File name: Pandora194s1_Tokyo-TMU_20240519_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240519T144449.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240519_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240518T211218.7Z 8904.883550 167 1 49.84 2 72.05 78.11 136.00 313.27 0.00 1 0.00 1 0 25 1.515e-01 1.061e-02 1.584e-01 5.133e-03 4.316215e-01 2.667577e-03 4.681121e-03 -6.000000e+00 8.838370e-02 231.46 -2.00 3.40 -2.00 320.18 0.00e+00 2.483069e-03 7.731990e-04 2.630753e-04 -6.000000e+00 3.484404e-03 286.55 -2.00 20.00 -2.00 319.87 0.00e+00 3.201 0.000 302.00 328.00 3 4.3333e+00 7.5453e-03 3.8572e-02 -6.0000e+00 2.2334e-01 -8.5983e-02 9.0647e-03 2.2095e-02 -6.0000e+00 2.4195e-01 3.6100e-02 8.8656e-03 1.1593e-02 -6.0000e+00 1.4175e-01 -2.7777e-02 4.7046e-03 3.6365e-03 -6.0000e+00 5.9634e-02 1.8286e-04 5.0003e-04 1.5377e-04 3.4491e-05 -6.0000e+00 4.0732e-03 1.4812e-02 -4.2778e-05 12 8 8 10 0 0 99.29 20.77 0.42 0.01481 0.01857 21 5 1 5 0 2373.060 24.46 15.00 20.77 27.09 11.6 1005.14 9543 -40028 -70443 -533 -33809 48868 56614 -28370 -56938 -18747 -75120 -25696 -20127 -21567 15736 -6333 1234 -33692 3233 -1612 39115 486 320 3636 -10883 652 -23281 -617 -12688 -3275 3716 19606 23638 -17624 -7991 -17377 6242 712 4822 10594 -2154 -2264 -6306 -2459 2104 -1537 -605 4871 2784 -3176 4332 1396 5052 789 415 2448 4883 -734 -2721 3393 -951 2141 4550 3554 2506 1801 326 -2537 1900 -466 1009 1471 1389 895 785 -735 -6336 -5449 -3584 -1850 -773 -1032 -179 -2134 -618 -939 1090 562 1589 1403 -114 -657 -2298 -1008 -1485 -167 811 1404 700 -138 -1630 -1366 -1241 -1114 -1251 -870 -709 -1012 1262 1046 1303 722 147 -426 -558 225 -536 443 921 523 1232 174 963 103 -154 -150 -467 -27 -17 -258 -1215 -158 -822 237 -306 150 318 -197 477 139 12 -388 900000 74 -583 -1474 -5 -431 267 309 -413 -1244 -299 -2153 -491 -440 -589 394 -228 45 -1889 134 -74 1233 23 16 184 -681 38 -1748 -36 -800 -197 236 1217 1585 -1861 -728 -1740 550 79 628 1532 -391 -437 -1326 -508 421 -325 -127 978 580 -735 1015 370 1391 242 134 798 1589 -251 -932 1094 -336 806 1863 1597 1147 782 138 -1123 890 -256 595 895 834 514 414 -354 -2991 -2547 -1821 -1072 -507 -757 -139 -1791 -550 -896 1073 570 1586 1338 -102 -546 -1832 -810 -1325 -167 911 1752 926 -180 -1991 -1514 -1312 -1237 -1505 -1098 -942 -1429 1879 1549 2056 1163 230 -630 -847 326 -800 692 1535 830 1935 295 1576 163 -233 -218 -661 -41 -27 -462 -2127 -284 -1543 465 -645 328 711 -451 1077 303 26 -778 900000 SS 20240518T220134.0Z 8904.917755 194 1 51.07 2 62.16 84.66 142.25 328.71 0.00 1 0.00 1 0 17 4.182e-02 9.684e-03 3.412e-02 4.675e-03 2.898164e-01 2.330326e-03 3.200467e-03 -6.000000e+00 2.396419e-02 231.46 -2.00 3.40 -2.00 318.90 0.00e+00 2.757443e-03 4.612729e-04 1.002804e-04 -6.000000e+00 9.561598e-04 286.55 -2.00 20.00 -2.00 318.54 0.00e+00 2.130 0.000 302.00 328.00 3 5.4291e+00 6.3317e-03 2.5608e-02 -6.0000e+00 6.0508e-02 -7.1270e-02 7.1625e-03 1.4475e-02 -6.0000e+00 6.5948e-02 3.5670e-02 5.1263e-03 7.1570e-03 -6.0000e+00 3.8670e-02 -2.4912e-02 2.7187e-03 2.0386e-03 -6.0000e+00 1.5809e-02 2.0405e-04 5.0444e-05 1.3876e-04 2.0304e-05 -6.0000e+00 1.1218e-03 1.3754e-02 -2.4292e-05 12 8 8 10 0 0 99.92 20.93 0.72 0.01375 0.01413 14 3 1 5 0 3646.830 24.65 15.00 20.93 29.49 11.7 1006.24 -20234 -10022 -11189 -1952 23535 -1315 13191 -13653 4459 -9094 -2776 -8037 -5728 -6181 -6289 4932 -1914 3612 4435 -1452 -5222 1894 8295 988 -1185 -1940 -769 -6417 -1785 8754 -260 -1199 3515 -3261 -329 -5890 -3661 2021 1759 -3631 -3586 -106 -698 -1091 -1083 981 575 -332 -822 955 3516 1379 -587 1117 1231 -444 94 -1108 662 -907 1678 3220 4331 2442 2092 -1286 213 -383 1185 1562 698 1638 -199 379 -31 -1156 -1872 -3336 -1165 -11 -1158 -1481 -1290 -1186 -1588 306 -191 1659 832 699 -129 -321 -764 -650 1 -395 296 736 -389 -205 -1862 -1382 -2029 -1093 -1534 -1156 -1171 -610 715 384 1821 715 760 413 -482 102 123 584 1214 986 860 1193 606 418 -137 -612 -197 -2 433 -886 -705 -788 -971 272 -257 76 233 18 465 229 311 -335 -649 -990 -494 -580 -87 732 -50 459 -696 232 -516 -162 -517 -415 -533 -634 497 -219 412 528 -191 -731 245 1029 139 -179 -306 -120 -1006 -254 1130 -40 -204 627 -639 -59 -1098 -734 451 473 -1199 -1292 -39 -266 -424 -423 379 221 -126 -311 362 1385 599 -276 545 617 -232 50 -587 339 -473 890 1829 2663 1632 1389 -816 125 -223 739 1104 542 1305 -160 291 -22 -746 -1110 -1950 -717 -8 -915 -1295 -1196 -1156 -1672 339 -224 1961 989 795 -136 -310 -683 -577 1 -423 351 964 -539 -276 -2366 -1604 -2280 -1284 -1964 -1552 -1649 -897 1000 578 2838 1129 1146 637 -691 138 170 850 1892 1627 1304 1946 966 638 -200 -856 -264 -3 645 -1434 -1197 -1370 -1737 460 -466 143 449 35 910 436 570 -595 -1150 SS 20240518T222434.1Z 8904.933728 209 1 48.39 2 57.49 87.83 144.38 337.26 0.00 1 0.00 1 0 17 2.542e-02 8.908e-03 1.455e-02 3.070e-03 2.562936e-01 1.538824e-03 2.818097e-03 -6.000000e+00 1.456692e-02 231.46 -2.00 3.40 -2.00 318.30 0.00e+00 1.344371e-03 2.552918e-04 7.170350e-05 -6.000000e+00 5.812116e-04 286.55 -2.00 20.00 -2.00 317.92 0.00e+00 1.854 0.000 302.00 328.00 3 5.0713e+00 4.1538e-03 2.2344e-02 -6.0000e+00 3.6780e-02 -6.4855e-02 4.6684e-03 1.2637e-02 -6.0000e+00 4.0087e-02 2.9214e-02 3.0460e-03 6.2147e-03 -6.0000e+00 2.3506e-02 -2.3629e-02 1.5530e-03 1.7678e-03 -6.0000e+00 9.6096e-03 4.0229e-04 2.7714e-04 9.0716e-05 1.7072e-05 -6.0000e+00 6.8192e-04 1.3579e-02 -3.2716e-05 11 9 0 11 8 0 99.05 21.05 0.38 0.01358 0.01566 23 5 1 5 0 2103.310 24.75 15.00 21.05 30.50 11.7 1007.40 -12522 -2743 -8179 -6180 4443 1023 10294 -8948 -365 -5595 -6270 -5032 -7512 -300 -3305 -732 -5236 1771 1629 1671 -689 1639 -328 -62 -2755 12 1894 -6731 -1039 186 228 -420 1933 -1474 -3307 -2000 -284 -836 -2020 -1118 -129 -652 471 -348 437 138 777 374 -555 1384 547 1130 1585 1158 747 1152 963 -301 1047 85 2122 2317 3314 3319 493 273 -916 -372 198 1303 818 542 539 141 -1057 -2042 -2296 -2887 -1510 -1203 -1353 -1602 -1845 -1852 -693 266 -311 1035 1178 267 294 -835 -1795 -770 -750 -518 593 1081 176 -763 -1123 -1079 -1383 -761 -1132 -765 -750 -375 316 631 1593 990 702 330 -97 -280 -245 347 492 1366 1259 840 564 273 155 -536 -233 -12 192 -520 -718 -536 -789 -172 -5 -136 42 424 145 342 47 -532 -499 -879 -193 -623 -477 275 63 610 -723 -30 -511 -571 -467 -810 -35 -456 -109 -853 281 270 288 -124 287 -60 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