File name: Pandora194s1_Tokyo-TMU_20240328_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240328T145232.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240328_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240328 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240327T231525.1Z 8852.969041 304 1 49.25 2 58.71 110.98 107.93 262.58 0.00 1 0.00 1 0 25 5.303e-02 9.627e-03 4.472e-02 6.421e-03 2.888798e-01 3.193721e-03 3.215908e-03 -6.000000e+00 3.000948e-02 227.75 -2.00 3.40 -2.00 319.05 0.00e+00 3.378489e-03 6.696486e-04 1.020234e-04 -6.000000e+00 1.212863e-03 281.62 -2.00 20.00 -2.00 318.70 0.00e+00 1.918 0.000 302.00 328.00 3 5.5225e+00 8.6631e-03 2.3718e-02 -6.0000e+00 7.5110e-02 -6.0504e-02 9.8582e-03 1.4153e-02 -6.0000e+00 8.2063e-02 3.1738e-02 7.1105e-03 7.0925e-03 -6.0000e+00 4.8258e-02 -2.1829e-02 3.7556e-03 2.0764e-03 -6.0000e+00 1.9907e-02 2.2577e-04 4.8530e-04 1.9260e-04 2.1335e-05 -6.0000e+00 1.4210e-03 5.5249e-03 -3.7817e-05 12 8 8 10 0 0 99.99 18.23 0.80 0.00552 0.00917 73 16 1 5 0 674.480 21.88 15.00 18.23 16.19 9.7 1005.65 16769 -9780 10663 -27050 -1775 -14556 -13573 5784 -3981 -1395 -25164 -15081 -25434 -6245 -2301 4336 3489 -933 3604 -7942 -1377 -4058 2486 -2525 3402 2346 -3840 3391 -5880 3881 -9083 2581 5996 3534 -3134 -3319 -4537 -3384 -871 1553 3303 -1982 -836 1211 -2049 371 -171 2903 -243 3625 4303 820 2290 308 -185 -414 2684 334 328 492 -1466 2449 3147 2627 181 977 -396 -454 1031 -180 1366 -508 1750 526 1011 -26 -3040 -372 -1897 -1274 -1857 -41 -3183 -1664 540 -1332 -57 -764 1476 171 988 -742 -579 -870 -1145 -370 336 1511 -193 12 -710 -1318 -578 -1612 -1269 -1257 -68 -250 248 1083 593 716 -72 625 -1287 -941 169 1024 1613 -247 1324 359 1008 -7 94 -292 226 372 -615 453 -590 -569 -629 -12 283 -150 342 261 -30 -104 206 -630 -366 601 -512 473 -1663 -76 -671 -649 254 -213 -76 -1733 -979 -2114 -508 -211 417 360 -106 410 -1058 -176 -527 307 -344 457 330 -575 450 -813 491 -1417 395 973 606 -539 -561 -850 -734 -221 447 1021 -678 -293 423 -745 133 -61 988 -84 1230 1543 328 958 139 -86 -197 1256 159 169 253 -801 1399 1955 1593 123 608 -233 -264 640 -129 1045 -411 1373 400 707 -16 -1810 -209 -1161 -882 -1458 -34 -2970 -1606 548 -1474 -65 -910 1715 193 1017 -707 -508 -759 -1080 -386 390 1919 -261 16 -875 -1497 -625 -1851 -1575 -1642 -93 -355 372 1726 999 1208 -118 937 -1808 -1256 226 1432 2414 -398 2122 569 1543 -10 132 -392 290 491 -888 694 -960 -948 -1074 -22 535 -297 693 539 -63 -209 395 -1177 -677 SS 20240328T002333.2Z 8853.016356 350 1 48.71 2 46.51 126.00 121.38 271.74 0.00 1 0.00 1 0 17 2.730e-02 1.018e-02 1.819e-02 4.607e-03 2.274895e-01 2.279445e-03 2.554898e-03 -6.000000e+00 1.546131e-02 227.76 -2.00 3.40 -2.00 317.96 0.00e+00 1.532038e-03 3.533789e-04 5.737058e-05 -6.000000e+00 6.244221e-04 281.63 -2.00 20.00 -2.00 317.62 0.00e+00 1.451 0.000 302.00 328.00 3 5.9438e+00 6.0619e-03 1.8187e-02 -6.0000e+00 3.8699e-02 -4.2208e-02 6.8134e-03 1.1068e-02 -6.0000e+00 4.2271e-02 3.2841e-02 4.3175e-03 5.5000e-03 -6.0000e+00 2.4859e-02 -2.4457e-02 2.1850e-03 1.5822e-03 -6.0000e+00 1.0261e-02 2.5552e-04 5.6866e-04 1.3603e-04 1.6030e-05 -6.0000e+00 7.3143e-04 3.7661e-03 7.3044e-05 12 8 8 10 0 0 99.98 18.43 0.80 0.00377 0.00804 25 5 1 5 0 1948.040 22.09 15.00 18.43 17.62 9.8 1013.86 666 -10397 -9533 -8990 1006 1495 5371 7070 -6614 -3241 -1162 -12494 5395 -6675 3422 -5450 5778 -536 -228 2289 -3156 5977 -2770 3304 -3141 -1101 -818 -1946 2739 -4902 617 1695 3091 -410 2020 -1268 -2068 2745 -1325 -130 -778 -1269 -994 189 2171 -756 1750 -2147 327 -1008 2055 1000 -912 1915 -1337 2855 -762 802 -1134 140 1504 2355 3160 1486 1673 -494 250 -1638 1025 898 -39 1104 -312 1087 636 -737 -1104 -3573 -1656 -861 -1405 -2221 -1464 -1554 171 353 -216 1189 1125 659 -461 -1015 -1252 -1291 -1549 -1425 -38 207 1246 -484 -1015 -2259 -1455 -329 -1153 -451 -1280 -269 -309 1508 1804 755 1153 96 115 -1152 -584 75 828 1728 775 545 81 460 -246 59 12 -9 357 -542 -390 -833 -563 -290 68 257 300 473 -107 309 -232 -231 -877 56 -1083 -1012 -896 81 112 406 586 -700 -348 -121 -1475 595 -957 507 -973 963 -98 -43 441 -656 1123 -576 677 -721 -256 -189 -473 593 -1126 141 415 807 -114 511 -323 -578 854 -514 -53 -346 -592 -476 91 1121 -402 890 -1105 160 -501 1043 549 -538 1153 -854 1779 -500 515 -729 88 975 1631 2356 1193 1322 -365 170 -1102 720 716 -34 995 -284 938 511 -539 -732 -2315 -1110 -645 -1187 -2077 -1440 -1604 186 412 -267 1491 1408 793 -517 -1038 -1172 -1181 -1514 -1538 -45 269 1678 -645 -1267 -2626 -1612 -379 -1455 -596 -1782 -386 -468 2383 2971 1140 1817 141 154 -1487 -757 102 1202 2640 1216 845 122 661 -338 77 15 -12 484 -791 -593 -1296 -891 -479 120 469 562 903 -205 574 -419 -402 -1525 SS 20240328T041502.4Z 8853.177111 505 1 49.34 2 38.25 216.96 160.35 339.01 0.00 1 0.00 1 0 17 1.233e-02 8.135e-03 7.694e-04 3.474e-04 1.879043e-01 1.734130e-04 2.140721e-03 -6.000000e+00 6.985213e-03 227.77 -2.00 3.40 -2.00 316.52 0.00e+00 1.067060e-03 1.867909e-05 3.011575e-05 -6.000000e+00 2.819806e-04 281.64 -2.00 20.00 -2.00 316.17 0.00e+00 1.272 0.000 302.00 328.00 3 2.1247e+00 4.5240e-04 1.5579e-02 -6.0000e+00 1.7485e-02 -7.0700e-02 5.0506e-04 9.1384e-03 -6.0000e+00 1.9095e-02 2.2710e-02 2.9573e-04 4.5110e-03 -6.0000e+00 1.1230e-02 -1.6273e-02 1.3827e-04 1.2752e-03 -6.0000e+00 4.6373e-03 1.5156e-02 4.5987e-04 1.0007e-05 1.4053e-05 -6.0000e+00 3.3026e-04 4.5152e-04 6.0633e-05 11 8 0 10 0 0 99.90 19.32 0.39 0.00045 0.00391 470 102 1 5 0 104.950 23.01 15.00 19.32 24.77 10.0 1053.64 -1643 -1897 -2311 -4148 -4452 -3480 -1713 -904 -696 -2391 -3625 -2861 -2151 -915 -53 209 110 577 933 1420 1033 681 1350 790 241 28 -601 -1088 -1116 212 1082 1733 1676 -662 -2622 -2269 -1647 -540 83 -211 -629 -620 -380 -422 261 351 26 144 -322 533 1173 1307 1446 1340 990 1034 675 275 271 447 1223 1834 2294 2073 510 -302 -960 -809 458 645 617 416 382 312 -104 -940 -1582 -1833 -1313 -1295 -1375 -1692 -2321 -1658 -1031 -360 20 443 725 445 337 -591 -797 -791 -477 -312 365 651 84 -545 -1089 -1535 -1264 -655 -960 -909 -746 -589 123 616 1102 1065 1024 489 33 132 232 715 877 1065 931 973 745 432 330 -169 136 305 249 48 -272 -444 -694 -315 -253 -253 91 191 3 -94 -301 -488 -512 -288 -364 -455 -781 -743 -539 -271 -158 -135 -494 -744 -584 -478 -228 -15 64 35 185 309 484 360 236 469 288 93 11 -240 -410 -390 71 373 633 656 -272 -1023 -855 -669 -230 42 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