File name: Pandora194s1_Tokyo-TMU_20240329_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240329T145501.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240329_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240329 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240329T034502.6Z 8854.156281 472 1 26.68 2 34.75 205.93 153.74 295.83 0.00 1 0.00 1 0 17 1.229e-02 8.734e-03 1.916e-03 9.665e-04 1.703162e-01 4.837035e-04 1.936246e-03 -6.000000e+00 6.971738e-03 227.84 -2.00 3.40 -2.00 316.19 0.00e+00 9.903364e-04 4.881209e-05 2.479444e-05 -6.000000e+00 2.811600e-04 281.73 -2.00 20.00 -2.00 315.87 0.00e+00 1.216 0.000 302.00 328.00 3 3.6534e+00 1.2587e-03 1.4605e-02 -6.0000e+00 1.7454e-02 -7.0624e-02 1.4052e-03 8.2693e-03 -6.0000e+00 1.9057e-02 2.5585e-02 8.1164e-04 4.0689e-03 -6.0000e+00 1.1207e-02 -1.6954e-02 3.7224e-04 1.1476e-03 -6.0000e+00 4.6305e-03 3.5887e-03 5.4667e-04 2.7759e-05 1.2926e-05 -6.0000e+00 3.2928e-04 -3.8609e-03 9.2979e-05 12 9 1 12 1 1 99.98 19.82 0.42 -0.00386 0.00025 76 31 1 5 0 346.310 23.53 15.00 19.82 23.73 10.1 1047.62 -1077 -1377 -2688 -2945 -5114 -2711 -1850 314 -52 -1349 -3522 -3280 -1407 -1035 983 346 403 391 914 1704 411 943 1081 774 216 78 -376 -917 -909 -523 1435 1973 2315 -592 -2884 -1940 -2222 -676 -228 132 -535 -421 -319 -219 189 -34 51 65 -301 257 1236 1266 1245 1329 947 1057 459 346 389 322 1144 1741 2500 2092 597 -259 -1081 -1043 250 778 478 653 214 455 -112 -782 -1482 -2026 -1284 -1403 -1431 -1611 -2208 -1721 -1099 -369 75 690 785 483 231 -629 -874 -978 -717 -436 285 625 297 -537 -916 -1692 -1519 -696 -1091 -841 -869 -637 45 664 1359 1211 1177 548 -171 -110 55 656 998 1218 1151 1012 821 679 279 -193 -34 162 146 -84 -180 -519 -814 -416 -216 -171 149 276 43 -4 -350 -474 -674 -221 -310 -625 -646 -1011 -488 -341 63 -12 -321 -839 -775 -355 -294 308 119 143 141 340 648 162 365 421 315 84 31 -151 -384 -352 -194 539 783 978 -264 -1226 -789 -978 -309 -124 83 -369 -302 -235 -162 139 -25 37 45 -202 169 840 916 945 966 707 800 355 267 295 244 888 1440 2214 1959 559 -223 -855 -866 199 698 469 668 220 451 -104 -658 -1231 -1591 -1038 -1164 -1325 -1636 -2389 -1939 -1220 -437 93 882 1004 596 263 -709 -894 -964 -743 -494 327 786 393 -699 -1119 -1924 -1796 -793 -1358 -1101 -1190 -907 61 956 2023 1799 1661 771 -221 -134 67 839 1374 1791 1613 1514 1198 948 371 -245 -41 196 188 -115 -257 -754 -1205 -639 -327 -271 243 458 72 -7 -557 -731 -1031 SS 20240329T035518.9Z 8854.163413 475 1 49.32 2 35.72 210.04 155.52 299.15 0.00 1 0.00 1 0 17 1.283e-02 8.455e-03 1.978e-03 8.443e-04 1.731676e-01 4.209815e-04 1.955469e-03 -6.000000e+00 7.272826e-03 227.84 -2.00 3.40 -2.00 316.76 0.00e+00 1.170600e-03 4.763207e-05 2.956931e-05 -6.000000e+00 2.933151e-04 281.73 -2.00 20.00 -2.00 316.40 0.00e+00 1.231 0.000 302.00 328.00 3 3.4688e+00 1.1033e-03 1.4798e-02 -6.0000e+00 1.8208e-02 -6.8130e-02 1.2338e-03 8.3829e-03 -6.0000e+00 1.9880e-02 2.6706e-02 7.2448e-04 4.1386e-03 -6.0000e+00 1.1691e-02 -1.9058e-02 3.3881e-04 1.1830e-03 -6.0000e+00 4.8302e-03 4.2251e-03 4.7373e-04 2.4549e-05 1.3054e-05 -6.0000e+00 3.4353e-04 -3.7101e-03 8.0432e-05 11 8 0 10 0 0 99.99 19.87 0.48 -0.00371 -0.00015 316 68 1 5 0 156.050 23.64 15.01 19.87 25.20 10.0 1054.78 -2758 -1465 -2044 -3371 -4647 -3936 -624 -1739 451 -2394 -3278 -3400 -2002 -948 -183 629 -364 1185 894 1407 1266 616 1524 328 638 88 -146 -1038 -1406 158 743 2225 1512 112 -2786 -2264 -2013 -620 -118 -496 -572 -772 -271 -563 310 302 -4 77 -620 377 1092 1461 1308 1306 993 907 616 69 409 104 1290 1610 2395 2352 655 -115 -1333 -783 225 892 640 554 505 426 7 -1041 -1565 -2236 -1458 -1491 -1462 -1670 -2445 -1586 -1033 -279 130 616 852 597 298 -742 -923 -1114 -761 -519 255 778 97 -414 -1127 -1613 -1547 -760 -1017 -930 -743 -601 179 726 1320 1133 1072 439 -273 -82 -113 589 743 1148 1037 1011 768 332 280 -432 -122 -41 113 -132 -356 -429 -880 -283 -257 -154 131 295 168 38 -218 -478 -432 -468 -268 -385 -605 -746 -585 -93 -290 82 -469 -635 -656 -416 -221 -48 177 -107 350 274 442 407 197 486 111 224 32 -53 -359 -451 48 233 730 534 41 -982 -767 -734 -259 -59 -287 -361 -508 -182 -383 209 203 -2 49 -382 228 683 968 912 951 743 689 477 54 310 79 1001 1336 1935 2003 558 -100 -1062 -598 180 803 573 518 473 386 6 -882 -1198 -1621 -1088 -1245 -1362 -1553 -2427 -1633 -1136 -327 160 781 1078 728 336 -765 -950 -1108 -794 -539 291 970 127 -534 -1370 -1819 -1676 -859 -1255 -1210 -1008 -849 262 1117 2102 1802 1621 614 -351 -99 -138 749 1019 1681 1558 1503 1115 463 369 -546 -160 -55 146 -181 -508 -621 -1299 -433 -418 -261 229 526 301 67 -372 -792 -708 SS 20240329T040358.9Z 8854.169432 478 1 3.41 2 36.65 213.35 156.99 302.28 0.00 1 0.00 1 0 17 1.145e-02 8.616e-03 2.189e-03 1.321e-03 1.776891e-01 6.645851e-04 2.019359e-03 -6.000000e+00 6.493500e-03 227.85 -2.00 3.40 -2.00 315.54 0.00e+00 9.195964e-04 5.819795e-05 2.184318e-05 -6.000000e+00 2.618958e-04 281.73 -2.00 20.00 -2.00 315.24 0.00e+00 1.245 0.000 302.00 328.00 3 2.5059e+00 1.7188e-03 1.5038e-02 -6.0000e+00 1.6257e-02 -6.8321e-02 1.9184e-03 8.5969e-03 -6.0000e+00 1.7750e-02 2.1309e-02 1.0975e-03 4.2315e-03 -6.0000e+00 1.0438e-02 -1.4272e-02 4.8593e-04 1.1919e-03 -6.0000e+00 4.3124e-03 1.0832e-02 3.3089e-04 3.7192e-05 1.3984e-05 -6.0000e+00 3.0674e-04 -3.4724e-03 7.1711e-05 12 9 1 12 1 1 99.96 19.92 0.37 -0.00347 -0.00099 23 75 1 5 0 141.790 23.64 15.01 19.92 26.11 10.0 1061.25 -956 -869 -1857 -3094 -4365 -2304 -1965 -256 269 -1286 -2937 -2611 -1710 -1140 681 331 232 1157 1294 2182 1028 1277 1020 1067 321 419 208 -567 -47 -91 1118 1732 1716 -250 -2248 -2432 -1861 -582 -238 -193 -872 -313 -461 -405 703 163 107 -254 -654 160 1104 1166 1364 1185 756 1150 642 474 23 621 1342 1581 2378 1934 563 -654 -1061 -1171 254 585 418 447 169 528 -188 -739 -1524 -1658 -1484 -1363 -1354 -1739 -2204 -1639 -947 -299 -251 476 753 520 420 -542 -938 -773 -531 -552 305 502 231 -474 -1072 -1395 -1408 -429 -957 -706 -791 -622 27 617 1129 1164 1199 491 70 1 156 765 951 1231 1181 1124 921 683 230 -142 -50 208 145 98 -172 -507 -543 -349 -268 -310 -31 235 5 -5 -359 -585 -749 -254 -252 -557 -884 -1114 -537 -473 -67 78 -399 -909 -802 -567 -390 257 137 99 502 579 921 448 549 443 484 154 207 103 -265 -22 -41 513 775 822 -125 -1071 -1121 -921 -330 -149 -132 -651 -242 -344 -304 521 121 83 -190 -476 115 814 916 1053 958 629 968 551 406 20 521 1155 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