File name: Pandora194s1_Tokyo-TMU_20240801_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240801T145657.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240801_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240731T203605.5Z 8978.858398 166 1 48.69 2 82.15 73.48 41.13 86.52 0.00 1 0.00 1 0 33 5.568e-01 4.150e-02 4.567e-01 3.003e-02 7.529747e-01 1.798885e-02 8.061006e-03 -6.000000e+00 3.322076e-01 231.80 -2.00 3.40 -2.00 321.89 0.00e+00 7.063889e-03 6.892225e-03 7.694656e-04 -6.000000e+00 1.500899e-02 291.98 -2.00 20.00 -2.00 321.54 0.00e+00 6.818 0.005 302.00 328.00 3 2.5835e+00 5.6927e-02 7.7927e-02 -6.0000e+00 8.4192e-01 9.2733e-01 7.1133e-02 3.9586e-02 -6.0000e+00 9.1601e-01 -1.1815e+00 6.6096e-02 2.1420e-02 -6.0000e+00 5.3455e-01 4.5666e-01 3.4191e-02 7.1793e-03 -6.0000e+00 2.2730e-01 2.0477e-05 -2.7289e-03 9.4375e-04 9.5007e-05 -6.0000e+00 1.5892e-02 1.6466e-02 -1.0198e-04 12 8 8 10 0 0 74.63 20.58 0.88 0.01647 -0.00404 13 3 1 5 0 3744.670 24.35 15.00 20.58 34.51 16.1 995.57 900000 900000 -101109 202841 -44544 -96938 -59286 63448 -107521 105754 900000 -166754 900000 -39946 -44782 -11809 37011 900000 19411 19093 52294 900000 900000 35 85435 900000 -57306 900000 900000 900000 -79481 900000 232728 75323 900000 83991 8163 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-1978 6740 351 2138 2667 249 4518 -3427 3405 765 3915 1521 175 1953 -6702 -1508 -7116 -666 278 -1155 3218 540 3112 -9327 596 -7033 -2107 3330 1649 -5558 -6603 -135 -1087 -99 -7886 -626 -3252 -1688 547 4751 1727 -5158 -1620 -8221 2923 2391 5669 8584 4583 3395 2138 201 2121 3965 2986 -2940 7793 1073 -1479 949 -4820 -1077 6136 3917 943 -4663 -5725 -3943 900000 SS 20240731T210256.2Z 8978.877040 177 1 48.66 2 76.87 77.14 35.82 90.06 0.00 1 0.00 1 0 25 2.567e-01 1.595e-02 3.330e-01 1.172e-02 5.015437e-01 6.374355e-03 5.448206e-03 -6.000000e+00 1.499593e-01 231.80 -2.00 3.40 -2.00 320.84 0.00e+00 8.207219e-03 2.150307e-03 3.870397e-04 -6.000000e+00 6.089156e-03 291.98 -2.00 20.00 -2.00 320.51 0.00e+00 4.289 0.001 302.00 328.00 3 4.2390e+00 1.8712e-02 4.9661e-02 -6.0000e+00 3.7948e-01 3.9172e-02 2.3732e-02 2.6412e-02 -6.0000e+00 4.1136e-01 -7.2508e-02 2.5560e-02 1.4225e-02 -6.0000e+00 2.4105e-01 2.2478e-02 1.3198e-02 4.6132e-03 -6.0000e+00 1.0167e-01 6.3560e-05 -3.4977e-04 3.6408e-04 5.0180e-05 -6.0000e+00 6.9343e-03 1.6313e-02 -1.5292e-04 12 8 8 10 0 0 99.97 20.62 0.52 0.01631 0.01369 13 3 1 5 0 3742.450 24.46 15.00 20.62 35.44 16.0 992.21 -18768 -80583 900000 -40251 -93980 -64113 -59579 -68418 -5698 -1197 34606 -878 900000 -57509 -74237 -44970 11498 136009 -10420 900000 25987 -28782 60819 -44510 14537 -54966 8313 -485 65672 -72338 -15627 4695 -4606 42342 -10571 -50 -22461 34741 -8285 -7419 -5187 2059 -16019 1175 9714 16293 8681 26147 654 12022 5110 2502 7366 882 -152 1443 1208 763 -204 -10923 13170 13793 3642 3517 -4660 4823 -993 -1425 5828 3967 267 3309 2994 562 776 -1208 1222 -6297 3148 3866 314 -164 -1721 -2188 -4819 1683 1256 329 1000 -1829 -782 -743 -1936 -3321 -868 -1900 -1017 1212 482 1438 -2705 -1114 -5298 -488 -1237 -86 -1324 -568 985 327 2814 352 819 101 530 178 188 -303 -199 257 84 2741 737 -304 209 -2341 809 308 1171 6 -1056 112 -467 -1018 -623 142 -50 793 620 -145 496 -1130 900000 -214 -1087 900000 -460 -1366 -732 -680 -852 -65 -14 395 -10 900000 -1373 -2620 -1400 227 1553 -303 900000 566 -1075 947 -2079 392 -3081 250 -16 1091 -5181 -746 214 -263 1582 -636 -3 -1678 1904 -765 -793 -598 259 -2311 162 1264 2046 1199 3105 103 1784 893 494 1497 205 -37 354 302 190 -50 -3018 3022 3496 1152 1225 -1793 1608 -340 -501 2116 1680 128 1587 1415 257 324 -463 428 -2416 1236 1770 171 -101 -1153 -1556 -3780 1322 1043 283 849 -1526 -598 -526 -1319 -2370 -676 -1716 -1043 1370 581 1676 -3042 -1116 -5238 -481 -1327 -96 -1581 -717 1333 491 4437 582 1312 154 752 246 265 -454 -319 425 138 4253 1131 -453 298 -3271 1070 436 1832 10 -1991 217 -952 -2216 -1441 340 -123 1960 1520 -343 1108 -2449 900000 SS 20240731T213108.5Z 8978.896626 190 1 11.43 2 71.25 80.94 30.23 94.32 0.00 1 0.00 1 0 17 1.268e-01 1.410e-02 9.784e-02 9.712e-03 3.732781e-01 4.968208e-03 4.180843e-03 -6.000000e+00 7.406822e-02 231.80 -2.00 3.40 -2.00 319.36 0.00e+00 2.226380e-03 1.123932e-03 1.529026e-04 -6.000000e+00 2.916703e-03 291.98 -2.00 20.00 -2.00 319.05 0.00e+00 3.072 0.000 302.00 328.00 3 4.6513e+00 1.3677e-02 3.5780e-02 -6.0000e+00 1.8732e-01 -4.4952e-02 1.5584e-02 1.8984e-02 -6.0000e+00 2.0290e-01 1.6031e-03 1.2462e-02 9.5420e-03 -6.0000e+00 1.1884e-01 -9.0858e-03 6.7240e-03 2.8377e-03 -6.0000e+00 4.9945e-02 1.6107e-04 -5.0374e-04 2.8544e-04 2.7703e-05 -6.0000e+00 3.4109e-03 1.4777e-02 -1.2961e-04 12 9 9 12 1 1 999.00 20.66 0.50 0.01478 0.01099 2 3 1 5 0 3807.950 24.46 15.00 20.66 34.99 16.1 991.31 -42253 39323 -8119 -57472 -52605 -66933 -51613 -34688 -7966 -4937 -27890 -100 -27605 5701 -15622 6990 -4307 5899 -3342 20531 6105 -4680 7853 -6476 -398 -2123 4350 -7190 15127 -5533 14890 3781 4281 -4381 -1882 7021 -5474 8098 8153 -9703 -2130 -3219 2839 -473 -146 4272 -1055 5487 2835 4333 751 335 -3203 2312 4585 3495 4958 1247 -3203 -2420 3486 833 2079 2301 960 691 -397 1953 -2721 1529 1990 52 1680 1158 -1287 -4821 -4270 -2617 -463 -633 1581 -140 -3709 -630 -2838 -804 813 2825 -673 2700 154 -2231 -674 -2274 -1309 -266 234 2167 -203 -432 -1616 -1360 -1924 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