File name: Pandora194s1_Tokyo-TMU_20240917_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240917T144933.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240917_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240916T222140.6Z 9025.931719 240 1 19.11 2 67.65 104.14 129.87 286.29 0.00 1 0.00 1 0 17 3.014e-02 8.059e-03 5.567e-03 1.003e-03 2.965856e-01 4.996565e-04 3.326504e-03 -6.000000e+00 1.715264e-02 229.13 -2.00 3.40 -2.00 318.48 0.00e+00 2.064503e-03 8.892923e-05 9.069156e-05 -6.000000e+00 6.892150e-04 290.20 -2.00 20.00 -2.00 318.12 0.00e+00 2.608 0.000 302.00 328.00 3 1.8677e+00 1.3442e-03 2.9561e-02 -6.0000e+00 4.3071e-02 -7.8068e-02 1.5139e-03 1.4738e-02 -6.0000e+00 4.6997e-02 2.7454e-02 1.0271e-03 7.2646e-03 -6.0000e+00 2.7609e-02 -2.0770e-02 5.3662e-04 2.0799e-03 -6.0000e+00 1.1365e-02 4.6394e-03 1.9880e-04 2.9274e-05 2.1200e-05 -6.0000e+00 8.0759e-04 1.2121e-03 -1.8869e-06 12 9 1 12 1 1 99.94 17.63 0.37 0.00121 0.00271 118 66 1 5 0 160.560 21.88 15.00 17.63 35.37 19.7 1005.22 -6678 -7323 -4401 -9069 -13929 -12147 -9181 -7080 -9468 -6998 -11024 -8569 -6006 -4190 -2561 -1765 -905 -654 1688 1553 1090 537 166 -250 -1408 -2126 -2415 -2501 -3004 215 258 1193 1716 -1364 -3510 -1995 -1753 -1146 -364 -656 -1280 -733 -854 -98 657 1072 341 584 -18 1028 1523 1859 1776 1592 1347 1031 421 94 -14 538 1615 2532 2896 2807 1024 308 -583 -511 820 884 801 644 462 129 -402 -1150 -1900 -1860 -1173 -1167 -1239 -1608 -2216 -1804 -722 -194 223 732 947 521 281 -649 -878 -745 -525 -316 395 647 97 -770 -1169 -1706 -1235 -767 -1120 -997 -958 -567 206 678 1090 991 926 436 -56 -33 88 707 801 742 856 967 706 405 177 -535 -56 199 117 -93 -374 -349 -687 -246 -299 -260 202 372 53 40 -181 -355 -287 -358 -444 -271 -559 -808 -658 -508 -431 -660 -504 -827 -650 -509 -412 -290 -223 -121 -92 243 234 170 84 26 -42 -255 -404 -463 -457 -522 36 47 237 373 -318 -788 -432 -414 -316 -120 -231 -499 -299 -362 -42 281 461 146 246 -8 434 682 897 913 867 761 599 251 56 -8 313 968 1631 1869 1945 723 221 -395 -341 585 657 653 547 392 106 -306 -866 -1313 -1241 -830 -863 -1037 -1496 -2215 -1889 -742 -213 258 867 1119 594 297 -684 -856 -717 -542 -336 467 849 125 -981 -1502 -2022 -1392 -902 -1439 -1350 -1263 -783 299 1053 1663 1527 1469 646 -77 -47 117 978 1193 1172 1369 1518 1081 595 249 -723 -77 284 168 -144 -611 -586 -1109 -415 -538 -489 389 686 98 77 -334 -634 -508 SS 20240916T223101.3Z 9025.938209 243 1 11.40 2 65.82 105.71 131.58 288.10 0.00 1 0.00 1 0 17 2.201e-02 8.222e-03 6.063e-03 1.447e-03 2.763301e-01 7.198556e-04 3.116639e-03 -6.000000e+00 1.252560e-02 229.13 -2.00 3.40 -2.00 317.94 0.00e+00 1.715922e-03 1.100051e-04 6.989960e-05 -6.000000e+00 5.034546e-04 290.20 -2.00 20.00 -2.00 317.58 0.00e+00 2.424 0.000 302.00 328.00 3 2.4172e+00 1.9167e-03 2.7475e-02 -6.0000e+00 3.1452e-02 -8.1711e-02 2.1537e-03 1.3693e-02 -6.0000e+00 3.4322e-02 2.7265e-02 1.3713e-03 6.7225e-03 -6.0000e+00 2.0163e-02 -1.7997e-02 6.9714e-04 1.9048e-03 -6.0000e+00 8.2978e-03 3.2893e-03 -1.4580e-04 4.1940e-05 1.9701e-05 -6.0000e+00 5.9002e-04 1.7466e-03 -5.8699e-05 12 9 1 12 1 1 86.28 17.63 0.39 0.00175 0.00065 39 37 1 5 0 284.910 21.88 15.00 17.63 36.18 19.7 1007.32 -5900 287 -6112 -6743 -9739 -6407 -3136 -2815 -3224 -7738 -6001 -9629 -2655 -3467 -239 -150 -1084 1746 -434 2513 -1329 1175 110 411 -584 -1080 -1475 -3427 -3046 -470 1698 1082 3022 -1155 -3087 -2720 -2722 -777 128 76 -769 -761 -320 -50 799 336 703 178 -282 991 1625 1913 1628 1335 492 954 475 260 -65 367 1682 1912 3104 2107 1079 -208 -696 -196 562 794 731 970 48 369 -377 -1087 -1598 -2311 -1470 -1290 -1195 -1607 -2222 -1454 -867 -88 16 589 767 719 534 -478 -703 -974 -397 -624 280 598 -20 -648 -1144 -1534 -1701 -515 -1209 -1129 -813 -502 226 797 1147 862 992 374 -32 156 106 796 911 1088 789 855 649 410 117 -384 -4 340 152 -343 -259 -462 -688 -227 -243 -171 156 270 -48 19 -173 -328 -325 -446 23 -538 -569 -757 -457 -228 -229 -294 -782 -594 -1018 -297 -459 -36 -25 -193 316 -84 494 -279 239 23 91 -137 -266 -366 -823 -687 -103 389 274 820 -308 -868 -745 -741 -243 48 33 -373 -355 -154 -24 388 165 340 85 -146 511 810 1026 930 808 311 613 313 171 -42 236 1112 1366 2213 1622 836 -151 -513 -141 433 642 646 893 44 328 -313 -816 -1187 -1665 -1118 -1027 -1073 -1486 -2206 -1506 -960 -97 18 701 912 820 604 -498 -677 -997 -402 -706 327 774 -27 -874 -1448 -1790 -2039 -597 -1536 -1513 -1068 -689 326 1226 1744 1323 1549 546 -43 213 146 1078 1329 1681 1242 1324 979 594 162 -543 -5 469 213 -519 -410 -752 -1083 -373 -426 -297 277 489 -88 34 -295 -572 -563 SS 20240916T235834.4Z 9025.999009 308 1 33.39 2 49.64 123.27 146.13 310.37 0.00 1 0.00 1 0 17 1.318e-02 8.379e-03 3.658e-03 1.607e-03 1.785738e-01 8.024383e-04 2.032316e-03 -6.000000e+00 7.505742e-03 229.13 -2.00 3.40 -2.00 316.69 0.00e+00 1.038757e-03 8.937728e-05 2.929885e-05 -6.000000e+00 3.014338e-04 290.20 -2.00 20.00 -2.00 316.35 0.00e+00 1.541 0.000 302.00 328.00 3 4.3758e+00 2.1042e-03 1.7527e-02 -6.0000e+00 1.8847e-02 -5.6753e-02 2.3488e-03 8.8055e-03 -6.0000e+00 2.0562e-02 2.6642e-02 1.3732e-03 4.3018e-03 -6.0000e+00 1.2080e-02 -1.8268e-02 6.4357e-04 1.2073e-03 -6.0000e+00 4.9750e-03 1.2567e-03 5.7246e-04 4.6412e-05 1.3402e-05 -6.0000e+00 3.5315e-04 -2.0579e-04 7.5800e-05 12 9 1 12 1 1 99.96 17.70 0.47 -0.00021 0.00410 32 11 1 5 0 1011.660 21.98 15.01 17.70 37.71 20.0 1005.72 -212 -2188 -1855 -4763 -4326 -4825 -748 -2684 -385 -2769 -4202 -1156 -2023 162 -520 -187 -611 1615 1225 1458 879 167 1671 1027 823 31 -537 -1004 -1348 200 877 1877 2413 -1039 -2529 -2332 -1503 -752 135 -414 -251 -764 -590 -636 329 601 -363 432 -875 291 751 883 1683 1368 1138 1179 337 -202 206 440 1269 2107 2406 2261 411 -116 -1107 -548 615 617 681 410 674 6 -108 -1391 -1559 -2016 -1094 -1352 -1455 -1294 -2488 -1660 -981 -368 57 406 960 473 206 -910 -821 -780 -753 -543 319 805 35 -751 -1188 -1474 -1076 -787 -1115 -1124 -700 -612 332 578 1111 1034 1121 647 -5 190 161 603 789 871 857 1002 794 462 567 -412 -9 148 209 36 -263 -299 -772 -305 -338 -166 134 123 8 -43 -301 -465 -419 -36 -412 -355 -883 -705 -740 -115 -466 -73 -562 -847 -226 -437 39 -141 -55 -187 495 390 479 296 56 558 360 303 12 -206 -364 -454 64 290 655 896 -408 -941 -839 -582 -336 65 -233 -153 -489 -387 -421 215 391 -233 265 -527 172 461 577 1147 977 835 878 257 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