File name: Pandora243s1_Toronto-CNTower_20240930_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20241016T160455.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20240930_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20240930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240930T114656.4Z 9039.490931 119 1 29.86 2 85.03 99.10 61.99 106.71 0.00 1 0.00 1 0 25 6.694e-01 4.495e-02 4.189e-01 3.352e-02 9.176776e-01 1.860608e-02 1.033124e-02 -6.000000e+00 3.792947e-01 227.07 -2.00 3.56 -2.00 322.05 0.00e+00 2.178803e-03 7.766164e-03 8.215911e-04 -6.000000e+00 1.686054e-02 282.19 -2.00 20.00 -2.00 321.50 0.00e+00 9.859 0.018 302.00 328.00 3 -5.9811e-01 6.3689e-02 1.0733e-01 -6.0000e+00 9.4226e-01 1.9251e+00 7.6002e-02 4.9810e-02 -6.0000e+00 1.0262e+00 -1.9116e+00 4.9143e-02 2.3805e-02 -6.0000e+00 6.1069e-01 6.5690e-01 2.5862e-02 8.2694e-03 -6.0000e+00 2.5877e-01 2.4382e-05 -9.1517e-04 8.7137e-04 1.0455e-04 -6.0000e+00 1.7915e-02 3.5339e-03 0.0000e+00 12 8 8 10 0 0 32.36 27.45 2.68 0.00353 -0.00334 23 23 1 5 0 1298.260 35.75 19.99 27.45 24.11 3.5 943.71 -834 17439 122379 130855 -79462 279860 21666 1511 -58517 17578 -11496 6224 -40357 126659 36694 96513 39390 188996 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3898 3167 -1717 11 4410 723 -5163 5696 -3051 5440 1707 2586 5563 5741 3395 9202 -1006 631 -1818 -8882 3126 2215 1267 -4483 -4194 -2062 -1983 7005 7165 3247 3275 7773 4014 75 165 -17356 -1279 -13107 64 1156 5605 -1912 2816 -3581 -5495 -3301 -6298 2888 3511 2142 825 -2179 2078 1006 -1774 274 -3029 2460 -1493 -3477 90 -6882 4123 7494 -258 4617 -1110 1089 -2216 1136 38 1340 1624 4794 685 -4286 -2524 2224 1028 3494 3795 -4331 -1719 2822 202 -6359 SS 20240930T115652.7Z 9039.497832 122 1 29.98 2 83.26 100.84 60.33 108.71 0.00 1 0.00 1 0 17 4.251e-01 1.809e-02 1.594e-01 6.488e-03 8.031229e-01 3.546077e-03 9.152804e-03 -6.000000e+00 2.403008e-01 227.07 -2.00 3.56 -2.00 321.88 0.00e+00 7.714759e-03 1.967197e-03 2.207329e-03 -6.000000e+00 1.065375e-02 282.19 -2.00 20.00 -2.00 321.38 0.00e+00 7.768 0.009 302.00 328.00 3 -2.9259e-01 1.3334e-02 8.6650e-02 -6.0000e+00 5.9618e-01 7.5410e-01 1.7896e-02 4.4879e-02 -6.0000e+00 6.4845e-01 -9.9330e-01 1.6135e-02 2.4467e-02 -6.0000e+00 3.8629e-01 3.9689e-01 7.5164e-03 1.0464e-02 -6.0000e+00 1.6431e-01 1.9005e-04 -1.1189e-03 1.7268e-04 1.5728e-04 -6.0000e+00 1.1376e-02 1.7915e-03 0.0000e+00 12 9 8 11 8 0 9.39 27.38 0.90 0.00179 -0.00662 120 120 1 5 0 249.760 35.75 20.00 27.38 24.34 3.5 945.79 -131423 -151797 -105503 -102413 -126087 -172581 -88453 -135760 -100321 -141640 -38829 -162133 -100843 -63385 -47119 -39604 -37150 -23204 -10281 635 22493 -26260 -33570 -25710 1609 -25863 -21865 -48718 3637 -36105 -47304 -13877 45132 4735 28039 -24539 -19346 -22302 44540 26445 26991 19120 41252 25048 -550 34015 36347 20523 41501 39913 25423 23048 22588 30503 26984 23997 25720 14310 8943 8452 12184 14777 9680 15111 14420 19536 10544 13693 8472 8057 9494 5565 8489 6296 -1384 -1172 -2220 -4775 -95 -1082 -520 826 -1595 -1471 642 1481 727 2273 348 1931 -778 -1921 -5097 -4093 -4931 -2962 -1629 -1146 -663 -1160 -2951 -952 -2158 -2194 -3153 -2174 -2103 485 -1322 180 210 167 235 -189 -736 -186 -838 -270 -235 292 408 2037 2174 1585 1364 1556 1101 961 408 315 294 792 355 129 117 353 163 -111 60 -194 -822 -746 -1286 -3175 -4889 -2124 -1767 -2393 -4963 -1119 -2889 -1558 -3340 -335 -5689 -2494 -1385 -1084 -980 -983 -574 -231 13 349 -634 -888 -651 31 -736 -581 -1603 71 -1211 -2185 -544 1114 177 763 -1118 -918 -1270 1550 1272 1400 1125 2010 1442 -41 1829 1955 1350 2337 2475 2043 2100 2244 3011 2868 2687 2848 1720 1081 1005 1457 1926 1531 2562 2564 3239 1935 2564 1876 2054 2583 1609 2299 1605 -341 -257 -472 -1103 -25 -342 -193 346 -749 -730 333 808 417 1310 203 1059 -408 -965 -2615 -2230 -3142 -2193 -1403 -1141 -650 -1134 -3009 -849 -1770 -1825 -2857 -2059 -2121 520 -1471 226 299 254 362 -286 -1070 -262 -1210 -409 -378 481 656 3071 3161 2243 1870 2068 1439 1348 669 592 616 1637 784 305 299 941 443 -307 164 -507 -2012 -1705 -2848 SS 20240930T120710.6Z 9039.504983 125 1 29.92 2 81.43 102.67 58.64 110.84 0.00 1 0.00 1 0 25 5.121e-01 9.519e-03 6.437e-02 2.137e-03 7.009268e-01 1.125712e-03 8.120945e-03 -6.000000e+00 2.894559e-01 227.06 -2.00 3.56 -2.00 321.10 0.00e+00 3.139599e-03 5.273200e-04 2.237358e-03 -6.000000e+00 1.283318e-02 282.19 -2.00 20.00 -2.00 320.54 0.00e+00 6.329 0.005 302.00 328.00 3 -3.4338e-01 3.7259e-03 7.1768e-02 -6.0000e+00 7.1814e-01 1.9524e-01 5.0748e-03 3.9446e-02 -6.0000e+00 7.8109e-01 -2.5425e-01 5.1295e-03 2.1223e-02 -6.0000e+00 4.6531e-01 9.5744e-02 2.4640e-03 7.0094e-03 -6.0000e+00 1.9792e-01 8.8832e-04 -5.4319e-04 5.6718e-05 9.6267e-05 -6.0000e+00 1.3703e-02 1.8855e-03 0.0000e+00 12 8 8 10 0 0 17.28 27.42 0.71 0.00189 -0.00220 169 169 1 5 0 177.020 35.75 20.00 27.42 24.78 3.5 948.47 -186624 -160714 -171238 -185485 -164010 -172263 -183374 -165018 -133077 -141621 -145363 -114788 -117646 -97535 -68982 -19463 -25457 -46251 -14690 -28601 -29994 -42909 -30221 -10155 -40287 -30910 -26010 -8110 -38989 -10603 -20535 -12278 -13116 -735 -7125 -15021 -12561 -5505 -2067 2552 2227 1506 5101 4671 1714 3626 2735 1741 -186 3105 6251 3707 6230 3629 4543 4058 3592 4489 3190 2455 2604 4821 6280 5399 3084 3561 1679 2838 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