File name: Pandora194s1_Tokyo-TMU_20240415_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240415T145502.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240415_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240414T210122.2Z 8870.875951 87 1 48.99 2 80.50 84.67 116.38 11.39 0.00 1 0.00 1 0 17 5.703e-01 3.347e-02 3.926e-01 1.892e-02 8.249061e-01 1.087387e-02 8.339656e-03 -6.000000e+00 3.304289e-01 229.15 -2.00 3.40 -2.00 322.20 0.00e+00 -2.287412e-04 4.472919e-03 9.167895e-04 -6.000000e+00 1.461047e-02 283.26 -2.00 20.00 -2.00 321.80 0.00e+00 5.773 0.003 302.00 328.00 3 2.9587e+00 3.4844e-02 7.0894e-02 -6.0000e+00 8.3211e-01 9.8349e-01 4.4496e-02 4.2003e-02 -6.0000e+00 9.1307e-01 -1.5838e+00 4.0671e-02 2.2841e-02 -6.0000e+00 5.3409e-01 6.4897e-01 2.1032e-02 7.5894e-03 -6.0000e+00 2.2057e-01 3.8975e-05 -1.9384e-03 5.6254e-04 9.7452e-05 -6.0000e+00 1.6129e-02 1.2819e-02 -7.9799e-05 12 8 8 10 0 0 -2.86 19.59 0.56 0.01282 -0.00175 24 5 1 5 0 2040.800 23.32 15.00 19.59 21.14 10.2 1010.76 900000 4219 900000 29142 -33792 168916 -92327 31638 43582 900000 -115610 -5069 -37068 40140 900000 7556 900000 95558 112259 78031 148155 16720 27898 65144 -4989 900000 -23404 900000 -52938 7312 17216 -53436 136401 80934 900000 -1345 900000 111196 181996 230030 85600 194256 -27963 900000 55970 137564 46436 38718 148855 26934 65818 1490 158488 50827 81568 39760 45837 80991 10726 97628 16432 36907 2820 55473 24855 18792 42323 -7270 21749 5065 27636 18036 9743 15372 -5584 28531 -17042 27990 -15542 8954 -429 -2060 4631 -9894 17168 -2359 10024 4171 6179 4770 -12622 -857 -12920 12165 -6750 -675 -3327 -1743 -3773 -7696 -540 -6088 3776 -8338 303 -2776 -40 2321 -1449 587 -2796 1979 -2064 1752 -707 -2565 603 -2696 2490 -1638 5571 1155 1814 3460 -1392 2732 -1036 3976 -1079 1462 226 -215 521 -550 1146 -1142 1301 728 48 436 -364 -1017 -3002 900000 168 900000 760 -1349 3111 -5669 583 803 900000 -10067 -153 -1800 1075 900000 367 900000 2080 2068 1960 2729 672 981 1636 -259 900000 -1372 900000 -3457 269 663 -4832 2512 2168 900000 -70 900000 2234 3352 4237 3297 3578 -3465 900000 2812 2995 2488 2269 2991 1939 3527 167 3981 4000 4917 3728 4068 5371 1221 4855 1846 3671 447 5824 3708 2908 5145 -1513 3766 1185 5600 4119 2333 3200 -1275 4099 -3641 3970 -3922 2128 -132 -740 1706 -4465 6293 -1112 4358 1959 2811 2100 -6161 -352 -5926 4661 -3618 -403 -2396 -1429 -3434 -7243 -440 -4665 2400 -6097 219 -2194 -32 2027 -1481 677 -3765 2719 -2996 2392 -948 -3421 799 -3898 3623 -2544 7829 1617 2440 4442 -1818 3316 -1288 5133 -1708 2586 448 -460 1181 -1355 2979 -3165 3575 2032 132 1129 -879 -2303 -6790 SS 20240414T211013.0Z 8870.882095 92 1 49.42 2 78.71 85.93 116.02 13.44 0.00 1 0.00 1 0 25 6.011e-01 1.543e-02 3.496e-01 7.520e-03 7.656448e-01 4.268490e-03 8.080390e-03 -6.000000e+00 3.515044e-01 229.15 -2.00 3.40 -2.00 321.81 0.00e+00 1.389143e-02 1.795986e-03 9.722458e-04 -6.000000e+00 1.547427e-02 283.26 -2.00 20.00 -2.00 321.47 0.00e+00 4.933 0.002 302.00 328.00 3 2.5235e+00 1.3636e-02 6.3567e-02 -6.0000e+00 8.8346e-01 2.6507e-01 2.0916e-02 4.1770e-02 -6.0000e+00 9.6018e-01 -4.7800e-01 2.5484e-02 2.4671e-02 -6.0000e+00 5.6110e-01 1.9061e-01 1.2276e-02 8.7077e-03 -6.0000e+00 2.3687e-01 1.4076e-04 -1.1418e-03 2.2319e-04 1.0273e-04 -6.0000e+00 1.6591e-02 1.3735e-02 -1.4639e-04 12 8 8 10 0 0 -28.75 19.59 0.64 0.01374 0.00516 57 12 1 5 0 866.760 23.32 15.00 19.59 22.02 10.2 1012.57 -118286 25538 103392 -148091 900000 -230473 900000 -176034 -170984 -237651 900000 900000 -148471 -84775 -138831 900000 -111357 -14857 429 -89539 199975 -86404 87035 -132197 13745 -57491 33217 272497 -28260 82703 -32211 47001 -28327 40931 10249 29678 16486 -30824 29303 -33465 75210 -16293 15821 15346 8709 52341 425 39703 -14093 26825 -4919 11300 27980 17834 18429 -3361 12690 -6052 9564 -406 8680 6714 6098 12504 -584 6791 1286 9387 8172 7955 9665 3267 6774 1209 501 -4363 -1852 3437 28 2268 -1603 -1465 -1992 -972 -1620 1165 2868 296 3848 -1162 1084 -4532 -2382 -1845 -3535 -1046 -2242 2112 -1044 1360 -1688 -1555 -777 -2106 -1493 -2503 -654 -2979 378 -556 1390 319 636 209 -2328 -383 -918 624 203 891 1788 1649 1314 -39 1111 -983 414 101 592 649 -495 308 -1064 526 -775 671 160 729 31 -737 132 -868 900000 -867 187 757 -1183 900000 -3530 900000 -1641 -1594 -4431 900000 900000 -1879 -790 -2959 900000 -2596 -148 4 -2147 1465 -1956 638 -4842 119 -1034 243 1996 -395 606 -686 563 -849 654 212 494 340 -1191 742 -1850 1708 -991 742 753 472 1917 27 1832 -1187 1631 -461 1010 2316 1764 1890 -438 1422 -802 1051 -49 1011 900 956 2098 -118 1259 253 1781 1760 1975 2570 953 1851 324 122 -1000 -396 738 7 699 -606 -632 -941 -480 -860 639 1622 176 2190 -665 565 -2351 -1187 -978 -2209 -756 -1928 2007 -1105 1388 -1640 -1340 -609 -1713 -1297 -2314 -631 -3190 439 -742 2027 497 987 314 -3419 -538 -1330 940 325 1448 2799 2464 1901 -56 1505 -1315 539 145 975 1215 -1032 678 -2521 1314 -1906 1690 411 1887 79 -1982 327 -2040 900000 SS 20240414T211612.6Z 8870.886257 95 1 49.28 2 77.49 86.78 115.74 14.81 0.00 1 0.00 1 0 17 4.917e-01 9.493e-03 3.140e-01 4.685e-03 6.979812e-01 2.561451e-03 7.367298e-03 -6.000000e+00 2.860423e-01 229.15 -2.00 3.40 -2.00 321.51 0.00e+00 9.543868e-03 1.043875e-03 8.136020e-04 -6.000000e+00 1.131891e-02 283.26 -2.00 20.00 -2.00 321.20 0.00e+00 4.488 0.001 302.00 328.00 3 2.3801e+00 8.0468e-03 5.7687e-02 -6.0000e+00 7.1988e-01 1.5897e-02 1.2335e-02 3.7832e-02 -6.0000e+00 7.8168e-01 -1.5231e-01 1.5284e-02 2.2279e-02 -6.0000e+00 4.5699e-01 5.5090e-02 7.4135e-03 7.8053e-03 -6.0000e+00 1.9246e-01 2.7973e-04 -3.1846e-04 1.3688e-04 8.7620e-05 -6.0000e+00 1.3412e-02 1.3092e-02 -1.3214e-04 12 9 8 11 8 0 15.69 19.60 0.55 0.01309 0.01070 87 19 1 5 0 566.370 23.32 15.00 19.60 22.61 10.2 1013.37 -219216 -108510 -240559 -71536 -140377 -13314 -118109 900000 -87262 -209933 -131898 -191654 39514 140080 -40388 1662 16405 -40605 -57956 -45764 -77389 -26844 -57907 28447 -23192 -31333 -65702 -64067 -59002 -34704 -12577 18150 15318 -7758 -16509 -11991 -49484 3532 -22804 11754 8048 12973 3528 -11233 -4659 -8560 8583 9283 12138 6834 12213 8518 788 4608 2397 3126 3831 4704 -4798 -2359 3532 856 4781 3312 7417 8286 4339 4684 373 2574 2697 3027 77 393 353 101 -2637 -4635 -1597 -1200 1062 149 -748 -256 -1179 753 58 954 554 265 -361 -469 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