File name: Pandora194s1_Tokyo-TMU_20230813_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20230813T163641.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20230813_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20230813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230812T220617.2Z 8624.921033 199 1 48.82 2 65.56 88.85 27.97 97.74 0.00 1 0.00 1 0 17 4.820e-02 1.284e-02 4.194e-02 8.362e-03 2.612270e-01 4.188236e-03 2.857377e-03 -6.000000e+00 2.762875e-02 231.45 -2.00 3.40 -2.00 318.67 0.00e+00 1.758051e-03 7.552572e-04 7.610504e-05 -6.000000e+00 1.102235e-03 292.20 -2.00 20.00 -2.00 318.30 0.00e+00 2.400 0.000 302.00 328.00 3 5.4988e+00 1.1307e-02 2.6923e-02 -6.0000e+00 6.9760e-02 3.5631e-02 1.2754e-02 1.2940e-02 -6.0000e+00 7.6021e-02 6.5222e-03 8.4973e-03 6.3215e-03 -6.0000e+00 4.4578e-02 -1.4975e-02 4.3939e-03 1.8012e-03 -6.0000e+00 1.8232e-02 1.5022e-04 9.1807e-04 2.4864e-04 1.7377e-05 -6.0000e+00 1.2927e-03 1.2765e-02 4.2644e-05 12 9 8 11 8 0 99.97 17.23 -0.31 0.01276 0.01966 41 9 1 5 0 1190.510 21.38 15.01 17.23 32.27 30.2 993.88 -8388 17413 10476 12367 -16232 -19812 -849 -24684 -7331 -13315 -1417 -16068 6463 3502 -2601 7847 295 -5023 3726 2182 6394 -6390 3614 1923 -297 -2451 -4203 -1434 -2487 -4163 4399 3413 -648 -6515 -4525 -454 -2957 6412 -197 -151 -1638 -6687 204 1617 3622 1979 687 -1014 -2087 -144 -2337 1542 3227 4424 2162 991 -28 169 819 94 844 4247 5280 3861 981 -1282 -2430 -2220 -199 2877 440 1288 2122 1384 -1928 -1424 -1604 -2899 -318 -111 -712 -2064 -1789 -3503 -603 229 -399 2114 1647 1015 60 -753 -1999 -2193 -683 -1579 446 1434 -208 -203 -2954 -1467 -1519 -763 -686 -689 -920 -955 -92 151 2023 1339 1035 441 -240 -108 79 600 886 -134 1007 2120 1059 -152 189 -759 -1063 -684 1 -22 -12 -143 -1135 -581 -559 372 209 967 224 258 -600 -794 -170 -585 1033 683 743 -1155 -1395 -52 -2159 -598 -1204 -112 -1525 556 361 -328 983 42 -782 555 343 981 -1104 576 328 -54 -474 -823 -257 -424 -719 747 638 -137 -1488 -946 -90 -660 1531 -60 -53 -640 -2870 84 665 1463 814 281 -413 -843 -58 -1017 693 1507 2145 1101 521 -15 90 426 49 458 2412 3229 2536 652 -800 -1569 -1412 -135 1947 331 995 1611 1115 -1482 -975 -1000 -1770 -202 -80 -580 -1871 -1714 -3587 -645 260 -480 2544 1981 1171 65 -739 -1829 -1992 -658 -1705 525 1846 -284 -268 -3727 -1675 -1678 -885 -862 -909 -1276 -1386 -141 245 3362 2233 1648 652 -328 -141 104 835 1325 -214 1607 3283 1609 -223 262 -1012 -1365 -902 1 -33 -19 -230 -1892 -1011 -1037 713 410 1926 448 500 -1130 -1446 -306 SS 20230812T221701.4Z 8624.928489 208 1 6.09 2 63.37 90.41 25.86 99.91 0.00 1 0.00 1 0 17 1.583e-02 8.728e-03 5.666e-03 2.202e-03 2.425958e-01 1.133555e-03 2.776840e-03 -6.000000e+00 9.234325e-03 231.45 -2.00 3.40 -2.00 316.86 0.00e+00 1.529736e-03 1.300954e-04 4.307675e-05 -6.000000e+00 3.640959e-04 292.20 -2.00 20.00 -2.00 316.55 0.00e+00 2.218 0.000 302.00 328.00 3 2.8477e+00 2.9883e-03 2.5003e-02 -6.0000e+00 2.3334e-02 -8.8246e-03 3.3128e-03 1.2176e-02 -6.0000e+00 2.5281e-02 9.7264e-03 1.9757e-03 5.9293e-03 -6.0000e+00 1.4811e-02 -1.3426e-02 9.5979e-04 1.6796e-03 -6.0000e+00 6.2294e-03 2.6414e-03 -8.3019e-05 6.2726e-05 1.7970e-05 -6.0000e+00 4.2574e-04 1.5583e-02 -9.4889e-05 12 9 1 12 1 1 72.79 17.24 0.36 0.01558 0.01496 11 22 1 5 0 492.410 21.38 15.00 17.24 32.83 30.5 994.83 -1228 579 -1650 -3309 -9142 -3860 -2311 -1053 -1406 -4150 -4034 -4126 -1365 -1547 738 -438 1334 1382 2437 1987 303 1631 -110 2444 311 43 -736 -2579 -745 -328 1953 1192 1643 -1082 -3780 -2285 -3432 -570 -1371 230 -1384 220 -459 -253 1523 -202 244 -513 -711 -23 1331 1576 1335 1647 720 734 394 224 237 134 1894 1790 2426 1969 830 -419 -1245 -551 979 845 793 1089 28 459 -334 -1053 -1395 -1949 -1645 -1302 -1382 -1717 -2157 -1503 -1144 -217 78 962 629 773 200 -773 -424 -1103 -351 -406 345 497 86 -529 -983 -1462 -1356 -387 -1021 -940 -945 -636 310 827 1201 1092 794 358 29 85 95 690 969 1294 928 823 469 428 391 -410 102 115 -72 -61 -301 -803 -606 -318 -180 -4 153 284 28 -195 -555 -386 900000 -172 87 -260 -495 -1290 -493 -307 -155 -230 -728 -696 -733 -266 -318 170 -112 349 376 684 581 92 483 -34 769 105 15 -258 -865 -230 -100 620 414 615 -423 -1417 -832 -1391 -242 -703 124 -822 134 -291 -161 955 -129 152 -314 -427 -14 839 1062 952 1141 517 537 293 166 172 98 1416 1450 2121 1705 713 -357 -995 -430 818 748 762 1081 28 437 -296 -902 -1089 -1475 -1326 -1183 -1315 -1799 -2254 -1639 -1338 -254 96 1202 785 919 234 -829 -444 -1149 -365 -469 415 656 112 -674 -1239 -1704 -1623 -458 -1319 -1205 -1268 -890 453 1215 1837 1665 1154 509 38 113 128 921 1391 1857 1355 1182 693 603 525 -559 132 153 -99 -88 -457 -1184 -912 -501 -286 -7 260 492 48 -329 -907 -608 900000 SS 20230812T222051.5Z 8624.931152 211 1 6.58 2 62.60 90.97 25.11 100.74 0.00 1 0.00 1 0 17 1.376e-02 8.610e-03 3.187e-03 1.275e-03 2.353649e-01 6.405577e-04 2.633847e-03 -6.000000e+00 7.885879e-03 231.45 -2.00 3.40 -2.00 316.89 0.00e+00 1.274173e-03 7.454294e-05 4.163081e-05 -6.000000e+00 3.146607e-04 292.20 -2.00 20.00 -2.00 316.53 0.00e+00 2.161 0.000 302.00 328.00 3 1.9782e+00 1.6901e-03 2.4252e-02 -6.0000e+00 1.9911e-02 -1.6427e-02 1.8887e-03 1.1675e-02 -6.0000e+00 2.1702e-02 1.0370e-02 1.1127e-03 5.6454e-03 -6.0000e+00 1.2725e-02 -1.4487e-02 5.2564e-04 1.5604e-03 -6.0000e+00 5.2019e-03 6.8301e-03 4.2722e-04 3.6335e-05 1.6640e-05 -6.0000e+00 3.6919e-04 1.4404e-02 -1.4561e-05 12 9 1 12 1 1 99.86 17.25 0.42 0.01440 0.01761 37 63 1 5 0 168.630 21.38 15.00 17.25 33.11 30.3 995.61 -1016 -1503 -1755 -3821 -5146 -3921 -2539 -256 -2189 -3400 -4269 -2481 -2423 -796 573 47 1306 410 1341 1542 1146 1323 1028 922 -494 -300 -1516 -1021 -1442 -142 464 1188 1870 -1774 -3614 -2999 -2249 -1088 -149 -33 -379 -385 -415 -169 832 509 120 113 -114 160 1424 1069 1493 1275 816 1066 667 272 -121 465 1242 1917 2567 2373 506 -111 -1265 -440 792 891 1019 656 443 282 -94 -1096 -2026 -1926 -1755 -1487 -1481 -1854 -2290 -1569 -781 -185 140 695 877 324 431 -583 -923 -857 -586 -327 611 532 -204 -572 -1114 -1642 -1043 -918 -1100 -931 -624 -625 360 763 1109 1036 837 485 68 90 346 732 1055 878 1155 1050 555 403 292 -410 57 395 71 -32 -454 -512 -632 -417 -213 -186 339 175 -57 -83 -271 -368 -460 -148 -240 -287 -597 -724 -520 -351 -39 -375 -616 -768 -450 -493 -167 135 12 350 115 388 462 351 401 318 301 -171 -108 -546 -344 -456 -44 151 416 703 -703 -1362 -1107 -906 -467 -76 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