File name: Pandora194s1_Tokyo-TMU_20241104_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20241105T132759.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20241104_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20241104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241103T215917.2Z 9073.916171 61 1 49.16 2 81.08 116.35 108.19 110.28 0.00 1 0.00 1 0 17 4.682e-01 1.497e-02 3.182e-01 8.527e-03 5.876998e-01 4.566575e-03 6.078382e-03 -6.000000e+00 2.626010e-01 225.10 -2.00 3.40 -2.00 321.70 0.00e+00 1.105176e-02 1.904473e-03 6.346345e-04 -6.000000e+00 1.075347e-02 285.05 -2.00 20.00 -2.00 321.32 0.00e+00 6.105 0.004 302.00 328.00 3 1.9102e+00 1.4169e-02 6.6732e-02 -6.0000e+00 6.5333e-01 1.4838e-01 1.9586e-02 3.0160e-02 -6.0000e+00 7.1528e-01 -3.2061e-01 2.2411e-02 1.6453e-02 -6.0000e+00 4.2133e-01 1.2389e-01 1.1021e-02 5.5075e-03 -6.0000e+00 1.7630e-01 1.1904e-04 -7.9538e-04 2.6500e-04 6.6807e-05 -6.0000e+00 1.2627e-02 -2.0902e-03 -9.5995e-05 12 8 8 10 0 0 99.80 17.17 0.62 -0.00209 -0.00807 51 11 1 5 0 963.760 21.06 15.00 17.17 19.95 20.7 1007.11 900000 -179079 -61081 -162713 -63434 -155117 -69581 86921 -162863 166404 -196155 178185 -146363 11955 -13959 -32955 -319 -62539 35601 -79966 93225 -35861 -15097 24546 11854 1002 -62905 -3446 -44761 44555 -6730 42425 23509 -11209 9796 -31017 22437 -43015 58103 25579 34368 19122 507 25043 -3404 21839 6066 4020 4507 18518 16592 5278 17748 702 19222 15375 9395 5167 2256 12794 -1251 18259 2379 8581 8802 6565 6061 3661 4597 265 1877 433 733 1829 736 4173 -3851 -2545 -4073 2848 -4217 614 246 -2194 877 -2511 962 -700 3252 222 -790 -1963 -6743 -1069 -5073 -1880 -431 289 1375 -792 521 -3013 -1611 -3966 -1032 -1738 -251 642 -430 639 354 1328 75 -651 -1012 -58 -326 482 878 210 1515 810 635 1046 -254 626 -505 886 -317 833 -183 348 -740 277 -106 -477 334 240 92 -356 17 -25 -656 900000 -4061 -508 -3321 -527 -2462 -579 723 -3201 1384 -5634 1482 -3651 99 -158 -548 -4 -1749 404 -3022 775 -867 -297 334 188 18 -2187 -65 -1286 573 -173 802 622 -449 304 -1407 644 -2764 1625 1160 1585 1099 37 1645 -306 1580 530 371 431 1632 1642 649 2095 106 2509 2135 1406 799 351 1787 -211 2824 493 1876 2012 1490 1351 855 1173 81 623 152 252 588 219 1079 -1012 -673 -1236 961 -1784 281 123 -1191 495 -1570 613 -469 2096 142 -476 -1117 -3857 -598 -3332 -1393 -366 279 1420 -831 503 -2718 -1331 -3443 -942 -1692 -255 696 -517 852 521 2024 114 -963 -1417 -78 -446 694 1345 338 2387 1244 948 1507 -357 844 -672 1238 -509 1482 -359 716 -1617 638 -263 -1246 886 649 247 -926 41 -58 -1516 SS 20241103T221043.6Z 9073.924115 66 1 15.32 2 79.02 118.20 106.12 111.67 0.00 1 0.00 1 0 17 3.308e-01 1.111e-02 2.056e-01 6.596e-03 5.018319e-01 3.392599e-03 5.409366e-03 -6.000000e+00 1.854796e-01 225.10 -2.00 3.40 -2.00 320.94 0.00e+00 7.223574e-03 1.207676e-03 3.925476e-04 -6.000000e+00 7.564607e-03 285.04 -2.00 20.00 -2.00 320.58 0.00e+00 5.059 0.002 302.00 328.00 3 2.2725e+00 9.9936e-03 5.5515e-02 -6.0000e+00 4.6146e-01 -3.3365e-02 1.2742e-02 2.5433e-02 -6.0000e+00 5.0502e-01 -8.3643e-02 1.3638e-02 1.3435e-02 -6.0000e+00 2.9756e-01 2.7951e-02 6.9674e-03 4.2868e-03 -6.0000e+00 1.2355e-01 2.4700e-04 -8.5584e-04 1.9952e-04 5.0631e-05 -6.0000e+00 8.8567e-03 -2.1577e-03 -1.1719e-04 12 9 9 12 1 1 99.89 17.17 0.57 -0.00216 -0.00859 18 13 1 5 0 805.670 21.06 15.00 17.17 20.54 20.9 1010.04 -132878 -59931 -124077 154619 -149187 -103920 -26327 -76492 -66571 -124895 -29701 -123315 -40965 -6513 -34605 -56299 -32434 -4029 -21465 -425 -33084 -11409 8664 4296 676 -17432 -8655 6924 -18485 -23105 1518 -12834 9837 16575 -19007 -9764 -12188 -7836 1500 -1388 -2385 -3087 949 -1858 6553 12224 18695 5351 1949 2249 6837 5670 1439 6220 2276 5206 40 -2353 -2727 -3558 2924 1794 8586 6174 4671 4876 1637 3483 2069 1265 541 1998 654 1302 144 -5440 -455 -3814 703 247 -194 -2302 -469 -1751 -907 339 -1351 926 -396 2124 -285 -912 -1796 -3114 -1077 -362 921 159 195 -963 -1189 -1740 -2337 -1347 -1856 -1908 -390 -287 774 627 1787 473 288 323 543 -363 182 305 -366 342 382 1355 709 466 120 -634 -193 104 81 -260 578 142 -491 -431 -346 -387 350 321 -129 57 48 -150 -356 -2176 -561 -2394 995 -3315 -1398 -169 -895 -779 -2775 -261 -3029 -551 -80 -708 -1883 -960 -98 -677 -11 -1277 -352 223 122 21 -673 -312 209 -713 -996 60 -685 481 810 -1271 -584 -815 -590 124 -140 -271 -379 118 -247 822 1494 2189 733 285 344 1095 1017 292 1296 517 1182 10 -587 -670 -881 711 488 2469 2021 1610 1612 540 1145 757 537 255 968 318 600 62 -2222 -165 -1430 280 116 -106 -1455 -316 -1264 -697 276 -1075 744 -323 1791 -229 -685 -1290 -2313 -872 -304 877 173 229 -1130 -1307 -1742 -2202 -1297 -1949 -2122 -452 -354 1029 923 2829 787 472 503 790 -512 259 458 -594 578 644 2201 1126 716 178 -912 -268 152 132 -471 1123 266 -966 -901 -773 -908 835 783 -315 133 108 -321 -753 SS 20241103T221630.2Z 9073.928127 69 1 49.36 2 77.99 119.16 105.08 112.38 0.00 1 0.00 1 0 17 2.060e-01 8.062e-03 6.573e-02 2.221e-03 4.673860e-01 1.136343e-03 4.989367e-03 -6.000000e+00 1.155359e-01 225.10 -2.00 3.40 -2.00 320.84 0.00e+00 6.165562e-03 3.968798e-04 3.411415e-04 -6.000000e+00 4.710043e-03 285.04 -2.00 20.00 -2.00 320.47 0.00e+00 4.658 0.002 302.00 328.00 3 1.3808e+00 3.2902e-03 5.1116e-02 -6.0000e+00 2.8745e-01 -8.0756e-02 4.1776e-03 2.3447e-02 -6.0000e+00 3.1454e-01 -2.0329e-02 4.4795e-03 1.2494e-02 -6.0000e+00 1.8534e-01 1.4535e-04 2.3115e-03 4.0200e-03 -6.0000e+00 7.6978e-02 9.1526e-04 -4.6573e-04 6.7797e-05 4.2471e-05 -6.0000e+00 5.5135e-03 -3.1467e-03 -5.0224e-05 11 8 0 10 0 0 99.39 17.17 0.40 -0.00315 -0.00665 195 42 1 5 0 253.080 21.06 15.00 17.17 21.03 20.9 1011.50 -70125 -36002 -58388 -29370 -77462 -45476 -93945 -70345 -64214 -70396 -52449 -62070 -52104 -52276 -21703 -16421 -9561 -13148 -18985 -5915 -22523 -6233 -13572 -6117 -11610 -17516 -9879 -21072 -9870 -19173 -9693 -6364 1618 -1450 -6973 -5040 -7730 -391 -5992 -3169 -634 -304 -500 -2765 1302 437 2242 835 3010 4541 3818 4127 4827 5048 2071 2667 -650 -629 447 -421 1434 3075 5502 4208 3572 2052 1162 661 1808 1810 169 1387 -59 -194 -696 -2189 -2393 -2988 -1342 -1339 -461 -1540 -1878 -1570 -1173 -81 550 977 1123 989 -62 -900 -1105 -1939 -635 -669 506 916 568 -237 -895 -1506 -1716 -1023 -1688 -1137 -1098 -466 468 692 1524 1041 932 31 -243 -436 -181 262 306 894 493 1005 468 248 -105 -709 -112 39 439 -41 -40 -402 -613 -335 -389 -285 176 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