File name: Pandora194s1_Tokyo-TMU_20241020_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20241020T143810.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20241020_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20241020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241020T005349.8Z 9059.037382 377 1 12.79 2 51.08 149.92 99.22 308.97 0.00 1 0.00 1 0 17 1.200e-02 8.413e-03 1.723e-03 8.321e-04 1.805750e-01 4.138638e-04 2.053977e-03 -6.000000e+00 6.767433e-03 226.25 -2.00 3.40 -2.00 316.36 0.00e+00 1.052348e-03 4.337879e-05 2.833623e-05 -6.000000e+00 2.744792e-04 286.72 -2.00 20.00 -2.00 316.02 0.00e+00 1.588 0.000 302.00 328.00 3 2.4180e+00 1.0750e-03 1.7871e-02 -6.0000e+00 1.6881e-02 -7.5186e-02 1.2025e-03 8.7458e-03 -6.0000e+00 1.8451e-02 2.3126e-02 7.0150e-04 4.3073e-03 -6.0000e+00 1.0863e-02 -1.5398e-02 3.2410e-04 1.2281e-03 -6.0000e+00 4.5049e-03 8.5664e-03 4.3194e-04 2.3837e-05 1.3645e-05 -6.0000e+00 3.2130e-04 -5.8310e-03 9.2099e-05 12 9 1 12 1 1 99.96 16.86 0.40 -0.00583 -0.00259 109 92 1 5 0 116.220 20.87 15.00 16.86 23.62 20.8 1011.44 -1241 -2114 -1479 -3597 -4081 -3444 -549 -625 -455 -1957 -3680 -2470 -1964 -750 558 519 364 1034 1112 1225 1091 830 1527 678 495 89 -760 -1229 -1286 26 1188 1648 1327 -1032 -2632 -2237 -1881 -408 -73 -346 -607 -493 -567 -306 419 229 59 379 -443 405 1193 898 1512 1194 1069 988 715 452 193 579 1295 1789 2359 2358 551 -315 -897 -745 375 459 593 426 346 299 -145 -971 -1685 -2024 -1362 -1450 -1529 -1627 -2398 -1755 -914 -521 30 426 893 408 266 -619 -776 -848 -587 -457 192 708 4 -532 -989 -1441 -1337 -609 -1082 -942 -726 -565 202 696 1165 1176 1096 664 53 193 237 726 953 1095 925 998 809 415 398 -331 80 326 163 -4 -332 -514 -788 -299 -270 -222 47 221 61 -55 -333 -464 -501 -242 -456 -324 -761 -767 -599 -96 -121 -98 -452 -849 -561 -485 -207 172 159 116 334 372 422 385 291 535 250 192 36 -308 -472 -457 9 412 606 525 -429 -1040 -849 -768 -191 -41 -206 -396 -335 -396 -216 293 160 40 250 -285 256 781 628 1106 916 843 792 585 369 155 463 1064 1449 2053 2169 510 -269 -762 -609 321 411 580 436 355 297 -135 -820 -1396 -1584 -1099 -1211 -1428 -1669 -2444 -1861 -1032 -631 36 520 1089 481 310 -661 -811 -855 -622 -493 228 860 5 -672 -1259 -1701 -1513 -719 -1399 -1198 -964 -781 290 987 1716 1730 1537 919 68 248 306 914 1294 1590 1380 1474 1166 574 523 -446 102 420 224 -6 -473 -746 -1166 -458 -413 -356 78 372 104 -91 -537 -726 -774 SS 20241020T005754.3Z 9059.040212 380 1 51.37 2 50.68 151.10 99.83 309.62 0.00 1 0.00 1 0 17 1.263e-02 8.151e-03 3.464e-04 1.516e-04 1.782970e-01 7.485379e-05 2.034405e-03 -6.000000e+00 7.121988e-03 226.25 -2.00 3.40 -2.00 316.70 0.00e+00 1.178463e-03 8.404399e-06 2.890675e-05 -6.000000e+00 2.889297e-04 286.72 -2.00 20.00 -2.00 316.35 0.00e+00 1.575 0.000 302.00 328.00 3 1.7060e-01 1.9527e-04 1.7708e-02 -6.0000e+00 1.7765e-02 -8.3701e-02 2.1895e-04 8.6577e-03 -6.0000e+00 1.9420e-02 2.6597e-02 1.2821e-04 4.2690e-03 -6.0000e+00 1.1434e-02 -1.8078e-02 6.0119e-05 1.2169e-03 -6.0000e+00 4.7398e-03 8.2704e-02 6.0673e-05 4.3527e-06 1.3658e-05 -6.0000e+00 3.3829e-04 -5.1626e-03 2.0092e-05 11 8 0 10 0 0 97.11 16.87 0.43 -0.00516 -0.00471 3099 671 1 5 0 15.890 20.87 15.00 16.87 23.78 21.0 1012.59 -1833 -1848 -2188 -4188 -4658 -3436 -1701 -955 -977 -2670 -3957 -3172 -2090 -981 107 155 84 696 878 1607 946 790 1422 865 259 -243 -764 -1184 -1243 144 1202 1450 1575 -812 -2695 -2135 -1633 -438 44 -136 -658 -605 -414 -341 366 370 132 241 -194 537 1258 1293 1416 1412 1018 1054 631 252 276 514 1396 1910 2394 2106 531 -253 -804 -620 586 583 498 356 272 301 -150 -995 -1500 -1805 -1221 -1375 -1437 -1702 -2400 -1628 -1001 -408 -12 426 701 380 272 -618 -715 -788 -521 -430 285 608 -8 -632 -1111 -1496 -1292 -650 -1106 -961 -786 -539 145 641 1103 1125 1075 567 58 190 194 705 865 1040 858 982 768 439 341 -279 149 329 150 -54 -307 -455 -690 -317 -311 -322 115 223 51 -61 -296 -411 -418 -310 -343 -418 -770 -760 -516 -260 -161 -183 -536 -790 -626 -447 -235 29 45 26 215 280 526 319 264 476 303 96 -93 -294 -432 -421 47 397 509 592 -321 -1015 -772 -634 -195 21 -76 -406 -389 -273 -227 242 244 85 151 -118 321 779 852 980 1023 759 799 488 195 210 390 1085 1586 1960 1826 462 -222 -646 -479 475 490 458 343 262 281 -132 -862 -1174 -1335 -932 -1177 -1261 -1643 -2477 -1745 -1146 -500 -15 522 858 448 322 -669 -702 -747 -519 -470 343 740 -11 -802 -1434 -1791 -1482 -778 -1450 -1226 -1048 -748 209 973 1739 1771 1612 788 74 247 253 964 1179 1516 1285 1456 1112 610 450 -382 194 431 209 -74 -440 -664 -1026 -489 -511 -515 189 374 87 -101 -476 -691 -695 SS 20241020T010221.4Z 9059.043304 383 1 51.50 2 50.25 152.41 100.48 310.35 0.00 1 0.00 1 0 17 1.243e-02 8.099e-03 3.506e-04 1.545e-04 1.765233e-01 7.618753e-05 2.011608e-03 -6.000000e+00 7.011611e-03 226.25 -2.00 3.40 -2.00 316.68 0.00e+00 1.169917e-03 8.539766e-06 2.842349e-05 -6.000000e+00 2.843893e-04 286.72 -2.00 20.00 -2.00 316.33 0.00e+00 1.561 0.000 302.00 328.00 3 2.1053e-01 1.9878e-04 1.7543e-02 -6.0000e+00 1.7490e-02 -8.2580e-02 2.2304e-04 8.5631e-03 -6.0000e+00 1.9117e-02 2.6440e-02 1.3045e-04 4.2214e-03 -6.0000e+00 1.1255e-02 -1.8099e-02 6.1082e-05 1.2057e-03 -6.0000e+00 4.6673e-03 8.0784e-02 3.9638e-04 4.4270e-06 1.3240e-05 -6.0000e+00 3.3292e-04 -5.8656e-03 7.9315e-05 11 8 0 10 0 0 99.90 16.87 0.42 -0.00587 -0.00289 3120 676 1 5 0 15.780 20.87 15.00 16.87 24.24 21.0 1015.22 -1695 -2115 -1965 -4106 -4366 -3307 -1837 -775 -964 -2609 -3949 -3066 -2101 -1050 126 123 137 609 944 1508 994 741 1380 851 262 -199 -746 -1074 -1145 140 1195 1424 1652 -799 -2566 -2158 -1649 -488 45 -217 -658 -593 -459 -303 341 410 109 213 -224 496 1297 1271 1480 1365 992 1072 624 321 252 533 1369 1913 2347 2126 532 -267 -792 -655 610 585 494 355 276 290 -133 -947 -1522 -1777 -1222 -1357 -1469 -1711 -2388 -1663 -1025 -389 -12 400 704 381 259 -600 -712 -737 -528 -407 273 621 -23 -654 -1096 -1514 -1262 -664 -1095 -977 -799 -517 159 648 1106 1114 1061 566 55 162 205 714 889 1003 841 979 767 409 332 -254 140 380 163 -58 -328 -455 -683 -286 -279 -304 137 214 42 -82 -284 -402 -425 -290 -398 -379 -763 -719 -502 -284 -132 -183 -529 -796 -610 -453 -254 34 36 42 189 303 497 336 249 464 300 97 -77 -289 -393 -389 45 396 501 621 -316 -967 -781 -641 -218 22 -122 -406 -381 -303 -202 226 271 71 133 -136 296 801 836 1022 988 738 810 481 248 192 403 1061 1583 1916 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