File name: Pandora194s1_Tokyo-TMU_20240509_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240511T143205.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240509_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240509T021951.9Z 8895.097129 222 1 10.62 2 18.65 165.64 18.99 122.93 0.00 1 0.00 1 0 17 1.448e-02 8.818e-03 6.388e-03 3.049e-03 1.907029e-01 1.539557e-03 2.151256e-03 -6.000000e+00 8.298522e-03 230.86 -2.00 3.40 -2.00 316.36 0.00e+00 9.335688e-04 1.596203e-04 2.986217e-05 -6.000000e+00 3.310441e-04 285.61 -2.00 20.00 -2.00 316.01 0.00e+00 1.055 0.000 302.00 328.00 3 5.0846e+00 4.0397e-03 1.4172e-02 -6.0000e+00 2.0925e-02 -6.9587e-02 4.5118e-03 9.3440e-03 -6.0000e+00 2.2795e-02 3.2195e-02 2.6111e-03 4.5862e-03 -6.0000e+00 1.3374e-02 -2.0393e-02 1.1919e-03 1.2810e-03 -6.0000e+00 5.4901e-03 9.4931e-04 7.4852e-04 8.7214e-05 1.3892e-05 -6.0000e+00 3.8798e-04 -8.8235e-04 1.4867e-04 12 9 1 12 1 1 99.99 19.42 0.50 -0.00088 0.00474 7 8 1 5 0 1324.920 23.11 15.00 19.42 23.88 11.2 1000.61 -2004 -2623 -261 -8283 -1589 -4970 2198 -211 -98 -2267 -4198 -2030 -2370 1898 -73 -1020 -243 383 167 829 2506 313 2654 1200 539 333 -950 -1035 -722 1062 2090 1115 1534 -2011 -2120 -3112 -731 -1644 20 132 -610 -577 -779 -833 -80 1029 428 208 -189 1776 938 1262 1399 1194 1238 1168 525 149 725 111 1169 1737 1733 2238 -18 -265 -1289 -746 37 774 170 775 360 165 391 -1459 -1729 -2357 -1413 -929 -1156 -1297 -2480 -1463 -991 -506 332 707 998 408 499 -628 -1156 -1423 -762 -483 203 557 -115 -20 -919 -1815 -1571 -629 -1045 -812 -696 -494 386 445 1295 924 977 548 10 305 202 979 635 1012 1073 1021 1094 90 627 65 -120 349 -154 -187 -298 111 -613 -343 -426 164 -196 202 -194 -189 -245 -519 -398 -382 -551 -55 -1778 -282 -854 365 -40 -21 -514 -954 -451 -580 505 -22 -314 -77 124 56 285 865 109 915 439 208 133 -384 -394 -253 390 789 413 606 -844 -831 -1194 -296 -783 11 78 -399 -393 -547 -591 -56 713 291 137 -121 1109 618 882 1027 920 977 937 431 122 581 89 961 1524 1517 2056 -17 -224 -1093 -608 32 692 167 788 366 162 359 -1323 -1414 -1831 -1134 -831 -1069 -1317 -2699 -1649 -1109 -605 415 908 1279 505 568 -706 -1185 -1415 -795 -552 237 713 -155 -27 -1138 -2091 -1869 -724 -1315 -1073 -961 -662 537 655 1967 1405 1411 731 14 377 252 1273 895 1416 1533 1442 1502 127 838 83 -147 429 -202 -261 -433 163 -863 -502 -664 266 -306 323 -312 -316 -396 -814 -617 SS 20240509T024939.9Z 8895.117822 237 1 9.51 2 18.31 188.17 14.47 140.01 0.00 1 0.00 1 0 9 1.538e-02 1.047e-02 9.614e-03 4.724e-03 1.904917e-01 2.387383e-03 2.151118e-03 -6.000000e+00 8.809094e-03 230.86 -2.00 3.40 -2.00 316.24 0.00e+00 8.387951e-04 2.406291e-04 2.889620e-05 -6.000000e+00 3.516894e-04 285.61 -2.00 20.00 -2.00 315.90 0.00e+00 1.053 0.000 302.00 328.00 3 5.6143e+00 6.2552e-03 1.4147e-02 -6.0000e+00 2.2212e-02 -6.7475e-02 6.9776e-03 9.3331e-03 -6.0000e+00 2.4203e-02 2.7213e-02 4.0429e-03 4.5747e-03 -6.0000e+00 1.4199e-02 -1.7699e-02 1.8431e-03 1.2743e-03 -6.0000e+00 5.8254e-03 5.6100e-04 -4.9483e-05 1.3410e-04 1.4141e-05 -6.0000e+00 4.1223e-04 1.3078e-04 -5.6721e-06 12 9 9 12 1 1 999.00 19.63 0.23 0.00013 -0.00024 2 3 1 5 0 3167.850 23.32 15.00 19.63 24.50 11.2 999.58 -1299 -139 139 -2324 -4340 1812 -4194 384 -2415 -3830 -3380 -1921 -2757 -1760 -2528 678 -321 -308 2131 1631 -477 186 2054 1153 1664 -1067 896 -3120 1714 -292 2602 1970 1863 -947 -4058 -5048 -2021 1120 -1111 1999 -627 -1086 -1540 -244 -282 1452 1724 -418 -522 1 1378 584 130 2663 892 357 1738 1422 419 571 999 1802 3302 2901 569 -727 -1351 -552 30 228 845 1141 -690 361 -281 -1274 -1053 -2750 -2331 -1663 -613 -1760 -2441 -1896 -1276 -980 -245 991 572 1052 -269 -1323 -1529 -350 -608 -461 1260 712 318 -388 -1284 -1318 -1435 -1201 -771 -706 -761 -206 -249 733 1338 602 614 865 611 632 -333 499 600 665 1742 1061 619 885 437 -360 95 679 484 48 -262 -743 -679 -139 -576 -541 420 162 189 108 -398 -255 -1334 -257 -30 30 -489 -824 303 -775 76 -544 -919 -793 -444 -705 -505 -751 213 -105 -104 724 575 -176 67 737 436 656 -447 367 -1251 606 -102 916 745 756 -404 -1669 -2032 -855 534 -649 1205 -422 -766 -1121 -176 -204 1029 1189 -285 -345 0 926 422 99 2072 724 297 1444 1180 345 468 844 1495 2915 2711 536 -633 -1174 -460 26 210 843 1182 -727 364 -265 -1090 -875 -2195 -1931 -1534 -577 -1835 -2522 -2040 -1465 -1204 -294 1213 703 1322 -316 -1421 -1610 -352 -648 -501 1488 930 408 -489 -1633 -1545 -1620 -1422 -989 -890 -1004 -281 -357 1100 1948 880 910 1177 815 797 -426 667 808 955 2530 1533 874 1189 599 -473 118 850 647 64 -363 -1053 -977 -208 -861 -846 669 265 309 172 -619 -382 -2002 SS 20240509T031038.0Z 8895.132385 243 1 49.45 2 19.47 203.24 12.26 157.92 0.00 1 0.00 1 0 17 1.294e-02 8.182e-03 2.893e-03 1.179e-03 1.927014e-01 5.930436e-04 2.161196e-03 -6.000000e+00 7.415943e-03 230.86 -2.00 3.40 -2.00 316.91 0.00e+00 1.050517e-03 6.874720e-05 3.337766e-05 -6.000000e+00 2.959292e-04 285.62 -2.00 20.00 -2.00 316.56 0.00e+00 1.060 0.000 302.00 328.00 3 4.4729e+00 1.5657e-03 1.4267e-02 -6.0000e+00 1.8699e-02 -6.7981e-02 1.7508e-03 9.4207e-03 -6.0000e+00 2.0373e-02 3.0617e-02 1.0262e-03 4.6256e-03 -6.0000e+00 1.1953e-02 -2.1045e-02 4.8165e-04 1.2975e-03 -6.0000e+00 4.9052e-03 1.7345e-03 5.3938e-04 3.3939e-05 1.3505e-05 -6.0000e+00 3.4684e-04 -3.8260e-04 8.3050e-05 11 8 0 10 0 0 99.96 19.77 0.58 -0.00038 0.00367 64 14 1 5 0 772.520 23.43 15.00 19.77 25.35 11.2 999.98 -2398 -3056 -2855 -3667 -5156 -3107 -2016 -578 217 -2593 -3934 -2519 -904 -2174 -462 359 -99 773 486 2080 696 784 1198 753 327 -443 -834 -786 -953 273 1507 1657 2329 -652 -2367 -2296 -2241 -391 157 -42 -997 -730 -697 -214 603 99 47 -73 -332 464 1049 1153 1057 1320 998 1004 332 421 344 312 1685 1769 2603 2092 691 -359 -957 -857 476 704 549 534 521 393 -19 -965 -1531 -1694 -997 -1212 -1200 -1729 -2078 -1670 -1224 -342 26 455 771 403 210 -616 -825 -859 -546 -383 506 802 244 -700 -955 -1477 -1308 -662 -1171 -864 -925 -614 104 640 1194 1086 1048 376 -88 -89 235 540 869 1073 1046 1177 560 309 358 -119 44 269 88 -26 -77 -543 -782 -317 -218 -295 133 199 38 66 -329 -488 -423 -372 -523 -499 -608 -768 -425 -283 -89 37 -478 -721 -456 -177 -490 -116 97 -28 222 145 633 219 244 375 248 113 -160 -301 -267 -300 82 467 548 821 -242 -836 -786 -830 -166 79 -23 -584 -445 -436 -135 375 61 29 -43 -210 289 678 722 696 908 706 722 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