File name: Pandora194s1_Tokyo-TMU_20240612_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240612T145057.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240612_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240611T202318.3Z 8928.849518 62 1 50.04 2 80.39 68.33 126.13 20.06 0.00 1 0.00 1 0 17 6.006e-01 2.613e-02 3.685e-01 1.617e-02 7.808343e-01 9.537671e-03 8.260641e-03 -6.000000e+00 3.604505e-01 232.57 -2.00 3.40 -2.00 322.02 0.00e+00 2.165919e-02 3.951318e-03 9.650531e-04 -6.000000e+00 1.483044e-02 288.80 -2.00 20.00 -2.00 321.68 0.00e+00 5.707 0.003 302.00 328.00 3 2.7582e+00 3.0665e-02 7.0285e-02 -6.0000e+00 9.1604e-01 8.1879e-01 3.9244e-02 4.1549e-02 -6.0000e+00 9.9614e-01 -1.2690e+00 3.9253e-02 2.2605e-02 -6.0000e+00 5.7593e-01 5.2881e-01 1.9944e-02 7.6764e-03 -6.0000e+00 2.3870e-01 4.8704e-05 -2.4678e-03 4.9189e-04 1.0178e-04 -6.0000e+00 1.6617e-02 1.7257e-02 -1.7399e-04 12 8 8 10 0 0 63.85 20.66 0.71 0.01726 -0.00129 28 6 1 5 0 1786.710 24.35 15.01 20.66 29.90 13.5 999.29 -67615 -36028 900000 62648 -38093 -113505 900000 -112830 900000 -71643 -83590 198065 -133679 -66557 175622 303873 153723 73739 300 -3857 101236 -92610 900000 -39626 26295 900000 -58188 279114 -31986 -51626 -35331 157826 73198 900000 67712 61304 53295 -2815 56326 17823 900000 20244 65109 110590 27268 25770 4049 18124 24687 56713 39848 33598 51615 -3132 64354 25074 61672 45772 8093 18578 13399 39581 11739 53033 1337 12654 19168 22461 26879 -3336 13697 8682 6741 6277 4323 11448 -14986 1778 4868 7543 -5769 6362 -2392 148 320 -3508 -1524 -1699 -443 3643 2753 2398 -5195 -5680 -6235 -4688 -3233 997 916 745 -3275 -1201 -1845 -6956 -1866 -3519 -3859 -4076 -994 -757 384 772 -1199 176 -2925 -1809 -266 2204 2569 2732 4135 859 1481 -32 1483 102 2495 1650 896 1548 -861 68 -721 -607 -517 458 577 -30 1079 -972 -840 -1240 900000 -2129 -945 900000 986 -800 -4318 900000 -3876 900000 -1435 -1795 3118 -7079 -2477 2765 4784 2420 1266 11 -149 1594 -7555 900000 -1645 527 900000 -2498 4394 -1053 -2364 -1719 2485 1676 900000 1551 1404 1373 -141 1774 918 900000 1130 2423 2691 1561 1549 313 1271 1696 3003 2737 2693 3694 -408 4329 2476 4563 3819 943 1930 1540 3926 1774 6011 267 2211 3108 3642 4612 -882 3299 2242 1708 1473 926 2037 -3303 350 1088 1995 -2052 2283 -1017 65 148 -1790 -799 -915 -234 1772 1257 1031 -2355 -2763 -3543 -3129 -2520 865 865 701 -2970 -947 -1339 -5410 -1484 -3003 -3517 -4049 -1075 -934 525 1115 -1775 250 -4079 -2441 -364 3120 3850 4194 6100 1249 2069 -44 1942 131 3102 2262 1439 2819 -1774 148 -1684 -1514 -1380 1258 1611 -84 2981 -2592 -2078 -2872 900000 SS 20240611T203151.6Z 8928.855458 67 1 49.77 2 78.77 69.46 125.55 22.38 0.00 1 0.00 1 0 17 5.449e-01 1.949e-02 3.425e-01 1.077e-02 7.056296e-01 6.111868e-03 7.461247e-03 -6.000000e+00 3.210107e-01 232.57 -2.00 3.40 -2.00 321.74 0.00e+00 1.767970e-02 2.446638e-03 7.951786e-04 -6.000000e+00 1.323093e-02 288.80 -2.00 20.00 -2.00 321.40 0.00e+00 4.954 0.002 302.00 328.00 3 3.0687e+00 1.9264e-02 6.1801e-02 -6.0000e+00 8.1438e-01 3.9419e-01 2.6118e-02 3.7787e-02 -6.0000e+00 8.8280e-01 -6.6297e-01 2.8843e-02 2.0895e-02 -6.0000e+00 5.1645e-01 2.7443e-01 1.4258e-02 7.0584e-03 -6.0000e+00 2.1594e-01 8.3034e-05 -1.2790e-03 3.2566e-04 8.6960e-05 -6.0000e+00 1.4777e-02 1.5706e-02 -9.1778e-05 12 8 8 10 0 0 89.68 20.67 0.65 0.01571 0.00610 33 7 1 5 0 1507.850 24.35 15.00 20.67 30.66 13.5 1000.35 -181783 175073 -173763 -93906 -162016 15162 -127572 -11213 150649 -168349 900000 -167228 -56199 -122166 -57491 31830 -33341 900000 -28202 21187 26315 -10593 156661 293557 -26179 -18127 -3902 49756 15601 -57519 -4912 -27787 7531 27965 566 87409 -46037 -8652 25253 24601 6523 26679 8506 -2830 25421 8663 19603 -20497 32155 24956 50468 50508 45432 14891 6662 21889 10353 -1582 1899 4994 16166 10761 16418 19586 10278 -3937 11351 6236 8530 14840 9255 4282 -3536 973 480 -4719 -11081 -3549 -3832 1331 874 -6781 2788 -2455 -816 -540 838 -331 -134 5801 -177 -1402 -5518 -1933 -961 -4305 -349 -353 1330 -225 -900 -2396 -1968 -1553 -3237 -1270 -3012 -2073 -342 158 1953 -657 45 -852 -301 -1556 -56 -597 164 2763 1101 3753 1121 838 511 -388 250 225 714 812 -192 -508 -46 390 -425 -227 440 459 20 -348 -10 -1525 900000 -4771 1838 -5804 -1344 -4020 159 -1948 -118 1582 -3856 900000 -4309 -644 -3731 -1207 334 -764 900000 -727 344 402 -222 1645 3082 -600 -381 -71 522 238 -2086 -131 -1140 252 801 20 1251 -2680 -396 964 1080 374 1324 536 -208 1456 673 1420 -2324 2262 2017 3497 3871 3959 1876 937 2666 1413 -238 267 682 2088 1649 2741 3578 2158 -930 2276 1362 2024 3786 2711 1353 -1173 287 128 -1194 -2839 -883 -1110 442 341 -3246 1314 -1286 -449 -315 507 -208 -84 3264 -98 -737 -2937 -1051 -595 -3254 -297 -346 1385 -235 -875 -2110 -1593 -1285 -2933 -1189 -3048 -2246 -405 211 2833 -1026 69 -1277 -425 -2171 -79 -897 260 4388 1740 5532 1639 1187 701 -519 328 320 1161 1492 -390 -1100 -105 942 -1108 -615 1202 1271 56 -910 -24 -3544 900000 SS 20240611T203807.0Z 8928.859803 70 1 50.18 2 77.57 70.28 125.09 24.05 0.00 1 0.00 1 0 17 4.894e-01 1.415e-02 3.282e-01 9.265e-03 6.700184e-01 5.215558e-03 7.052747e-03 -6.000000e+00 2.886337e-01 232.57 -2.00 3.40 -2.00 321.56 0.00e+00 1.055301e-02 2.066716e-03 7.313304e-04 -6.000000e+00 1.186845e-02 288.80 -2.00 20.00 -2.00 321.23 0.00e+00 4.513 0.001 302.00 328.00 3 3.4777e+00 1.6253e-02 5.7173e-02 -6.0000e+00 7.3213e-01 1.4961e-01 2.2926e-02 3.6163e-02 -6.0000e+00 7.9319e-01 -3.2146e-01 2.6861e-02 2.0470e-02 -6.0000e+00 4.6199e-01 1.3069e-01 1.3252e-02 6.9754e-03 -6.0000e+00 1.9354e-01 9.0856e-05 -3.4925e-04 2.8243e-04 7.8804e-05 -6.0000e+00 1.3479e-02 1.5363e-02 -9.2137e-05 12 8 8 10 0 0 97.74 20.69 0.48 0.01536 0.01274 27 6 1 5 0 1857.950 24.46 15.00 20.69 31.09 13.4 999.27 -12290 -184922 -134093 -111172 900000 -209583 -170579 900000 -219063 -145929 -128642 900000 -147692 -77614 115493 -68701 -75357 -25847 82105 25112 63145 -36856 -47307 -13450 94794 -16869 -43506 -12610 -46289 34807 -26406 15897 -22440 13349 -30310 -46248 8121 21724 37686 -17257 6392 -1658 11815 16768 15602 -859 9245 9195 3807 30786 16292 19943 4706 10081 12336 -2512 9357 6083 5238 2164 15000 5193 -4460 6789 4052 7267 4373 -4305 5283 5123 4810 190 261 3624 -2111 -614 -1952 -571 -1976 3968 -1838 -1952 -2030 -1198 -1823 -2028 2016 1961 1406 -1242 1210 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