File name: Pandora194s1_Tokyo-TMU_20241218_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20241218T145010.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20241218_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20241218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241217T222957.0Z 9117.937466 287 1 48.10 2 83.34 125.12 70.16 286.11 0.00 1 0.00 1 0 25 6.882e-01 4.683e-02 5.209e-01 3.703e-02 8.504266e-01 2.261836e-02 8.927842e-03 -6.000000e+00 4.119945e-01 223.77 -2.00 3.40 -2.00 322.26 0.00e+00 1.588727e-02 9.609627e-03 1.115081e-03 -6.000000e+00 1.910186e-02 280.70 -2.00 20.00 -2.00 321.93 0.00e+00 7.856 0.008 302.00 328.00 3 1.7374e+00 7.3440e-02 8.8321e-02 -6.0000e+00 1.0275e+00 1.3775e+00 8.5452e-02 4.2034e-02 -6.0000e+00 1.1244e+00 -1.8065e+00 7.3029e-02 2.2488e-02 -6.0000e+00 6.5358e-01 6.9017e-01 4.0314e-02 7.9110e-03 -6.0000e+00 2.7670e-01 1.6083e-05 -2.3170e-04 1.1500e-03 1.2130e-04 -6.0000e+00 1.9974e-02 1.0476e-02 -1.9771e-04 12 8 8 10 0 0 96.68 17.61 0.70 0.01048 0.00873 18 4 1 5 0 2671.680 21.27 14.99 17.61 9.86 20.3 999.63 217967 11005 181270 81472 900000 -4113 900000 900000 900000 900000 -60881 -43471 69346 900000 -26179 35827 900000 83339 900000 -79936 12452 116937 900000 900000 900000 900000 25361 59152 -88634 900000 129780 124590 900000 32674 106194 -80675 119438 290110 900000 63755 178731 900000 91131 -45278 6726 900000 -24120 900000 109840 225473 4036 19305 109974 99084 46160 37114 152493 194088 77823 40962 -42508 37437 -5183 63378 39826 57651 65147 22309 193701 -19221 33204 -2406 28675 5298 17391 23308 -9572 23284 -17703 16433 2666 10666 8170 -1351 14424 -4002 6907 -9559 23734 8565 1302 6003 -14556 -10052 -7024 -14559 1445 6273 10739 -8794 3100 -13331 7640 -8913 -2179 -7312 481 -4551 470 5249 1585 2520 -2342 3551 -74 -163 2667 -5006 -526 -2673 1966 761 8243 3442 -3805 -30 -4238 1907 557 926 -5 3614 856 -3582 1809 -1947 1435 -1083 1002 874 -1159 -627 900000 7841 561 6521 2931 900000 -148 900000 900000 900000 900000 -2373 -1564 2495 900000 -1648 1523 900000 2998 900000 -11502 652 4207 900000 900000 900000 900000 912 2128 -7536 900000 4669 4482 900000 1496 3820 -9498 4297 10436 900000 2502 6430 900000 3278 -5775 506 900000 -2524 900000 3951 8111 396 1768 4316 4536 3623 3156 5486 6982 3818 2813 -6951 3061 -746 5182 4298 5090 5326 2918 6968 -4777 5733 -543 4951 1048 2690 3018 -1653 3099 -4203 3370 738 3108 2645 -506 4878 -1713 2758 -4574 8026 3204 487 2030 -6022 -4339 -3462 -9270 931 4468 7919 -7782 2241 -10023 4260 -5996 -1473 -5498 358 -3913 438 5400 1910 3209 -3167 4419 -91 -200 3281 -7059 -751 -3961 2688 1002 9755 4160 -4819 -35 -5259 2483 868 1655 -11 7541 1966 -9252 4743 -5505 3984 -3117 2769 2273 -2848 -1430 900000 SS 20241217T225648.3Z 9117.956115 295 1 49.21 2 79.01 129.55 75.22 289.29 0.00 1 0.00 1 0 17 4.735e-01 8.473e-03 8.504e-02 1.980e-03 6.237288e-01 1.030250e-03 6.398517e-03 -6.000000e+00 2.638535e-01 223.77 -2.00 3.40 -2.00 321.48 0.00e+00 8.641717e-03 4.236964e-04 6.339592e-04 -6.000000e+00 1.082749e-02 280.70 -2.00 20.00 -2.00 321.12 0.00e+00 5.057 0.002 302.00 328.00 3 4.9155e-01 3.1135e-03 5.8385e-02 -6.0000e+00 6.5448e-01 -1.4717e-02 4.5472e-03 3.1506e-02 -6.0000e+00 7.1731e-01 -1.1404e-01 5.5069e-03 1.7730e-02 -6.0000e+00 4.2304e-01 3.9702e-02 2.6978e-03 5.9929e-03 -6.0000e+00 1.7585e-01 1.2667e-03 -6.1066e-04 5.8077e-05 6.2880e-05 -6.0000e+00 1.2679e-02 8.1986e-03 -1.1246e-04 11 8 0 10 0 0 21.28 17.61 0.39 0.00820 0.00361 392 85 1 5 0 125.510 21.27 15.00 17.61 11.70 20.4 1005.19 -163533 -135328 -140363 -156199 -138569 -182706 -142318 -143850 -129729 -130024 -129932 -129182 -122574 -82701 -91151 -58945 -50122 -29949 -26116 -29701 -24732 -48106 -26040 -54950 -42217 -34277 -34726 -25712 -44072 -19189 -31571 -7510 -13373 -1853 -16804 -12365 -5906 -11236 -1339 -7332 -226 -880 1843 4816 132 7931 649 6634 2599 4009 4215 5930 9132 4687 6162 2274 1793 -831 426 336 2849 4749 4349 7247 3182 3544 1466 1484 1865 2699 2850 1280 1152 147 -421 -2215 -3923 -3137 -2768 -102 -974 175 -2257 -988 -855 156 729 738 1617 823 662 -1465 -1683 -1781 -1452 -358 33 1020 352 -32 -1140 -1368 -1470 -1285 -1251 -1976 -1150 -681 246 666 1074 1129 576 -9 -863 -290 -537 181 486 472 753 750 743 318 80 -740 -104 503 159 357 15 -19 -584 -210 -323 -348 307 202 384 -13 -48 -184 -328 -1234 -926 -1109 -1425 -973 -1924 -1049 -1187 -1025 -1095 -1140 -1292 -1506 -914 -1424 -817 -730 -399 -367 -459 -373 -912 -407 -1215 -867 -680 -707 -474 -990 -411 -933 -212 -467 -62 -626 -437 -215 -512 -67 -463 -15 -63 136 360 11 616 56 565 242 396 464 718 1172 681 928 368 298 -141 69 55 477 875 924 1684 806 872 364 381 533 881 1018 482 426 52 -136 -654 -1114 -913 -918 -39 -443 89 -1286 -589 -545 105 514 535 1158 569 427 -903 -1005 -1117 -1031 -293 31 1093 407 -37 -1225 -1322 -1322 -1190 -1251 -2100 -1285 -815 322 886 1565 1716 872 -13 -1196 -426 -808 285 740 741 1162 1113 1177 489 119 -1067 -146 755 273 624 28 -38 -1245 -475 -785 -881 788 527 992 -31 -113 -407 -720 SS 20241217T230242.5Z 9117.960214 298 1 49.22 2 78.09 130.56 76.32 290.00 0.00 1 0.00 1 0 25 4.032e-01 8.221e-03 6.231e-02 1.526e-03 5.862990e-01 7.932756e-04 6.113997e-03 -6.000000e+00 2.246956e-01 223.77 -2.00 3.40 -2.00 321.31 0.00e+00 7.720456e-03 3.146290e-04 5.427713e-04 -6.000000e+00 9.220630e-03 280.70 -2.00 20.00 -2.00 320.94 0.00e+00 4.697 0.002 302.00 328.00 3 4.7092e-01 2.3722e-03 5.4403e-02 -6.0000e+00 5.5735e-01 -5.7342e-02 3.3082e-03 2.9480e-02 -6.0000e+00 6.1086e-01 -5.6628e-02 3.9148e-03 1.6362e-02 -6.0000e+00 3.6026e-01 1.5922e-02 1.9466e-03 5.4549e-03 -6.0000e+00 1.4975e-01 1.8872e-03 -5.3514e-04 4.5321e-05 5.9359e-05 -6.0000e+00 1.0797e-02 8.1991e-03 -1.1433e-04 11 8 0 10 0 0 15.45 17.62 0.38 0.00820 0.00418 490 106 1 5 0 100.430 21.27 14.98 17.62 12.67 20.3 1006.96 -127020 -146124 -100010 -126588 -138196 -135098 -155657 -121008 -147918 -105780 -100128 -100600 -86624 -81811 -34600 -46570 -32501 -39794 -26335 -14589 -20522 -6805 -23067 -18333 -32772 -20740 -33788 -24119 -28023 -24023 -9239 -9421 -4660 -10466 -11696 -11715 -6072 -3762 -988 1943 -5125 -954 -3534 3769 2533 3797 3390 3686 4186 2231 4904 4123 6167 5493 3931 3659 -1557 -368 -2265 250 956 3274 6063 5462 4945 1533 1552 11 1504 2080 1846 1774 647 237 -1746 -1857 -3910 -2675 -1559 -661 -772 -1034 -1420 -1708 -919 -90 441 1258 1180 1351 465 -847 -2038 -1805 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