File name: Pandora194s1_Tokyo-TMU_20231015_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20231016T160027.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20231015_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20231015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231015T034343.2Z 8688.155361 265 1 5.36 2 47.46 205.68 48.52 199.39 0.00 1 0.00 1 0 17 1.108e-02 8.297e-03 2.084e-03 1.258e-03 1.748710e-01 6.295088e-04 2.002772e-03 -6.000000e+00 6.258085e-03 226.72 -2.00 3.40 -2.00 315.54 0.00e+00 8.210433e-04 5.531481e-05 2.126845e-05 -6.000000e+00 2.534345e-04 287.38 -2.00 20.00 -2.00 315.23 0.00e+00 1.477 0.000 302.00 328.00 3 2.6400e+00 1.6243e-03 1.6807e-02 -6.0000e+00 1.5627e-02 -5.5672e-02 1.8147e-03 8.4865e-03 -6.0000e+00 1.7076e-02 2.6247e-02 1.0394e-03 4.1743e-03 -6.0000e+00 1.0050e-02 -1.5914e-02 4.6166e-04 1.1805e-03 -6.0000e+00 4.1623e-03 7.6350e-03 3.7950e-04 3.5427e-05 1.4089e-05 -6.0000e+00 2.9675e-04 -3.9966e-03 8.1805e-05 12 9 1 12 1 1 99.88 17.16 0.43 -0.00400 -0.00114 21 44 1 5 0 243.170 20.96 15.00 17.16 22.07 31.1 990.14 -1306 -1379 -1267 -3247 -4098 -2489 -2371 359 -235 -1326 -3128 -1618 -919 -632 630 -266 420 698 1150 1555 802 980 1575 1381 906 -181 -449 -316 -906 461 1767 1714 1909 -453 -2352 -2305 -1334 -688 147 -134 -699 -596 -570 -127 406 435 -65 -99 -171 317 1055 1022 1134 1369 733 1013 368 157 377 383 985 1841 2041 1990 313 -440 -795 -741 659 583 509 348 221 198 18 -840 -1348 -1688 -1377 -1312 -1618 -1639 -2486 -1687 -918 -672 35 383 654 384 182 -409 -661 -626 -216 -310 333 491 -92 -747 -1029 -1272 -1077 -792 -930 -836 -753 -420 112 581 1049 1084 1107 555 325 338 341 733 1061 1044 789 1024 855 644 504 -101 267 354 101 -3 -278 -675 -609 -227 -259 -247 80 105 -66 -60 -445 -659 -522 -348 -402 -377 -928 -1042 -581 -572 94 -69 -413 -972 -493 -303 -215 238 -111 179 304 515 660 350 423 681 624 431 -90 -224 -148 -427 206 806 767 912 -227 -1123 -1061 -657 -391 92 -91 -522 -463 -426 -95 303 323 -50 -75 -124 227 780 804 878 1107 611 856 318 135 319 323 853 1595 1906 1959 309 -400 -702 -630 586 552 498 356 227 196 18 -748 -1151 -1450 -1148 -1222 -1589 -1666 -2701 -1904 -1045 -780 42 479 818 463 214 -461 -677 -654 -224 -353 394 606 -120 -957 -1236 -1489 -1209 -931 -1134 -1075 -1010 -558 155 805 1508 1553 1579 732 411 425 431 922 1437 1442 1120 1436 1170 886 658 -127 332 445 129 -4 -374 -924 -845 -327 -379 -379 121 162 -102 -90 -684 -983 -770 SS 20231015T034735.4Z 8688.158049 268 1 2.09 2 47.81 206.89 48.80 200.58 0.00 1 0.00 1 0 17 1.064e-02 8.194e-03 1.208e-03 7.484e-04 1.766404e-01 3.756337e-04 2.034314e-03 -6.000000e+00 6.007979e-03 226.72 -2.00 3.40 -2.00 315.42 0.00e+00 8.045082e-04 3.225935e-05 2.017059e-05 -6.000000e+00 2.433200e-04 287.37 -2.00 20.00 -2.00 315.11 0.00e+00 1.486 0.000 302.00 328.00 3 7.1573e-01 9.6760e-04 1.6944e-02 -6.0000e+00 1.5002e-02 -5.8984e-02 1.0799e-03 8.5935e-03 -6.0000e+00 1.6394e-02 2.5056e-02 6.1856e-04 4.2291e-03 -6.0000e+00 9.6489e-03 -1.5834e-02 2.7374e-04 1.1952e-03 -6.0000e+00 3.9958e-03 5.1739e-02 2.6293e-04 2.1098e-05 1.4413e-05 -6.0000e+00 2.8491e-04 -3.6955e-03 7.0295e-05 12 9 1 12 1 1 98.71 17.16 0.42 -0.00370 -0.00172 58 307 1 5 0 34.720 20.96 15.00 17.16 22.25 31.1 989.96 -944 -1959 -1465 -3540 -3530 -2383 75 185 -156 -1489 -2920 -1953 -1130 -701 469 537 56 951 880 1302 1032 840 1489 859 538 331 232 -744 -455 721 1524 1607 1742 -659 -2506 -1852 -1420 -452 165 -125 -716 -663 -707 -421 242 325 -99 42 -274 510 1014 978 1267 1207 805 931 687 268 230 400 1183 1619 2025 1802 514 -271 -872 -723 567 428 374 234 276 97 -21 -802 -1476 -1448 -1060 -1354 -1448 -1739 -2473 -1667 -1100 -398 -82 343 611 417 389 -474 -573 -642 -366 -224 400 667 -104 -664 -1102 -1326 -1142 -528 -1064 -947 -706 -519 128 586 1061 1122 1145 691 218 467 352 823 842 977 883 883 875 428 506 -43 269 578 257 10 -314 -532 -595 -358 -314 -384 68 191 -6 -198 -433 -509 -551 -255 -586 -445 -1035 -911 -619 20 50 -47 -474 -926 -610 -382 -246 183 229 25 426 408 576 467 377 670 406 267 170 119 -363 -205 333 722 751 869 -345 -1250 -886 -730 -249 101 -89 -530 -512 -561 -336 191 256 -77 31 -198 362 746 766 1040 980 673 789 593 232 195 338 1026 1420 1910 1707 487 -248 -775 -618 507 411 373 244 288 98 -21 -723 -1270 -1241 -886 -1271 -1439 -1805 -2612 -1827 -1229 -475 -99 424 754 496 447 -521 -600 -648 -388 -248 464 813 -134 -841 -1370 -1525 -1319 -607 -1342 -1204 -936 -686 176 814 1528 1611 1562 908 274 577 438 1025 1133 1347 1249 1237 1195 585 655 -56 330 714 324 14 -422 -727 -827 -517 -462 -570 103 297 -10 -303 -644 -764 -817 SS 20231015T035147.0Z 8688.160961 271 1 49.38 2 48.21 208.18 49.12 201.85 0.00 1 0.00 1 0 17 1.230e-02 7.915e-03 1.397e-03 6.049e-04 1.783919e-01 3.003947e-04 2.024377e-03 -6.000000e+00 6.946856e-03 226.72 -2.00 3.40 -2.00 316.77 0.00e+00 1.022052e-03 3.408650e-05 2.924171e-05 -6.000000e+00 2.813294e-04 287.37 -2.00 20.00 -2.00 316.43 0.00e+00 1.498 0.000 302.00 328.00 3 2.7746e+00 7.8516e-04 1.7069e-02 -6.0000e+00 1.7347e-02 -4.7898e-02 8.8045e-04 8.6386e-03 -6.0000e+00 1.8955e-02 2.7042e-02 5.1497e-04 4.2612e-03 -6.0000e+00 1.1156e-02 -1.8498e-02 2.4157e-04 1.2187e-03 -6.0000e+00 4.6205e-03 6.4723e-03 4.4368e-04 1.7380e-05 1.3032e-05 -6.0000e+00 3.2941e-04 -4.1249e-03 7.5272e-05 11 8 0 10 0 0 99.90 17.17 0.41 -0.00412 -0.00079 326 71 1 5 0 151.450 21.06 15.00 17.17 22.44 31.2 990.69 -2158 -1918 -1625 -4473 -4437 -3727 -1522 -677 -985 -2222 -3947 -2518 -1474 -581 108 201 257 501 706 1396 1089 424 1570 886 270 -69 -676 -1282 -1080 332 1448 1727 1787 -682 -2632 -2211 -1497 -501 -13 -371 -751 -680 -633 -420 173 316 -53 250 -346 399 1179 1250 1369 1277 976 973 692 365 225 572 1437 1921 2336 2107 611 -180 -824 -579 531 593 514 397 285 410 -39 -862 -1482 -1665 -1092 -1229 -1396 -1586 -2332 -1622 -1060 -466 -37 428 731 372 265 -584 -696 -637 -485 -295 342 628 -28 -650 -1039 -1498 -1255 -576 -1039 -932 -802 -581 129 618 1034 1049 1009 580 55 252 190 714 906 941 875 883 760 363 299 -212 157 422 124 -15 -306 -415 -713 -332 -259 -294 139 185 75 -96 -326 -424 -403 -366 -356 -307 -820 -718 -558 -231 -113 -184 -442 -783 -491 -311 -137 29 58 77 153 222 450 360 139 515 305 98 -26 -255 -458 -357 104 466 590 653 -261 -961 -777 -564 -217 -7 -203 -449 -423 -404 -271 111 201 -33 150 -223 252 771 790 909 887 697 706 511 269 164 413 1063 1518 1985 1893 549 -149 -626 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