File name: Pandora194s1_Tokyo-TMU_20240420_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240422T003040.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240420_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240419T220520.5Z 8875.920376 212 1 10.31 2 66.29 92.56 129.34 322.51 0.00 1 0.00 1 0 17 1.129e-01 1.303e-02 1.037e-01 9.233e-03 3.940660e-01 4.626314e-03 4.386324e-03 -6.000000e+00 6.425739e-02 229.50 -2.00 3.40 -2.00 319.39 0.00e+00 1.263843e-03 1.073867e-03 1.598373e-04 -6.000000e+00 2.581612e-03 283.75 -2.00 20.00 -2.00 319.05 0.00e+00 2.469 0.000 302.00 328.00 3 5.0738e+00 1.2657e-02 3.1480e-02 -6.0000e+00 1.6149e-01 -7.0618e-02 1.4537e-02 1.9612e-02 -6.0000e+00 1.7624e-01 2.1919e-03 1.1649e-02 9.8563e-03 -6.0000e+00 1.0350e-01 -8.5156e-03 6.2535e-03 2.8782e-03 -6.0000e+00 4.2512e-02 1.8294e-04 9.2858e-05 2.6945e-04 2.9762e-05 -6.0000e+00 3.0267e-03 8.4384e-03 -9.7310e-05 12 9 9 12 1 1 999.00 19.73 0.23 0.00844 0.00914 2 3 1 5 0 3432.850 23.43 15.01 19.73 26.75 10.4 1005.56 -21731 -9223 -33101 -8794 -25381 18376 -30600 -68274 -14001 16106 -55050 -4703 -39935 38132 7169 9245 1729 -15529 2280 -6773 6196 -15596 -1928 3229 11877 1162 22149 -4733 -5082 -148 -19921 5389 9753 1883 -3033 10757 -1337 -4234 -3637 2907 1016 -4503 1632 667 4488 645 -1872 -930 -2793 2268 -1195 10046 782 193 1867 4127 2933 -2865 1099 -1896 1004 5376 1709 1209 504 1743 2180 330 -181 1801 891 765 -870 1846 565 -3360 -3224 -2873 -2825 211 -1477 -2159 -1682 -1176 341 187 -1113 1762 354 760 -357 -1463 -2141 -625 19 568 574 1255 997 -1148 -922 -1648 -1801 -162 -1050 -1601 -797 -610 1633 518 1291 1187 537 613 -279 -1496 -1246 -129 70 -646 1121 1974 152 934 464 -748 1497 -834 306 -472 862 837 -1169 -169 -537 -495 546 991 -561 228 -37 106 -1253 -587 -249 -1192 -238 -731 331 -964 -3565 -479 435 -3073 -169 -2409 1270 387 558 121 -1384 181 -616 508 -1587 -177 302 1091 125 1934 -516 -531 -15 -2744 650 1256 273 -437 1337 -207 -801 -832 733 288 -1427 506 212 1382 208 -619 -304 -936 747 -441 3618 301 80 790 1760 1294 -1332 480 -850 455 2548 930 715 302 967 1146 177 -107 1196 651 581 -664 1307 373 -2068 -1823 -1597 -1713 143 -1160 -1901 -1579 -1061 326 191 -1214 1917 389 793 -349 -1448 -1998 -579 19 588 672 1628 1367 -1568 -1167 -1913 -1993 -185 -1310 -2114 -1098 -818 2296 800 2107 1967 865 922 -393 -2213 -1724 -186 108 -1053 1798 3061 233 1360 703 -1093 2065 -1229 453 -763 1458 1464 -2156 -302 -1028 -989 1104 2033 -1162 450 -71 192 -2288 SS 20240419T221725.0Z 8875.928762 218 1 18.88 2 63.84 94.39 130.77 325.78 0.00 1 0.00 1 0 25 6.710e-02 9.846e-03 6.638e-02 6.178e-03 3.615230e-01 3.078743e-03 3.903376e-03 -6.000000e+00 3.824526e-02 229.50 -2.00 3.40 -2.00 319.22 0.00e+00 2.100158e-03 6.825356e-04 1.465420e-04 -6.000000e+00 1.534463e-03 283.75 -2.00 20.00 -2.00 318.86 0.00e+00 2.255 0.000 302.00 328.00 3 5.1319e+00 8.4049e-03 2.8615e-02 -6.0000e+00 9.6120e-02 -6.4281e-02 9.6059e-03 1.7673e-02 -6.0000e+00 1.0485e-01 3.3670e-02 7.5215e-03 8.9205e-03 -6.0000e+00 6.1581e-02 -2.6983e-02 4.0417e-03 2.6314e-03 -6.0000e+00 2.5326e-02 2.1750e-04 1.6491e-03 1.8136e-04 2.4634e-05 -6.0000e+00 1.7979e-03 5.5875e-03 1.6848e-04 12 9 9 12 9 1 99.93 19.90 0.37 0.00559 0.01798 5 3 1 5 0 3145.470 23.64 15.01 19.90 28.48 10.5 1006.01 -1317 -7755 -8369 24339 -15334 18513 8936 -13532 -11781 -25429 -34223 -26018 14031 25209 -6713 -11905 5330 -2417 -1871 4837 4184 -4134 2371 3319 -3687 -3274 2881 -15798 -1514 -5435 5472 2911 1069 -8162 -4270 -9705 681 5760 5171 5075 1070 -2019 -2697 -1645 187 167 955 613 4896 -1665 -843 652 4040 1693 -1026 1416 -1170 891 2286 -1112 1163 1250 2424 2456 -584 -458 -1203 -2221 1394 2763 779 1171 1106 1847 819 -1784 -1396 -2333 -276 -874 -869 -2018 -1465 -1745 -1422 -845 121 613 71 764 823 -227 -1844 -1613 -176 147 1166 1736 1025 20 -1192 -1004 -1463 -1352 -408 -863 -1447 -605 315 795 1391 73 396 -317 373 -387 -335 641 689 809 1646 328 763 92 624 -280 -497 -539 602 15 -1043 -879 -409 -431 -520 -386 692 509 71 68 161 21 -264 -34 -243 -277 557 -471 390 221 -473 -454 -1195 -1773 -1317 558 1078 -469 -997 405 -211 -172 437 391 -418 231 342 -433 -400 333 -2104 -167 -635 633 388 161 -1401 -666 -1579 110 1045 1143 1318 318 -654 -915 -562 63 57 322 207 1581 -591 -319 265 1697 773 -500 691 -598 444 1099 -552 588 689 1323 1445 -354 -285 -714 -1330 880 1783 559 869 813 1284 530 -1170 -836 -1383 -174 -637 -653 -1703 -1313 -1652 -1440 -911 136 703 82 832 826 -211 -1624 -1422 -167 156 1378 2271 1301 27 -1526 -1171 -1634 -1585 -514 -1147 -2031 -813 449 1217 2245 121 627 -472 510 -557 -489 896 1033 1271 2574 507 1141 132 929 -402 -689 -778 938 23 -1732 -1501 -717 -796 -1025 -793 1328 997 140 139 315 40 -496 SS 20240419T222341.1Z 8875.933115 221 1 49.03 2 62.57 95.36 131.46 327.53 0.00 1 0.00 1 0 17 5.372e-02 7.913e-03 3.507e-02 3.519e-03 3.411668e-01 1.763167e-03 3.729059e-03 -6.000000e+00 3.059239e-02 229.50 -2.00 3.40 -2.00 319.30 0.00e+00 2.521936e-03 3.984650e-04 1.368375e-04 -6.000000e+00 1.228718e-03 283.75 -2.00 20.00 -2.00 318.94 0.00e+00 2.159 0.000 302.00 328.00 3 4.8269e+00 4.8487e-03 2.7306e-02 -6.0000e+00 7.6884e-02 -8.6396e-02 5.5436e-03 1.6793e-02 -6.0000e+00 8.3896e-02 4.5845e-02 4.3209e-03 8.4591e-03 -6.0000e+00 4.9270e-02 -3.0830e-02 2.3081e-03 2.4875e-03 -6.0000e+00 2.0245e-02 3.3514e-04 4.8485e-04 1.0446e-04 2.4056e-05 -6.0000e+00 1.4402e-03 7.5220e-03 -2.1750e-05 11 9 0 11 8 0 99.98 19.98 0.63 0.00752 0.01117 28 6 1 5 0 1750.710 23.72 15.01 19.98 29.10 10.4 1004.59 -15829 -7822 -26394 -10605 -15717 -3313 -19881 9670 -19204 -21927 -17520 -17150 -14410 -1155 8125 336 2077 -3365 889 1452 -4068 -250 -2433 -3304 1230 -8147 -3484 166 -5009 -4161 -499 359 2901 -2334 2678 -3099 -2782 -1123 408 744 -613 -870 -63 55 -2018 -535 173 -20 1811 1435 2910 2981 941 198 615 -707 -1022 1250 -153 -160 1993 2442 2760 2954 510 -128 92 330 598 1735 1165 1179 162 408 -1120 9 -1968 -2742 -1807 -1422 -482 -1827 -1152 -1521 -298 -388 449 651 625 336 409 -44 -604 -866 -444 -57 680 592 8 -409 -1170 -1014 -1648 -747 -1885 -982 -1217 -281 193 788 1376 609 527 16 -210 -292 -317 1097 1085 432 1077 982 501 86 206 -461 410 171 -130 94 -834 -590 -413 -367 -62 -75 163 -24 199 -21 97 -152 -248 -449 -232 -988 -324 -456 -82 -675 275 -817 -1016 -782 -806 -771 -65 493 25 163 -297 80 136 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