15.88 184.91 0.00 1 0.00 1 0 22 3.818e-03 3.840e-03 2.647e-03 2.641e-03 1.642402e+04 2.073759e+02 1.042050e+03 -6.000000e+00 2.309666e+02 292.12 -2.00 20.00 -2.00 505.30 0.00e+00 1.164661e-03 7.650171e-05 8.795822e-05 -6.000000e+00 1.119256e-04 292.12 -2.00 20.00 -2.00 500.40 0.00e+00 5.689032e-01 5.369461e-02 9.305459e-02 -6.000000e+00 7.710380e-02 231.58 -2.00 3.40 -2.00 502.00 0.00e+00 5.404 0.002 489.00 513.00 1 4.7914e+00 4.1433e-03 1.1191e-02 -6.0000e+00 5.9566e-03 1.9792e-02 1.0231e-03 2.3183e-03 -6.0000e+00 1.5048e-03 6.9777e-03 1.3597e-03 2.7163e-04 7.4227e-05 -6.0000e+00 4.5016e-04 2.0710e-02 -1.2299e-04 12 9 1 12 1 1 999.00 17.35 0.80 0.02071 0.03014 1 18 1 4 0 605.550 21.48 15.00 17.35 35.52 30.0 999.53 -860 -55 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314 -66 81 -47 732 369 214 -194 584 -54 -297 58 54 -586 -199 -230 -59 -476 -234 -16 -10 -267 -191 88 -183 -169 -541 214 87 734 422 623 271 71 -199 394 214 515 55 165 -25 251 72 215 -241 -397 39 -556 -121 -67 167 384 -225 -93 617 75 830 150 -132 -306 198 -221 -410 -768 SQ 20230808T205646.8Z 8620.872764 228 1 40.28 2 79.04 78.05 15.95 188.09 0.00 1 0.00 1 0 22 2.782e-03 2.773e-03 4.668e-04 4.648e-04 1.566792e+04 3.696078e+01 9.968869e+02 -6.000000e+00 1.682972e+02 292.12 -2.00 20.00 -2.00 505.30 0.00e+00 1.071817e-03 1.346779e-05 8.082752e-05 -6.000000e+00 8.155808e-05 292.12 -2.00 20.00 -2.00 500.32 0.00e+00 5.901715e-01 9.502032e-03 8.931350e-02 -6.000000e+00 5.619097e-02 231.58 -2.00 3.40 -2.00 501.94 0.00e+00 5.066 0.002 489.00 513.00 1 5.2447e+00 7.3337e-04 1.0602e-02 -6.0000e+00 4.3409e-03 1.6389e-02 1.8067e-04 2.2190e-03 -6.0000e+00 1.0968e-03 4.6558e-03 1.3949e-03 4.8163e-05 6.6185e-05 -6.0000e+00 3.2805e-04 1.4703e-02 -9.6852e-05 12 1 1 12 1 1 99.99 17.35 0.84 0.01470 0.02438 90 24 1 4 0 440.420 21.48 15.00 17.35 35.77 30.4 1000.99 -665 -474 -337 -196 66 184 438 308 426 296 95 -146 -225 -300 -256 -195 -86 9 89 77 132 162 269 371 383 248 144 -147 -178 -301 -397 -309 32 176 -22 -33 72 83 2 -61 106 155 256 293 426 404 321 129 -179 -354 -474 -603 -643 -299 -195 -38 -6 4 189 239 361 349 345 200 180 101 -101 -145 -287 -198 -218 -146 -57 15 -20 -268 -212 -294 -235 -135 -312 -288 -131 17 -175 -136 -185 53 138 291 520 453 507 360 310 90 -112 -170 -390 -536 -495 -261 -177 -183 -350 -443 -361 -229 -53 -46 -94 -80 70 245 446 694 576 448 134 69 0 98 338 296 214 138 62 47 143 -125 -224 -254 -359 -261 -88 20 -61 64 188 241 253 214 231 198 46 -148 -285 -393 -455 -275 -669 -461 -336 -201 69 197 475 323 445 320 101 -154 -234 -310 -264 -202 -91 10 93 81 140 172 285 395 409 264 152 -153 -182 -315 -410 -321 32 183 -24 -35 76 87 2 -64 110 161 269 310 454 430 340 135 -183 -355 -486 -608 -645 -303 -193 -38 -7 4 196 248 375 363 359 208 185 102 -102 -143 -281 -192 -220 -141 -56 14 -19 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