File name: Pandora194s1_Tokyo-TMU_20240921_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240921T144242.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240921_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240920T212037.7Z 9029.889325 242 1 49.95 2 80.50 96.09 61.59 270.01 0.00 1 0.00 1 0 17 5.273e-01 2.330e-02 3.288e-01 1.266e-02 5.823673e-01 6.828067e-03 6.066373e-03 -6.000000e+00 2.996689e-01 228.78 -2.00 3.40 -2.00 321.58 0.00e+00 1.191132e-02 2.712603e-03 5.603646e-04 -6.000000e+00 1.290906e-02 289.79 -2.00 20.00 -2.00 321.20 0.00e+00 5.766 0.003 302.00 328.00 3 2.8518e+00 2.0943e-02 6.3883e-02 -6.0000e+00 7.5198e-01 3.0290e-01 2.6944e-02 2.9886e-02 -6.0000e+00 8.2118e-01 -5.4456e-01 2.7523e-02 1.5708e-02 -6.0000e+00 4.8267e-01 2.2903e-01 1.3812e-02 5.0533e-03 -6.0000e+00 2.0048e-01 6.0904e-05 -8.3813e-04 3.9274e-04 6.2215e-05 -6.0000e+00 1.4255e-02 1.0292e-03 -8.9987e-05 12 8 8 10 0 0 97.80 17.53 0.35 0.00103 -0.00527 22 5 1 5 0 2269.880 21.88 14.99 17.53 33.83 20.7 993.98 -47173 900000 27468 -115935 -15372 -176277 -106246 -167002 -170549 -141722 900000 1331 -119883 120765 -72834 161425 -41917 48007 61044 -15243 900000 -12451 4622 -2638 84032 -8677 29722 321389 -4899 72326 -9841 168126 7158 20245 -9713 -17631 -12849 62697 17748 28287 4896 16264 33667 43786 19404 45304 17910 43524 24977 30001 14722 18421 25918 19672 11878 622 15707 11861 17714 4973 19483 25168 12427 11195 7098 15273 2588 9530 5922 4848 3426 1124 8100 -5174 1801 -8643 -5699 988 535 1022 -2794 1970 -1782 -1738 816 -398 -2770 2121 885 -3655 2706 -2193 -3364 -3449 -5686 -2331 -2000 511 -1415 -739 -1932 -1873 -2470 -3619 -2840 -3516 -1815 -3478 2597 -753 14 1522 964 -1127 -1260 -399 -1266 1238 -32 1518 2672 1228 1782 2453 788 267 1372 1997 183 1352 291 770 -539 -308 -399 532 404 -787 -47 269 -22 -1296 -1103 -582 900000 339 -3641 -190 -8106 -2383 -7118 -7843 -4928 900000 16 -4572 1490 -2859 1992 -1598 808 959 -530 900000 -405 124 -77 1037 -272 633 3965 -143 1055 -386 2074 321 840 -512 -969 -721 1899 995 1650 395 1240 2266 2750 1589 3242 1567 3329 2373 2850 1780 2364 3326 2864 1934 115 2519 1946 2666 847 3005 4068 2591 2638 1813 3467 648 2269 1607 1525 1196 416 2748 -1890 560 -2676 -1603 264 162 367 -1213 924 -941 -969 475 -251 -1886 1418 599 -2494 1612 -1277 -1897 -2013 -3823 -1763 -1749 499 -1521 -782 -1931 -1686 -2081 -3175 -2677 -3531 -1899 -3973 3066 -1027 21 2326 1468 -1676 -1769 -537 -1755 1772 -50 2415 4173 1883 2639 3486 1097 361 1789 2754 292 2375 562 1560 -1160 -703 -977 1352 1051 -2108 -124 678 -54 -2975 -2488 SS 20240920T212930.3Z 9029.895489 247 1 48.78 2 78.71 97.43 63.32 271.28 0.00 1 0.00 1 0 17 3.194e-01 1.445e-02 1.935e-01 7.931e-03 5.215199e-01 4.244721e-03 5.471841e-03 -6.000000e+00 1.829276e-01 228.78 -2.00 3.40 -2.00 321.22 0.00e+00 7.578210e-03 1.576582e-03 4.444497e-04 -6.000000e+00 8.041699e-03 289.79 -2.00 20.00 -2.00 320.85 0.00e+00 4.930 0.002 302.00 328.00 3 3.0260e+00 1.2665e-02 5.5116e-02 -6.0000e+00 4.6066e-01 5.0032e-02 1.6376e-02 2.6722e-02 -6.0000e+00 5.0371e-01 -1.6231e-01 1.7732e-02 1.4167e-02 -6.0000e+00 2.9373e-01 6.1587e-02 8.9916e-03 4.5391e-03 -6.0000e+00 1.2252e-01 1.2296e-04 -1.2142e-04 2.4932e-04 5.1936e-05 -6.0000e+00 8.7733e-03 5.9457e-06 -6.1596e-05 12 8 8 10 0 0 79.80 17.53 0.50 0.00001 -0.00091 34 7 1 5 0 1434.480 21.88 15.00 17.53 34.14 20.8 995.10 900000 -155347 900000 -22315 -41840 -120823 -184516 900000 -129246 900000 -122451 900000 -56146 -71424 1358 -39972 -10541 -32706 -351 -29259 7239 -18687 -32949 29246 -35606 11406 -55148 19379 -3915 -47131 -18590 -7263 11369 7603 25535 -28601 24933 -9379 -8626 3129 11020 7817 71 30642 5028 7935 5989 13684 6240 -2412 17561 13662 15147 6455 9550 2496 -2433 4910 -5546 4211 4028 9242 2882 3407 1360 5208 2528 2672 7938 465 2631 655 -2326 -2151 1562 -459 126 -1981 -2949 4096 -1747 -755 -2544 -2109 114 -2132 111 -412 1868 1438 -231 -2365 -3048 493 -3922 -504 -425 2274 -361 -591 -352 -2780 -1123 -2514 -747 -2665 -2065 -1746 524 2161 429 905 -92 1099 -700 -735 167 275 1245 400 1547 355 1361 522 -49 70 561 633 -630 1212 -792 -278 -233 -486 482 -721 124 -45 294 -400 -59 513 -592 900000 -3928 900000 -172 -323 -1952 -5832 900000 -2814 900000 -2666 900000 -868 -1656 19 -1011 -222 -942 -8 -925 163 -538 -1111 555 -1351 280 -2673 436 -110 -2185 -757 -311 463 342 1006 -1901 1060 -660 -727 276 996 779 8 2652 575 907 713 1544 781 -347 2266 2027 2399 1197 1793 517 -539 1005 -1234 849 853 2057 773 1008 425 1501 725 778 2417 175 1065 282 -1017 -891 572 -154 39 -635 -1067 1627 -852 -411 -1527 -1333 76 -1550 83 -321 1419 1054 -160 -1553 -1917 307 -2848 -407 -395 2333 -408 -660 -365 -2676 -996 -2341 -741 -2845 -2317 -2086 667 2995 659 1429 -144 1617 -984 -995 229 397 1904 644 2453 552 2037 759 -68 94 733 874 -987 2067 -1486 -544 -476 -1058 1112 -1760 308 -115 738 -971 -135 1116 -1288 SS 20240920T220545.7Z 9029.920667 262 1 47.71 2 71.46 103.07 70.37 276.30 0.00 1 0.00 1 0 17 8.742e-02 1.014e-02 8.198e-02 5.631e-03 3.499202e-01 2.817705e-03 3.869371e-03 -6.000000e+00 4.967788e-02 228.78 -2.00 3.40 -2.00 319.69 0.00e+00 2.223441e-03 7.040941e-04 1.639670e-04 -6.000000e+00 1.999258e-03 289.79 -2.00 20.00 -2.00 319.34 0.00e+00 3.105 0.000 302.00 328.00 3 4.6531e+00 7.7771e-03 3.5173e-02 -6.0000e+00 1.2464e-01 -5.9245e-02 8.9987e-03 1.7590e-02 -6.0000e+00 1.3605e-01 3.2915e-02 7.5772e-03 8.8633e-03 -6.0000e+00 7.9942e-02 -2.7746e-02 4.0698e-03 2.6197e-03 -6.0000e+00 3.2928e-02 1.6444e-04 -3.2153e-04 1.6971e-04 2.7636e-05 -6.0000e+00 2.3428e-03 6.0696e-05 -1.0093e-04 12 8 8 10 0 0 97.49 17.52 0.33 0.00006 -0.00236 14 3 1 5 0 3406.870 21.79 14.99 17.52 34.01 20.9 993.67 3142 -17887 73553 -18019 -16207 -9312 -34114 3828 -15402 -5531 -28888 -2761 -18541 -11621 -6623 -11034 4113 -3433 351 -1935 8188 -3188 -4506 2366 -7939 2836 -5009 -1015 2018 -7776 9691 -4240 6345 -2586 12871 -9370 -6969 1708 -3736 153 -2388 -93 -4981 -1190 -885 2870 5368 430 -342 -2155 3134 332 5893 880 1535 1011 569 -1091 -2955 -968 838 2647 4027 3857 397 -1023 -459 -418 2062 997 2497 1129 -338 500 -1699 241 -3064 -281 -2921 -906 -1835 -983 -34 -3354 -151 435 611 542 998 1212 707 -571 -2623 -577 422 695 720 961 -368 -1031 -785 -1799 -755 -1407 -952 -1695 -1273 -789 -516 1064 1373 922 1393 932 -139 -1252 -311 103 1047 478 1370 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