File name: Pandora243s1_Toronto-CNTower_20241102_L2Fit_fwvt1c3d20240624p1-8.txt File generation date: 20241103T055036.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20241102_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20241102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241102T120432.8Z 9072.503157 39 1 30.01 2 89.29 111.68 101.36 109.96 0.00 1 0.00 1 0 22 6.561e-03 6.516e-03 1.652e-04 1.646e-04 1.267253e+04 1.121647e+01 8.303982e+02 -6.000000e+00 3.612565e+02 277.97 -2.00 20.00 -2.00 505.42 0.00e+00 2.723212e-03 4.539069e-06 1.633628e-04 -6.000000e+00 1.824448e-04 277.97 -2.00 20.00 -2.00 501.05 0.00e+00 1.038363e+00 3.172968e-03 9.993551e-02 -6.000000e+00 1.300805e-01 223.63 -2.00 3.56 -2.00 502.55 0.00e+00 19.431 0.142 489.00 513.00 1 6.5339e-01 2.4248e-04 3.4412e-02 -6.0000e+00 9.9701e-03 -3.5625e-02 6.0675e-05 2.9448e-03 -6.0000e+00 2.5722e-03 6.2374e-02 1.1017e-03 1.5968e-05 1.1881e-04 -6.0000e+00 6.9179e-04 -1.8636e-03 1.6024e-05 12 8 8 10 0 0 88.90 27.34 6.68 -0.00186 0.00578 437 437 1 4 0 68.650 35.75 20.00 27.34 8.42 3.9 835.37 -1040 -846 -381 115 550 1033 1252 1219 1133 908 578 304 -60 -320 -450 -513 -241 69 275 295 342 463 507 589 685 627 476 326 -116 -673 -987 -896 -653 -162 23 41 50 47 -175 -348 -207 -117 79 379 568 631 600 424 133 -248 -704 -1065 -1241 -1140 -704 -280 -11 208 416 548 635 700 722 670 608 385 118 -109 -340 -563 -791 -757 -590 -398 -239 -435 -703 -841 -914 -1001 -1134 -1032 -970 -885 -654 -649 -634 -618 -533 -456 -171 77 350 547 467 405 154 -226 -599 -1167 -1482 -1238 -882 -429 -205 -270 -295 -317 -349 -260 -60 183 459 808 1149 1331 1528 1534 1200 821 636 458 459 645 707 509 556 609 485 515 483 53 -249 -344 -554 -496 -174 -92 32 337 385 332 436 424 381 241 34 -447 -843 -1028 -931 -922 -759 -345 105 512 964 1190 1154 1076 857 549 286 -56 -296 -416 -477 -226 65 266 286 334 453 498 573 671 617 468 319 -111 -645 -932 -846 -628 -158 23 41 50 47 -173 -343 -204 -116 78 380 575 633 603 423 133 -244 -690 -1025 -1201 -1109 -687 -277 -11 210 423 557 637 707 733 682 617 388 119 -109 -337 -554 -775 -742 -582 -398 -237 -433 -704 -830 -891 -986 -1102 -1009 -956 -880 -648 -650 -638 -621 -534 -457 -172 77 353 552 465 399 150 -217 -565 -1105 -1401 -1166 -843 -421 -206 -275 -303 -324 -354 -265 -61 188 477 833 1187 1383 1603 1608 1270 868 664 478 473 663 730 531 575 633 505 536 501 55 -259 -355 -574 -512 -183 -98 34 363 415 362 473 463 417 263 37 -486 -905 -1098 -1000 SQ 20241102T120719.2Z 9072.505083 43 1 29.98 2 88.82 112.16 100.91 110.39 0.00 1 0.00 1 0 22 5.412e-03 5.381e-03 1.276e-04 1.273e-04 1.087337e+04 8.550332e+00 7.210622e+02 -6.000000e+00 2.980045e+02 277.97 -2.00 20.00 -2.00 505.40 0.00e+00 2.313466e-03 3.507370e-06 1.389734e-04 -6.000000e+00 1.504997e-04 277.97 -2.00 20.00 -2.00 500.97 0.00e+00 1.092560e+00 2.463936e-03 8.591615e-02 -6.000000e+00 1.073019e-01 223.63 -2.00 3.56 -2.00 502.49 0.00e+00 18.334 0.119 489.00 513.00 1 2.9985e-01 1.8841e-04 3.1149e-02 -6.0000e+00 8.2243e-03 -2.6302e-02 4.7226e-05 2.5873e-03 -6.0000e+00 2.1217e-03 1.0363e-01 9.5505e-04 1.2456e-05 1.0284e-04 -6.0000e+00 5.7067e-04 -5.4573e-04 1.0272e-05 12 8 8 10 0 0 48.31 27.34 5.34 -0.00055 0.00608 701 701 1 4 0 42.760 35.75 20.01 27.34 8.56 3.9 836.37 -841 -695 -344 33 365 793 1068 964 902 745 450 209 -55 -244 -387 -413 -177 82 228 196 259 409 433 499 568 506 375 286 -96 -540 -790 -692 -534 -100 30 -2 58 60 -153 -272 -188 -89 87 317 458 514 499 350 127 -210 -600 -882 -1063 -934 -575 -247 -33 173 308 448 536 600 593 550 504 336 103 -116 -259 -496 -652 -602 -494 -296 -194 -374 -603 -675 -738 -812 -939 -853 -822 -696 -542 -571 -524 -489 -431 -354 -104 58 322 456 415 339 110 -189 -471 -939 -1232 -1057 -764 -356 -182 -274 -283 -275 -297 -194 -11 143 363 673 933 1109 1286 1266 996 686 532 436 367 529 592 371 420 503 382 447 422 32 -212 -266 -451 -383 -106 -59 34 285 304 282 346 380 323 203 -4 -397 -759 -862 -776 -756 -623 -317 31 346 757 1021 934 876 719 430 198 -52 -230 -364 -391 -167 80 222 191 255 403 428 495 559 500 371 280 -95 -525 -757 -662 -513 -98 29 -2 58 60 -151 -268 -185 -89 88 318 465 524 509 354 127 -210 -593 -854 -1020 -899 -565 -245 -33 174 311 453 543 611 600 557 509 341 104 -116 -258 -490 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9.0727e-05 -6.0000e+00 4.6264e-04 1.2093e-03 -3.8768e-06 11 8 0 10 0 0 60.80 27.35 4.18 0.00121 0.00773 541 541 1 4 0 27.700 35.75 20.00 27.35 8.87 3.8 837.93 -682 -510 -309 2 250 633 803 756 698 598 367 192 -42 -218 -338 -348 -169 68 163 137 169 339 372 424 468 442 285 210 -42 -404 -593 -489 -371 -13 -39 -93 10 62 -103 -193 -140 -83 86 254 352 426 429 270 100 -164 -472 -702 -871 -782 -456 -237 -70 89 230 378 458 510 482 443 409 268 67 -99 -193 -369 -533 -430 -374 -231 -138 -301 -534 -533 -574 -641 -762 -702 -690 -580 -401 -454 -407 -401 -345 -285 -57 66 296 333 293 271 102 -136 -356 -761 -1040 -847 -594 -295 -173 -286 -242 -189 -242 -157 -26 64 296 555 783 904 1068 1029 823 569 455 359 333 467 477 308 307 424 320 380 356 23 -194 -209 -384 -315 -77 -49 -19 250 257 246 315 296 270 156 -11 -358 -647 -753 -644 -616 -467 -286 2 240 612 780 743 687 584 355 186 -40 -207 -320 -331 -163 67 160 135 167 337 370 424 465 441 285 208 -42 -394 -569 -469 -362 -13 -39 -94 10 62 -103 -193 -140 -83 86 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