File name: Pandora194s1_Tokyo-TMU_20240528_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240528T144837.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240528_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240528T014812.3Z 8914.075143 377 1 50.05 2 18.05 137.92 117.26 258.03 0.00 1 0.00 1 0 25 4.586e-02 3.632e-02 1.046e-02 5.143e-03 1.565156e-01 2.575107e-03 1.553481e-03 -6.000000e+00 2.639131e-02 231.88 -2.00 3.40 -2.00 316.64 0.00e+00 3.434980e-03 2.785561e-04 2.838238e-05 -6.000000e+00 1.048674e-03 287.41 -2.00 20.00 -2.00 316.29 0.00e+00 1.052 0.000 302.00 328.00 3 6.4856e+00 6.7681e-03 1.2748e-02 -6.0000e+00 6.6713e-02 1.5694e-02 7.5652e-03 7.1917e-03 -6.0000e+00 7.2610e-02 -1.9784e-02 4.3668e-03 3.4580e-03 -6.0000e+00 4.2566e-02 -1.9555e-03 1.9867e-03 9.6287e-04 -6.0000e+00 1.7447e-02 2.4781e-04 1.9726e-03 1.4749e-04 7.6822e-06 -6.0000e+00 1.2294e-03 -8.8069e-03 -6.9150e-05 12 8 8 10 0 0 99.20 21.22 0.58 -0.00881 0.00602 28 6 1 5 0 1787.260 24.96 15.01 21.22 31.42 12.2 992.01 -267 3168 3548 -780 -3626 -11710 -10298 -4262 -6264 -5407 -10510 -10272 -4026 -3688 1650 2088 5349 3231 6486 7837 2992 3187 1996 2533 -1114 -2243 1208 -4384 -4754 -7992 -4582 -2611 208 -2004 -7903 -13262 -9316 -2979 -959 3820 4859 4900 4477 4457 3949 4959 2142 494 -1788 -2362 -433 2054 2617 3070 2380 1471 -724 -421 -3107 -894 -254 2777 6475 6926 4383 -983 -3721 -8346 -2180 1298 2344 4749 3075 1956 -796 -5979 -8702 -12510 -11055 -6864 -2915 -2127 -2102 -1932 767 2499 3544 5019 5494 3686 1287 -3252 -7329 -7557 -7158 -3235 1443 2134 3990 541 -893 -5175 -5301 -3550 -984 -19 -155 1091 1980 3953 6120 5226 3087 542 -2447 -6542 -4309 -2119 487 3056 4890 3594 2488 615 -1422 -2630 -5517 -4696 -2522 -1128 -688 -1487 -1940 -915 867 929 1461 2237 1815 1137 294 -1592 -2614 -58 715 807 -172 -721 -2344 -2080 -884 -1442 -1267 -2501 -2435 -987 -1024 489 666 1695 1066 2132 2612 1060 1104 698 902 -422 -877 451 -1625 -1645 -2780 -1598 -946 78 -776 -3001 -5152 -3763 -1305 -487 2118 2867 2991 2815 2829 2517 3122 1350 305 -1086 -1426 -267 1304 1725 2091 1657 1041 -528 -303 -2262 -639 -187 2134 5161 5750 3637 -779 -3036 -6873 -1797 1166 2055 4216 2763 1886 -733 -5194 -6974 -9831 -8943 -5952 -2700 -2129 -2215 -2124 881 3028 4074 5851 7002 4575 1503 -3583 -7605 -7599 -7567 -3608 1695 2730 5220 711 -1110 -6200 -6150 -4276 -1256 -25 -215 1556 2923 6025 9450 8059 4594 758 -3213 -8468 -5505 -2792 676 4423 7107 5229 3559 854 -1910 -3388 -6964 -5963 -3328 -1550 -975 -2150 -2858 -1390 1375 1539 2471 3842 3136 1931 489 -2612 -4293 SS 20240528T020641.4Z 8914.087979 390 1 49.59 2 15.85 150.63 120.76 260.30 0.00 1 0.00 1 0 17 1.090e-02 8.362e-03 2.184e-03 1.258e-03 1.334044e-01 6.343858e-04 1.503898e-03 -6.000000e+00 6.260184e-03 231.88 -2.00 3.40 -2.00 315.85 0.00e+00 7.890141e-04 5.797486e-05 1.625101e-05 -6.000000e+00 2.492796e-04 287.41 -2.00 20.00 -2.00 315.51 0.00e+00 1.039 0.000 302.00 328.00 3 3.6375e+00 1.6588e-03 1.2224e-02 -6.0000e+00 1.5823e-02 -6.1595e-02 1.8467e-03 6.5927e-03 -6.0000e+00 1.7235e-02 1.8696e-02 1.0549e-03 3.1947e-03 -6.0000e+00 1.0103e-02 -1.4772e-02 4.6752e-04 8.7814e-04 -6.0000e+00 4.1303e-03 4.6726e-03 4.5497e-04 3.5863e-05 1.0087e-05 -6.0000e+00 2.9233e-04 9.8432e-03 4.2790e-05 11 8 0 10 0 0 99.89 21.31 0.42 0.00984 0.01326 39 8 2 5 0 1271.330 25.07 15.00 21.31 31.69 12.2 989.74 -835 -1562 -1449 -3216 -3485 -3053 -422 -514 618 -1789 -1917 -1370 -1617 -400 -108 84 81 536 1478 1042 1335 1207 1993 409 683 434 -205 -512 -1508 1073 1508 1495 1656 -924 -2423 -2367 -798 -867 -77 -505 -229 -1053 -644 -576 288 321 -267 239 -888 314 1439 793 1315 1047 949 609 727 322 213 520 1208 1515 2110 2113 524 -318 -992 -1039 556 641 911 427 534 360 -284 -786 -1474 -1636 -1403 -1098 -1511 -1569 -2419 -1510 -812 -279 -66 603 589 146 128 -629 -585 -705 -698 -225 266 757 -64 -442 -1184 -1567 -1291 -713 -1182 -817 -690 -742 309 573 1244 1099 857 425 -157 -23 175 633 1015 1101 1210 1030 816 364 496 -97 233 164 111 72 -222 -273 -877 -261 -319 -264 228 258 70 -254 -281 -630 -635 -222 -448 -418 -874 -833 -682 -96 -130 170 -523 -544 -384 -491 -134 -40 33 33 219 613 446 579 517 854 185 321 210 -99 -230 -630 420 603 628 736 -424 -1046 -995 -360 -455 -47 -329 -160 -770 -479 -431 212 235 -190 163 -586 223 1047 559 963 800 739 482 581 257 167 408 978 1311 1945 2030 496 -274 -783 -871 445 579 891 436 543 355 -262 -654 -1217 -1274 -1136 -988 -1377 -1557 -2551 -1653 -949 -349 -80 744 725 188 152 -677 -569 -664 -693 -243 315 976 -87 -580 -1461 -1801 -1440 -840 -1522 -1103 -971 -995 427 831 1850 1616 1190 592 -201 -27 213 810 1404 1629 1680 1547 1194 510 658 -123 279 199 144 97 -313 -389 -1273 -393 -469 -405 358 414 113 -403 -433 -946 -948 SS 20240528T021139.2Z 8914.091426 393 1 14.41 2 15.38 154.56 121.71 260.92 0.00 1 0.00 1 0 17 1.063e-02 8.495e-03 1.135e-03 7.757e-04 1.322895e-01 3.972305e-04 1.482943e-03 -6.000000e+00 6.105469e-03 231.88 -2.00 3.40 -2.00 314.98 0.00e+00 7.920636e-04 3.056247e-05 1.329827e-05 -6.000000e+00 2.431149e-04 287.41 -2.00 20.00 -2.00 314.67 0.00e+00 1.037 0.000 302.00 328.00 3 3.0789e+00 1.0321e-03 1.2151e-02 -6.0000e+00 1.5432e-02 -6.6480e-02 1.1456e-03 6.4934e-03 -6.0000e+00 1.6809e-02 1.9503e-02 6.5190e-04 3.1443e-03 -6.0000e+00 9.8534e-03 -1.3208e-02 2.7915e-04 8.6559e-04 -6.0000e+00 4.0283e-03 8.2121e-03 3.6865e-04 2.1815e-05 1.0461e-05 -6.0000e+00 2.8510e-04 9.8883e-03 4.8283e-05 12 9 1 12 1 1 98.33 21.32 0.45 0.00989 0.01266 56 42 1 5 0 252.580 25.07 15.00 21.32 32.05 12.3 991.87 -556 -1342 -1271 -3423 -3179 -2450 -129 815 715 -1364 -2454 -1813 -1369 -85 596 238 536 1034 1242 1543 947 1056 1559 974 645 228 -204 -524 -818 580 1401 1854 1818 -726 -2442 -2003 -1506 -491 -38 -272 -570 -433 -578 -351 70 105 -219 -228 -528 415 1091 1191 1218 1110 689 969 487 207 272 608 1130 1547 2165 1766 381 -487 -1278 -951 346 451 460 256 523 399 -30 -689 -1493 -1956 -1394 -1386 -1504 -1852 -2270 -1551 -1012 -367 58 569 620 264 309 -610 -606 -580 -536 -202 421 481 -55 -585 -971 -1437 -1098 -560 -962 -963 -745 -492 188 677 1150 1051 1127 593 77 184 266 794 1002 1164 1079 1170 854 579 341 -112 153 369 246 -30 -343 -518 -743 -341 -218 -271 5 130 55 -155 -399 -622 -648 -191 -498 -474 -1210 -983 -705 -38 263 255 -515 -907 -660 -537 -37 260 111 255 497 612 779 489 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