File name: Pandora194s1_Tokyo-TMU_20250106_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20250106T145601.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20250106_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20250106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250105T232515.8Z 9136.975878 82 1 49.07 2 75.37 132.33 118.45 66.19 0.00 1 0.00 1 0 17 2.185e-01 8.287e-03 8.320e-02 2.823e-03 4.908390e-01 1.438442e-03 5.274380e-03 -6.000000e+00 1.219431e-01 224.06 -2.00 3.40 -2.00 320.73 0.00e+00 6.450171e-03 4.937393e-04 3.433958e-04 -6.000000e+00 4.997637e-03 279.78 -2.00 20.00 -2.00 320.37 0.00e+00 3.880 0.001 302.00 328.00 3 2.6292e+00 4.1428e-03 4.5005e-02 -6.0000e+00 3.0267e-01 -7.7780e-02 5.2171e-03 2.4280e-02 -6.0000e+00 3.3161e-01 -5.0585e-03 5.5449e-03 1.2966e-02 -6.0000e+00 1.9554e-01 -7.1616e-03 2.8730e-03 4.1470e-03 -6.0000e+00 8.1266e-02 5.1390e-04 -4.2514e-04 8.4426e-05 4.4190e-05 -6.0000e+00 5.8508e-03 5.4301e-03 -1.1649e-04 11 8 0 10 0 0 99.50 17.58 0.45 0.00543 0.00224 83 18 1 5 0 591.110 21.27 15.01 17.58 12.50 20.2 1008.22 -109520 -49006 -79838 -78162 -34183 -89047 -53817 -75294 -47718 -50468 -45607 -78792 -39572 -32897 -18410 -7289 -29552 -9315 -25306 4186 -5516 -6705 -7425 -9462 -9787 -29148 -10378 -22025 -12192 -10022 -1582 -2137 -5856 78 -13848 -3017 -5062 -1231 -2621 -3466 -39 -2269 1354 -2303 4479 875 5153 2026 1231 7040 2254 3511 3160 4028 3090 770 158 -1706 63 -497 1462 1686 6211 4346 2034 3724 -1105 1806 -63 1346 967 800 90 -441 83 -3190 -743 -3813 -1445 -885 -731 -776 -1658 -1229 -1190 -105 192 919 1137 762 621 -445 -861 -1495 -841 -985 650 1163 344 -329 -1395 -1330 -1965 -723 -1536 -940 -831 -611 350 667 1434 857 1049 279 -469 -182 -426 625 284 518 667 784 781 -219 -124 -838 -26 -33 440 117 -48 -115 -996 31 -421 -244 90 226 274 131 59 -282 -32 -1535 -442 -1059 -998 -257 -1114 -498 -961 -514 -594 -525 -1400 -594 -593 -359 -151 -944 -267 -920 120 -179 -220 -251 -346 -380 -1437 -432 -1007 -500 -430 -73 -116 -377 5 -980 -189 -357 -99 -258 -407 -5 -313 190 -347 645 134 773 321 202 1148 423 718 703 954 772 203 43 -467 17 -132 399 509 2021 1593 784 1349 -406 655 -26 621 490 422 47 -220 38 -1354 -287 -1526 -629 -450 -428 -511 -1189 -927 -962 -90 173 844 1039 670 507 -340 -627 -1123 -698 -938 697 1274 405 -384 -1677 -1445 -2019 -761 -1766 -1133 -1056 -750 463 969 2235 1382 1651 418 -662 -246 -588 901 439 833 1067 1215 1175 -320 -174 -1249 -37 -50 674 198 -87 -219 -1994 66 -949 -573 215 550 663 306 130 -599 -66 SS 20250105T234629.7Z 9136.990621 92 1 48.99 2 72.29 136.29 114.54 69.86 0.00 1 0.00 1 0 17 1.231e-01 8.219e-03 8.597e-02 4.185e-03 4.170184e-01 2.084582e-03 4.579466e-03 -6.000000e+00 6.869120e-02 224.06 -2.00 3.40 -2.00 320.23 0.00e+00 4.007067e-03 6.250798e-04 2.473050e-04 -6.000000e+00 2.814812e-03 279.78 -2.00 20.00 -2.00 319.89 0.00e+00 3.241 0.000 302.00 328.00 3 3.8432e+00 5.8413e-03 3.7809e-02 -6.0000e+00 1.7050e-01 -9.0298e-02 7.0309e-03 2.0577e-02 -6.0000e+00 1.8679e-01 3.3828e-02 6.7997e-03 1.0725e-02 -6.0000e+00 1.1014e-01 -2.3541e-02 3.6154e-03 3.3149e-03 -6.0000e+00 4.5782e-02 3.0131e-04 -1.7483e-04 1.2510e-04 3.6460e-05 -6.0000e+00 3.2953e-03 4.7113e-03 -1.0150e-04 11 8 0 10 0 0 99.95 17.66 0.51 0.00471 0.00340 56 12 1 5 0 874.690 21.27 15.00 17.66 13.12 20.3 1007.09 -56590 1810 -48171 -4661 -54790 -47519 -29324 -50939 -18706 -50524 -19291 -17604 -16917 -32557 -9313 -5462 -14571 -3194 -12368 2710 -4242 -2861 -6930 3100 -385 -11249 133 -5197 16011 -11531 -430 -1192 52 -300 -2637 -3895 -2555 -1226 -5226 -990 -200 -2705 -3880 -2264 1225 -887 3120 2947 2596 746 345 3915 -182 3016 2261 2860 1289 -2849 921 -1230 2691 1361 4525 2330 2470 1131 -1232 906 1050 1293 901 1353 55 104 -590 -1094 -2357 -3658 -722 -643 -689 -803 -1596 -1262 -1644 292 -52 1095 1099 281 943 -568 -948 -1884 -456 -1188 765 1672 403 -741 -1552 -1421 -1383 -255 -1046 -1442 -761 -591 416 400 1460 650 1218 27 -492 -362 -833 489 430 553 507 898 185 415 415 -384 -448 -498 495 -142 -369 -205 -627 -246 -280 -82 241 493 326 -71 8 -217 -342 -945 19 -912 -55 -976 -758 -413 -1002 -298 -1181 -336 -327 -377 -1051 -290 -191 -611 -129 -587 128 -222 -147 -382 165 -22 -767 8 -327 791 -781 -29 -94 5 -28 -239 -353 -251 -141 -757 -162 -36 -531 -808 -476 252 -190 648 618 554 169 85 1021 -53 914 719 930 435 -998 304 -415 913 514 1847 1061 1141 500 -533 386 489 688 526 819 33 60 -316 -529 -1066 -1662 -349 -361 -442 -577 -1242 -1032 -1450 270 -51 1089 1091 269 832 -468 -737 -1495 -393 -1168 837 2031 526 -957 -1878 -1561 -1437 -274 -1225 -1786 -986 -810 607 638 2242 1026 2041 44 -732 -515 -1210 739 697 938 860 1480 298 641 613 -547 -618 -719 781 -246 -683 -393 -1250 -469 -570 -174 523 1086 716 -151 17 -423 -660 SS 20250105T235211.1Z 9136.994573 95 1 49.39 2 71.49 137.39 113.48 70.80 0.00 1 0.00 1 0 17 1.242e-01 8.309e-03 1.034e-01 4.497e-03 4.019139e-01 2.258999e-03 4.398503e-03 -6.000000e+00 6.937161e-02 224.07 -2.00 3.40 -2.00 320.25 0.00e+00 3.045149e-03 6.680488e-04 2.276635e-04 -6.000000e+00 2.841189e-03 279.78 -2.00 20.00 -2.00 319.89 0.00e+00 3.111 0.000 302.00 328.00 3 3.9198e+00 6.3447e-03 3.6281e-02 -6.0000e+00 1.7219e-01 -9.5349e-02 7.5718e-03 1.9692e-02 -6.0000e+00 1.8861e-01 3.7267e-02 7.1722e-03 1.0252e-02 -6.0000e+00 1.1122e-01 -2.4186e-02 3.8192e-03 3.1851e-03 -6.0000e+00 4.6249e-02 3.2258e-04 3.1563e-04 1.3751e-04 3.4968e-05 -6.0000e+00 3.3260e-03 3.5207e-03 -1.4462e-05 11 8 0 10 0 0 100.00 17.69 0.26 0.00352 0.00589 93 20 1 5 0 530.960 21.38 15.01 17.69 13.48 20.3 1007.50 -46281 14247 -48930 3292 -52208 33661 -57700 46958 -30045 3405 -36172 -46119 -28271 -14650 -7012 2873 -7849 -7704 -3645 -1863 -5304 8591 -14741 8038 -3825 -3598 -3639 -13467 -8380 -11985 2544 -4083 5034 -11043 -4585 -3643 -8341 292 -2685 815 -1775 -613 -1029 1111 728 594 1994 1435 911 870 1940 2542 569 2942 1021 2644 -2146 698 -1569 -493 2696 2636 4796 2362 3622 -264 -355 -366 2311 2015 845 1758 -406 1392 -1175 -1016 -1699 -4280 -352 -1223 -342 -1006 -1414 -1791 -1232 -181 263 777 99 1448 370 -1046 -950 -1840 -418 -488 445 820 536 -722 -872 -1265 -1954 -515 -1887 -931 -1579 448 88 735 1082 851 1253 -535 6 -280 -185 136 590 608 -74 1306 109 14 96 -401 235 302 473 -112 -378 -537 -284 -202 -433 -125 351 141 -98 362 1 10 -421 -793 153 -1053 41 -1020 268 -1219 393 -611 53 -851 -1287 -789 -438 -235 101 -335 -353 -171 -91 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