File name: Pandora194s1_Tokyo-TMU_20231130_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20231130T144103.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20231130_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20231130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231129T224340.5Z 8733.946996 293 1 4.32 2 78.46 127.41 74.41 293.09 0.00 1 0.00 1 0 41 3.843e-01 2.409e-02 3.450e-01 1.956e-02 5.613043e-01 1.013397e-02 6.097617e-03 -6.000000e+00 2.156742e-01 224.02 -2.00 3.40 -2.00 320.77 0.00e+00 7.464863e-03 3.456167e-03 3.897297e-04 -6.000000e+00 1.002399e-02 282.43 -2.00 20.00 -2.00 320.42 0.00e+00 4.835 0.002 302.00 328.00 3 3.0463e+00 2.9143e-02 5.4870e-02 -6.0000e+00 5.3519e-01 9.0761e-02 3.6426e-02 2.7898e-02 -6.0000e+00 5.8723e-01 -2.2020e-01 3.7305e-02 1.4711e-02 -6.0000e+00 3.4527e-01 9.5477e-02 1.9276e-02 4.6462e-03 -6.0000e+00 1.4420e-01 1.2366e-04 -1.8770e-03 5.7204e-04 5.2772e-05 -6.0000e+00 1.0408e-02 8.5511e-03 -1.4210e-04 12 9 9 12 1 1 999.00 18.00 0.10 0.00855 -0.00555 1 5 1 5 0 2155.310 21.69 15.00 18.00 13.81 30.7 998.14 -91809 -176732 900000 67564 -137414 900000 -84065 -62126 -122629 -158223 900000 900000 2052 -70145 -58681 8478 -66005 61030 -60361 900000 43216 32939 -35015 177699 -66284 -13487 32869 -66779 36870 17317 -807 -2683 -18321 4676 19939 29455 12261 18820 9546 28135 16445 26752 -1404 10231 70442 7968 7465 -1111 2330 26118 923 10199 4442 13433 14430 18912 -2438 -4008 7366 -2256 11130 167 4286 -3867 12341 -4530 4959 2833 -63 6785 4376 1573 2974 -1236 -68 -7932 -3112 -7282 3820 -2370 2853 -3472 760 -3236 1113 -1989 -1035 640 441 2851 -839 -4801 -4502 -3734 -1266 -623 1494 1712 2746 -1741 -2406 -386 -3138 -2816 -543 -85 -3049 -4073 1108 -1851 4235 -540 3160 1811 213 -3260 -724 38 -1046 1012 863 2558 1900 2224 -373 -962 2181 2107 1283 -153 602 -88 -1454 -2543 654 231 297 905 -593 -750 598 -515 -788 -1750 -6736 900000 1288 -3333 900000 -1602 -1184 -2974 -5757 900000 900000 39 -1944 -2013 178 -3271 1163 -3336 900000 906 753 -1602 3387 -4548 -565 877 -4709 913 561 -37 -148 -1362 294 1026 1347 724 1219 819 2359 1724 2702 -198 1326 5101 1108 1067 -178 373 3484 174 1944 974 2893 3218 4145 -674 -1115 1783 -598 2694 50 1397 -1387 4304 -1804 1749 1042 -26 2762 2002 768 1412 -578 -29 -3583 -1251 -3095 1631 -1158 1537 -2256 514 -2405 848 -1671 -908 568 391 2371 -673 -3726 -3331 -2827 -1049 -593 1471 1914 3267 -2141 -2770 -393 -3050 -2808 -573 -94 -3681 -5317 1502 -2657 6252 -869 4837 2676 301 -4583 -1094 55 -1646 1622 1372 3867 2803 3415 -565 -1411 3014 3088 1971 -266 1123 -174 -2825 -5300 1411 524 686 2112 -1395 -1691 1256 -1038 -1570 SS 20231129T224824.5Z 8733.950283 296 1 4.73 2 77.70 128.23 75.26 293.65 0.00 1 0.00 1 0 25 2.566e-01 1.407e-02 3.187e-01 1.280e-02 5.396807e-01 6.516768e-03 5.812871e-03 -6.000000e+00 1.439125e-01 224.02 -2.00 3.40 -2.00 320.58 0.00e+00 7.137520e-03 2.168077e-03 3.668513e-04 -6.000000e+00 6.044326e-03 282.43 -2.00 20.00 -2.00 320.24 0.00e+00 4.558 0.001 302.00 328.00 3 2.9057e+00 1.8469e-02 5.1952e-02 -6.0000e+00 3.5685e-01 6.7898e-04 2.3281e-02 2.6720e-02 -6.0000e+00 3.9124e-01 -4.8057e-02 2.4749e-02 1.4082e-02 -6.0000e+00 2.3023e-01 9.9698e-03 1.2850e-02 4.4283e-03 -6.0000e+00 9.5951e-02 1.8927e-04 -3.8812e-04 3.7033e-04 4.8772e-05 -6.0000e+00 6.9077e-03 8.7301e-03 -1.4450e-04 12 9 9 12 1 1 999.00 18.01 0.69 0.00873 0.00581 2 7 1 5 0 1572.120 21.69 15.02 18.01 13.93 30.6 998.31 -33428 -16692 900000 -57979 -153466 900000 -97036 14511 -44667 -61015 -75996 -72107 681 900000 -50540 36887 -57969 -27238 -30019 -37300 107039 14922 -51633 5296 -49910 11030 -29122 -10634 -41027 7849 14638 -5571 15416 -14357 -25363 2624 -11502 10391 8155 -949 6558 -1958 -4117 3539 12261 10920 12466 12030 3740 -3545 4410 10361 6027 2596 4680 2167 1503 -1855 -1902 2141 -1869 3154 6497 5906 3082 -2656 -4592 -2698 5329 4452 3153 -1285 3687 3664 2995 -4996 -7450 -3439 -4495 -726 -2157 -3522 -3062 -2350 -204 -424 -527 1270 2123 1534 -650 -288 -2457 -1416 1378 599 918 -342 2343 -1391 -670 -225 -905 365 -759 -54 -1506 -1566 -1206 911 1219 -205 1432 569 -1403 -701 -780 1374 852 -3 826 1471 -416 98 -64 702 -753 759 -46 1219 -1404 -576 -589 1019 -449 -767 540 -382 286 61 77 -38 -203 -417 -208 900000 -723 -3306 900000 -1331 181 -557 -761 -1137 -1169 8 900000 -1387 506 -2314 -883 -1086 -1535 1335 372 -2576 159 -2739 344 -1380 -411 -2149 274 566 -313 808 -1074 -2025 157 -875 752 732 -110 785 -273 -621 512 1667 1553 1788 1786 625 -676 858 2106 1391 667 1232 603 429 -544 -546 590 -564 1007 2277 2313 1164 -1021 -1930 -1141 2097 2029 1591 -702 1885 1770 1331 -2164 -3410 -1540 -2084 -383 -1336 -2492 -2329 -1876 -171 -380 -456 1109 1830 1388 -558 -229 -1908 -1127 1197 554 974 -416 2956 -1787 -792 -239 -906 374 -851 -63 -1896 -2108 -1632 1339 1941 -341 2301 874 -2063 -987 -1122 2042 1358 -5 1351 2312 -647 145 -91 1037 -1102 1075 -73 2143 -2535 -1082 -1155 2089 -932 -1664 1182 -859 633 129 166 -78 -413 SS 20231129T225302.0Z 8733.953495 299 1 10.78 2 76.96 129.03 76.09 294.20 0.00 1 0.00 1 0 25 2.547e-01 1.077e-02 1.727e-01 6.109e-03 5.102320e-01 3.083727e-03 5.562566e-03 -6.000000e+00 1.420660e-01 224.02 -2.00 3.40 -2.00 320.54 0.00e+00 5.437933e-03 1.018851e-03 3.353055e-04 -6.000000e+00 5.876515e-03 282.43 -2.00 20.00 -2.00 320.20 0.00e+00 4.320 0.001 302.00 328.00 3 2.7043e+00 8.8237e-03 4.9246e-02 -6.0000e+00 3.5258e-01 -3.8909e-02 1.0993e-02 2.5374e-02 -6.0000e+00 3.8641e-01 -1.5383e-02 1.1468e-02 1.3287e-02 -6.0000e+00 2.2802e-01 -3.2794e-03 5.9838e-03 4.1299e-03 -6.0000e+00 9.5353e-02 3.0461e-04 -6.7166e-04 1.7793e-04 4.7471e-05 -6.0000e+00 6.8253e-03 8.9450e-03 -1.4203e-04 12 9 9 12 1 1 98.98 18.01 0.37 0.00894 0.00390 10 11 1 5 0 979.200 21.69 15.02 18.01 14.11 30.6 998.31 -103310 900000 -91243 97351 -67418 -75719 -95962 -53197 -4181 -81220 -78028 -82703 -73549 -40964 -42470 -16267 -34918 -21968 -19293 -2917 18577 -7470 -709 -21071 -24206 -29038 -21398 -26200 -6145 -26127 24008 -4002 -11452 -3077 -24680 -3184 -9704 -1354 2929 -1645 -4718 -1200 919 3657 -1375 1732 1842 2824 1068 2637 -1657 7404 5073 3751 4977 2370 -114 -2077 -1433 515 5898 2358 5231 5304 1849 3612 768 338 1784 2151 743 2202 2029 748 -681 -3126 -997 -4005 -99 -746 -1551 -1532 -2180 -1802 -1925 812 256 1909 882 334 815 -360 -111 -2977 38 -1 97 900 -316 -116 -1477 -1761 -1486 -1073 -1710 -1738 -1802 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