File name: Pandora194s1_Tokyo-TMU_20240703_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240703T145735.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240703_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T225929.0Z 8949.957975 240 1 24.27 2 50.46 88.27 17.47 124.46 0.00 1 0.00 1 0 17 1.546e-02 9.650e-03 1.156e-02 4.205e-03 1.991690e-01 2.107082e-03 2.217750e-03 -6.000000e+00 8.894401e-03 232.47 -2.00 3.40 -2.00 317.22 0.00e+00 1.464430e-03 2.622232e-04 3.951607e-05 -6.000000e+00 3.535761e-04 290.62 -2.00 20.00 -2.00 316.86 0.00e+00 1.567 0.000 302.00 328.00 3 5.5536e+00 5.5898e-03 1.8409e-02 -6.0000e+00 2.2514e-02 -4.1304e-02 6.2387e-03 9.8975e-03 -6.0000e+00 2.4518e-02 2.7492e-02 3.7165e-03 4.7943e-03 -6.0000e+00 1.4365e-02 -2.0499e-02 1.7875e-03 1.3200e-03 -6.0000e+00 5.8606e-03 3.5766e-04 2.9465e-04 1.2182e-04 1.3873e-05 -6.0000e+00 4.1492e-04 1.3450e-02 -2.3502e-05 12 9 9 12 1 1 99.79 20.75 0.61 0.01345 0.01566 7 3 1 5 0 3031.510 24.46 15.00 20.75 33.15 14.7 1001.32 -2312 -2943 -5225 -3687 299 966 -989 -2453 -3451 -2084 762 -2937 -3834 -907 1797 538 1109 -1114 1020 1303 1001 3457 2721 363 -2199 -156 -1287 -1394 -2443 514 884 774 3712 -2148 -3834 -3415 -1464 -2576 226 -269 -1390 1546 -1748 -384 152 1618 103 -919 369 -1261 1333 612 1678 700 689 2249 421 -478 -516 757 1077 932 3218 3064 1200 -743 -1164 -1847 1537 1517 1254 1727 663 840 -285 -899 -1162 -2324 -1387 -1246 -1951 -1546 -2818 -1335 -197 -922 -761 499 1266 73 -220 -909 -1773 -556 -404 -176 470 1184 539 -596 -1456 -1280 -1149 -930 -954 -599 -174 -735 -47 982 794 939 1059 393 -392 31 -3 499 1024 690 1407 849 825 50 412 107 -51 236 -355 -621 -932 -443 -924 62 -152 -474 606 155 281 137 306 -686 -689 -316 -440 -814 -528 36 111 -122 -342 -538 -333 116 -471 -690 -181 396 131 277 -293 273 360 282 940 757 108 -702 -50 -416 -424 -699 140 252 237 1186 -737 -1245 -1085 -500 -1042 106 -146 -829 932 -1017 -223 88 1008 64 -555 214 -744 805 397 1133 454 457 1493 288 -328 -349 557 748 699 2546 2552 994 -571 -910 -1421 1233 1252 1127 1601 618 752 -239 -747 -875 -1690 -1058 -1067 -1708 -1474 -2875 -1408 -222 -1117 -970 646 1620 91 -251 -944 -1694 -514 -398 -190 561 1541 735 -795 -1824 -1479 -1285 -1101 -1227 -808 -244 -1082 -66 1448 1220 1428 1524 571 -525 39 -4 675 1492 1071 2209 1320 1247 73 566 139 -64 302 -488 -908 -1420 -682 -1458 101 -243 -794 1031 271 489 232 502 -1101 -1101 SS 20240702T235916.2Z 8949.999493 280 1 48.58 2 38.34 97.66 10.84 174.17 0.00 1 0.00 1 0 25 1.683e-02 9.860e-03 1.167e-02 4.648e-03 1.681099e-01 2.329968e-03 1.857960e-03 -6.000000e+00 9.685882e-03 232.47 -2.00 3.40 -2.00 317.13 0.00e+00 1.298109e-03 2.824886e-04 3.117432e-05 -6.000000e+00 3.849006e-04 290.63 -2.00 20.00 -2.00 316.77 0.00e+00 1.274 0.000 302.00 328.00 3 6.1789e+00 6.1719e-03 1.5117e-02 -6.0000e+00 2.4517e-02 -3.2307e-02 6.8989e-03 8.2820e-03 -6.0000e+00 2.6693e-02 2.2772e-02 4.0598e-03 4.0161e-03 -6.0000e+00 1.5640e-02 -1.9219e-02 1.9036e-03 1.1167e-03 -6.0000e+00 6.3854e-03 2.6887e-04 7.9509e-04 1.3479e-04 1.1456e-05 -6.0000e+00 4.5144e-04 1.1114e-02 6.3633e-05 12 8 8 10 0 0 99.98 20.84 0.44 0.01111 0.01709 24 5 1 5 0 2023.940 24.56 15.00 20.84 34.95 14.8 1000.99 267 -1834 1542 -5052 -8987 -2338 -5207 -498 807 -218 -2473 75 -199 -2769 1801 -530 -1127 -312 3615 611 957 2917 -778 2461 650 2434 -1661 -3157 -2216 653 2674 479 1252 -902 -4341 -1860 -621 -3852 -116 -396 -1378 -690 -650 -471 1741 2508 613 295 -217 -462 1245 719 1713 1082 1242 1425 525 -186 -1128 -457 771 1275 2873 1950 751 -1326 -699 -767 -743 -313 1364 1413 661 1517 -533 -381 -2877 -2413 -1579 -1269 -753 -1805 -2394 -839 -630 591 442 744 699 647 930 -780 -1787 -877 -1491 -608 901 1202 86 -113 -1338 -1897 -1362 -1182 -1497 -1083 -368 -300 -40 1031 1531 1169 524 66 -743 -469 -368 936 774 1113 1162 939 1129 452 -109 -478 -455 -542 -317 -119 -743 -636 -159 -232 61 -537 143 638 520 38 -26 -491 -767 42 -318 262 -851 -1389 -319 -764 -78 137 -39 -438 13 -38 -614 428 -139 -306 -86 989 178 282 832 -233 742 208 787 -554 -999 -644 179 747 145 402 -299 -1519 -621 -224 -1521 -53 -207 -786 -406 -392 -285 1028 1464 354 165 -129 -275 762 469 1055 699 817 949 357 -139 -838 -338 585 1035 2246 1610 610 -1096 -526 -560 -583 -276 1284 1379 647 1419 -472 -301 -2102 -1665 -1136 -1019 -669 -1767 -2486 -899 -725 721 517 891 836 813 1070 -824 -1732 -820 -1488 -661 1065 1552 116 -149 -1660 -2190 -1518 -1397 -1928 -1460 -515 -436 -61 1632 2271 1893 806 94 -969 -579 -460 1219 1094 1671 1779 1422 1658 637 -146 -611 -555 -673 -419 -166 -1079 -934 -236 -360 101 -931 252 1148 935 67 -45 -819 -1274 SS 20240703T000409.9Z 8950.002893 283 1 49.25 2 37.35 98.55 10.78 179.95 0.00 1 0.00 1 0 17 1.269e-02 8.318e-03 4.051e-03 1.942e-03 1.600711e-01 9.728027e-04 1.793528e-03 -6.000000e+00 7.302953e-03 232.47 -2.00 3.40 -2.00 316.51 0.00e+00 8.212474e-04 1.024759e-04 2.419907e-05 -6.000000e+00 2.902406e-04 290.63 -2.00 20.00 -2.00 316.16 0.00e+00 1.257 0.000 302.00 328.00 3 5.2226e+00 2.5624e-03 1.4767e-02 -6.0000e+00 1.8485e-02 -5.2648e-02 2.8578e-03 7.9399e-03 -6.0000e+00 2.0127e-02 2.5989e-02 1.6505e-03 3.8391e-03 -6.0000e+00 1.1793e-02 -1.8240e-02 7.5346e-04 1.0518e-03 -6.0000e+00 4.8138e-03 7.2949e-04 6.8753e-04 5.5729e-05 1.1773e-05 -6.0000e+00 3.4043e-04 1.2389e-02 6.9119e-05 11 9 0 11 8 0 99.96 20.85 0.44 0.01239 0.01756 22 5 1 5 0 2237.840 24.65 15.00 20.85 35.04 14.7 1000.61 -682 -2965 -814 -4253 -3899 -3214 1201 427 -831 -2199 -3445 -3365 -1056 -2072 1397 1052 -272 844 1675 971 341 1481 1822 1436 611 -28 -781 -1616 -520 -92 1108 1375 2767 -277 -3041 -3345 -1298 -1008 -175 -111 -196 -207 -546 -318 -137 271 112 89 -559 254 539 1131 1121 1122 374 1074 139 430 398 282 1302 1756 2408 2136 564 -973 -817 -389 651 343 782 726 522 401 -58 -1092 -2079 -2044 -1500 -1408 -1789 -1106 -1845 -1547 -1039 -73 131 798 889 571 17 -571 -889 -848 -391 -426 423 560 102 -329 -1341 -1759 -1252 -640 -955 -979 -803 -738 283 775 1408 1010 796 346 -153 -142 -16 432 736 974 1149 981 697 360 346 -110 -6 153 -81 -188 -389 -210 -679 -387 -146 27 83 333 78 -69 -441 -345 -448 -135 -650 -176 -885 -712 -551 206 82 -180 -501 -774 -756 -254 -566 412 336 -90 282 573 345 124 526 652 539 241 -11 -319 -620 -183 -31 384 503 1063 -111 -1160 -1252 -521 -471 -97 -71 -122 -134 -364 -213 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