File name: Pandora194s1_Tokyo-TMU_20231220_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240129T034044.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20231220_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231219T225706.6Z 8753.956326 73 1 49.94 2 79.08 129.51 136.22 47.42 0.00 1 0.00 1 0 17 3.993e-01 1.475e-02 2.732e-01 8.606e-03 5.632513e-01 4.505816e-03 5.950534e-03 -6.000000e+00 2.224970e-01 223.79 -2.00 3.40 -2.00 321.35 0.00e+00 9.022894e-03 1.747323e-03 5.062676e-04 -6.000000e+00 9.142490e-03 280.65 -2.00 20.00 -2.00 320.98 0.00e+00 5.086 0.002 302.00 328.00 3 3.0236e+00 1.3485e-02 5.7108e-02 -6.0000e+00 5.5187e-01 9.9991e-02 1.7968e-02 2.8322e-02 -6.0000e+00 6.0496e-01 -1.9390e-01 2.0103e-02 1.5285e-02 -6.0000e+00 3.5688e-01 7.1672e-02 1.0122e-02 4.9930e-03 -6.0000e+00 1.4831e-01 9.9956e-05 -7.1072e-04 2.6277e-04 5.9794e-05 -6.0000e+00 1.0733e-02 8.4937e-03 -2.1050e-04 12 8 8 10 0 0 99.76 17.80 0.54 0.00849 0.00315 31 7 1 5 0 1610.280 21.48 14.96 17.80 13.00 8.1 999.21 -168387 12744 -75482 -121771 -40247 -183833 -159821 -139336 -126735 48087 -30742 -121001 -110876 900000 -66579 115760 -26515 39115 -9234 -26659 -12825 -49414 36027 -48106 34208 -38692 -48091 -27684 -13954 7180 -18913 -3623 14539 2549 4896 43093 -1650 -23880 14742 -15441 14006 -13345 22948 7645 11909 12564 19477 4867 -4599 6726 5532 9197 9058 9460 16067 2693 6422 1818 3798 -1816 8537 1876 -741 12294 163 9267 -1884 3088 323 6756 1006 454 3959 -2235 8057 -3579 -949 -7989 -938 -1427 -2658 707 -2005 -1102 -1126 -1920 -549 -134 1804 1052 2410 -1484 -458 -3046 -2815 -1356 -841 1713 -269 1185 -2052 -1050 -2858 -2222 -1707 -2705 -1505 -1635 1633 820 1993 984 -119 234 -1730 -503 32 1170 -365 567 1244 251 966 170 1678 -963 574 385 262 1139 -406 177 -1090 461 -837 26 364 228 451 -341 -157 -737 -96 -3340 107 -749 -1858 -338 -4488 -3170 -2445 -2127 404 -258 -2308 -2453 900000 -1575 971 -566 477 -197 -712 -303 -1659 522 -1688 548 -1328 -1834 -845 -373 170 -693 -135 521 109 214 1266 -83 -1763 891 -1477 1105 -1478 1868 751 1149 1244 1847 551 -594 824 757 1343 1437 1604 2656 522 1218 357 714 -361 1612 422 -195 3157 49 2442 -542 868 104 2330 401 188 1555 -880 2610 -1171 -284 -2628 -326 -590 -1291 375 -1181 -680 -744 -1366 -406 -102 1331 749 1571 -937 -274 -1948 -2024 -1113 -792 1789 -306 1306 -2165 -987 -2559 -2049 -1693 -2858 -1663 -1939 2056 1159 3037 1568 -188 351 -2491 -692 45 1709 -578 921 1984 391 1448 247 2318 -1314 755 541 416 1999 -783 356 -2328 1030 -2025 66 926 592 1158 -844 -367 -1642 -211 SS 20231219T230250.1Z 8753.960302 76 1 18.12 2 78.18 130.50 135.37 48.96 0.00 1 0.00 1 0 33 2.873e-01 9.180e-03 2.085e-01 5.483e-03 5.269406e-01 2.799477e-03 5.651629e-03 -6.000000e+00 1.601026e-01 223.79 -2.00 3.40 -2.00 320.91 0.00e+00 6.103913e-03 1.015051e-03 4.133088e-04 -6.000000e+00 6.569977e-03 280.65 -2.00 20.00 -2.00 320.56 0.00e+00 4.732 0.002 302.00 328.00 3 2.3945e+00 8.2136e-03 5.3168e-02 -6.0000e+00 3.9714e-01 -3.6226e-02 1.0667e-02 2.6382e-02 -6.0000e+00 4.3530e-01 -3.0204e-02 1.1838e-02 1.4040e-02 -6.0000e+00 2.5672e-01 3.2618e-03 6.0453e-03 4.4953e-03 -6.0000e+00 1.0669e-01 2.8103e-04 -6.4357e-04 1.6321e-04 5.2883e-05 -6.0000e+00 7.6957e-03 7.9034e-03 -1.9186e-04 12 9 1 12 1 1 99.55 17.80 0.45 0.00790 0.00307 21 13 1 5 0 823.220 21.48 14.98 17.80 13.28 8.1 999.70 -88347 -92979 -85065 -96431 -141384 -43331 -83417 -48646 2694 -31409 -100618 -130764 -74926 -75075 12852 -8447 -15474 39882 -11210 8186 -27044 -2823 -20685 -30149 19363 -16429 -6745 -28146 -775 -34793 1012 -10671 13474 15935 -4399 -5067 -17755 919 -13946 4523 8762 -81 -2471 -1634 322 -6056 -2306 4351 4316 2872 5914 4185 4709 5609 -728 947 1619 2585 471 718 885 2254 6400 5027 3992 3065 1380 2848 353 955 -2430 769 912 397 265 -891 24 -3719 -1567 -1501 -1176 96 -1655 -936 -1480 -379 -389 740 1337 1261 1251 26 -1861 -1167 -1023 -894 671 798 -524 77 -811 -1105 -1900 -1088 -2196 -1477 -1209 -300 638 644 1550 719 157 -167 -647 -32 104 904 478 427 280 487 232 -176 753 -103 168 -678 665 -383 -220 117 -718 529 -207 -415 273 86 -348 60 163 -268 126 -730 -949 -868 -1078 -2268 -253 -770 -355 14 -229 -1516 -2987 -1238 -1606 158 -154 -339 554 -282 179 -868 -71 -641 -1096 456 -580 -220 -1114 -23 -1581 38 -531 605 741 -240 -276 -1215 62 -1327 423 876 -9 -313 -212 42 -868 -326 591 607 435 958 765 932 1185 -172 227 394 619 113 172 222 619 1913 1691 1398 1040 464 967 136 421 -1214 386 451 187 114 -350 9 -1428 -662 -747 -675 61 -1164 -692 -1073 -291 -314 608 1088 983 996 19 -1358 -874 -857 -783 665 895 -635 91 -897 -1107 -1801 -1064 -2349 -1655 -1428 -375 864 966 2503 1207 260 -263 -961 -46 151 1374 779 723 472 793 367 -270 1098 -146 232 -999 1086 -700 -397 219 -1423 1102 -464 -973 651 209 -844 139 358 -562 260 SS 20231219T230734.3Z 8753.963591 79 1 7.97 2 77.46 131.32 134.65 50.20 0.00 1 0.00 1 0 17 2.351e-01 9.413e-03 1.050e-01 4.127e-03 5.006943e-01 2.075354e-03 5.445681e-03 -6.000000e+00 1.310533e-01 223.79 -2.00 3.40 -2.00 320.44 0.00e+00 5.241104e-03 6.657125e-04 3.173123e-04 -6.000000e+00 5.376390e-03 280.65 -2.00 20.00 -2.00 320.10 0.00e+00 4.477 0.001 302.00 328.00 3 1.6896e+00 5.8495e-03 5.0250e-02 -6.0000e+00 3.2509e-01 -6.0940e-02 7.2633e-03 2.4774e-02 -6.0000e+00 3.5624e-01 -4.7223e-03 7.5040e-03 1.2935e-02 -6.0000e+00 2.1010e-01 -6.3962e-03 3.9299e-03 4.0229e-03 -6.0000e+00 8.7369e-02 7.4691e-04 -2.9847e-04 1.1945e-04 4.4370e-05 -6.0000e+00 6.2938e-03 5.7729e-03 -9.9284e-05 12 9 9 12 1 1 4.35 17.81 0.49 0.00577 0.00353 20 28 1 5 0 378.700 21.48 15.00 17.81 13.52 8.2 1000.30 -70252 -109468 -66314 -55563 -71121 -77516 -112039 -39185 -65859 -21146 -79287 -70967 -48819 -50960 -13512 -27251 -1701 -27050 -15812 -6644 -13548 -5950 -16515 -515 -12999 -8062 -14848 -23627 -17649 -12692 -650 -2037 2656 -6551 -7215 -7551 -1442 956 -2673 -5002 -6855 -506 -2900 1742 996 2103 1911 3320 5406 2437 5164 2538 4873 1634 2662 2145 -723 1662 -270 710 2199 4088 5480 5395 3497 -113 1161 -1458 476 652 1771 1234 765 1287 -3136 -444 -3063 -3910 -1799 -1194 369 -915 -1054 -1692 -740 174 -91 1284 573 1491 -25 -313 -2268 -1242 -1024 -789 226 652 713 -124 -1086 -2555 -1975 -855 -1096 -790 -977 -870 -54 954 1289 873 924 55 -298 -419 329 560 502 350 393 786 940 374 -92 -371 -216 163 -11 317 56 -420 -709 -591 -325 -236 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