File name: Pandora243s1_Toronto-CNTower_20241119_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20241120T051058.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20241119_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20241119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241119T150356.9Z 9089.627742 397 1 29.87 2 68.95 149.92 76.62 294.19 0.00 1 0.00 1 0 17 1.250e-01 2.875e-02 1.296e-01 2.561e-02 3.223403e-01 1.256417e-02 3.938093e-03 -6.000000e+00 6.945169e-02 222.46 -2.00 3.56 -2.00 318.56 0.00e+00 4.200374e-03 2.483791e-03 4.506886e-04 -6.000000e+00 3.051607e-03 275.83 -2.00 20.00 -2.00 317.97 0.00e+00 2.758 0.000 302.00 328.00 3 6.3709e+00 3.3591e-02 3.0999e-02 -6.0000e+00 1.7090e-01 2.3943e-01 3.8462e-02 1.6601e-02 -6.0000e+00 1.8668e-01 -9.4526e-02 2.5178e-02 8.7033e-03 -6.0000e+00 1.1119e-01 4.4605e-02 1.3067e-02 4.1695e-03 -6.0000e+00 4.7502e-02 3.9813e-05 -9.0081e-04 7.3451e-04 3.5776e-05 -6.0000e+00 3.3412e-03 5.7099e-04 0.0000e+00 12 8 8 10 0 0 85.06 27.26 -0.91 0.00057 -0.00620 8 8 1 5 0 3732.870 35.75 20.00 27.26 12.48 3.7 862.15 8459 66848 -37332 -39333 24824 -14977 -33994 -19759 10592 -8436 -1798 -44444 -28223 -4601 17722 -14906 2234 23042 3329 44552 29030 12330 8581 27802 16829 -11872 6138 18048 -2342 -1547 4000 3655 1458 12052 -4689 33000 -4188 -6935 -12652 -5856 2270 5507 1138 10395 7659 2278 -1448 4224 9732 -7130 -3421 1388 2033 3275 5364 2703 -1877 -5526 4660 6861 651 6888 825 -210 -2789 -4994 1374 -1108 3142 -5492 475 521 1209 1381 20 -7976 -442 -4797 -3443 -1202 1072 -5815 -1195 734 -2331 1812 -987 2706 -2572 345 1167 -1717 6129 2492 -4838 -125 1535 4317 3070 -197 -2307 -5213 -1706 4900 690 -2667 -4533 194 340 2262 2628 102 780 1425 3150 -2201 -2270 -4345 2028 435 768 2425 1955 -497 895 -3384 2786 -2616 2394 104 -3225 247 -3089 -468 543 58 2589 -201 765 -1799 1112 1456 -1944 528 2733 -4324 -4198 1240 -1088 -3165 -1750 746 -728 -143 -5854 -3717 -564 2012 -2573 340 2983 544 4958 3758 1848 1364 3788 2637 -2534 1073 2623 -399 -270 727 730 324 2408 -1022 4946 -1008 -2000 -4597 -2274 871 2126 473 3966 3009 947 -615 1669 3602 -3190 -1577 652 1002 1673 2741 1437 -1053 -3162 2349 3381 356 3848 536 -147 -1969 -3323 808 -662 1948 -4203 370 417 947 1025 15 -5857 -275 -3032 -2314 -901 884 -5665 -1180 743 -2366 2068 -1214 3285 -3276 407 1254 -1733 5282 2197 -4942 -135 1837 5585 4233 -273 -3043 -6459 -1918 5348 851 -3571 -6465 278 513 3594 4405 178 1296 2189 4367 -3034 -3136 -6404 2999 691 1228 3731 2935 -730 1227 -4616 3396 -3411 3206 154 -5188 395 -5208 -799 973 109 4851 -395 1489 -3470 1991 2488 -3341 SS 20241119T164402.1Z 9089.697246 458 1 5.18 2 63.48 174.98 91.50 309.70 0.00 1 0.00 1 0 17 3.246e-02 1.149e-02 3.137e-02 1.011e-02 2.809336e-01 4.949118e-03 3.430734e-03 -6.000000e+00 1.803673e-02 222.46 -2.00 3.56 -2.00 317.22 0.00e+00 -1.866947e-03 6.972920e-04 2.658330e-04 -6.000000e+00 7.923537e-04 275.83 -2.00 20.00 -2.00 316.61 0.00e+00 2.227 0.000 302.00 328.00 3 4.6481e+00 1.2919e-02 2.5626e-02 -6.0000e+00 4.4384e-02 6.7418e-02 1.4596e-02 1.4543e-02 -6.0000e+00 4.8480e-02 -9.6579e-03 8.8564e-03 7.1238e-03 -6.0000e+00 2.8873e-02 9.8620e-05 4.4240e-03 2.5451e-03 -6.0000e+00 1.2338e-02 4.2431e-04 -2.4064e-04 2.8436e-04 2.6111e-05 -6.0000e+00 8.6752e-04 -9.5940e-04 0.0000e+00 12 9 9 12 1 1 999.00 27.23 0.71 -0.00096 -0.00277 1 12 1 5 0 2587.560 35.75 20.00 27.23 13.43 3.6 868.72 7167 3342 -5644 -10135 -6168 3595 5255 -3527 -10411 12555 -7754 -5277 -11000 3751 -7678 321 10856 3438 985 -6520 2035 3214 7692 3196 -338 -1786 1770 -641 -7933 3413 2238 -3103 -3746 -1314 -4811 1944 7943 -43 1404 -2466 -986 -1997 -750 2602 -53 -2521 -245 1194 -656 1756 834 -784 1047 2361 942 -427 352 1011 2848 2804 -17 1611 880 -244 1085 -384 1393 500 445 -608 694 -1043 -1160 1029 610 -1494 -1382 -2133 -1833 -1979 -1790 -1010 -2156 -424 -367 913 1058 1827 1972 -1771 -160 467 -404 -1838 1364 -1043 345 238 376 -437 -263 -644 -1207 -416 -1117 285 -996 -862 489 1074 -323 -6 -676 -142 633 259 1253 296 -177 798 -1078 -324 1311 1037 1188 1380 -10 351 495 45 -1329 -284 389 292 302 532 -247 -463 837 -249 -741 -1440 239 742 382 -701 -1189 -626 333 528 -441 -1549 1534 -1146 -806 -2016 677 -1756 73 2300 817 249 -1831 527 820 1971 920 -97 -538 553 -189 -2345 908 646 -1022 -1222 -458 -1612 617 2662 -17 653 -1376 -584 -1136 -431 1573 -33 -1581 -146 687 -378 1009 517 -485 673 1578 658 -310 257 726 1958 1918 -12 1249 747 -205 949 -313 1047 376 363 -526 642 -1015 -1117 926 549 -1227 -1032 -1549 -1418 -1738 -1625 -1002 -2296 -466 -402 1054 1279 2248 2412 -2143 -188 499 -401 -1824 1404 -1218 411 314 519 -591 -331 -749 -1440 -515 -1406 371 -1375 -1246 687 1601 -515 -10 -1046 -203 882 342 1640 409 -246 1167 -1629 -478 1853 1505 1630 1801 -13 445 675 67 -1940 -422 584 457 503 868 -416 -798 1429 -417 -1197 -2406 384 SS 20241119T173853.7Z 9089.735344 493 1 9.16 2 63.86 189.38 98.37 319.24 0.00 1 0.00 1 0 17 3.230e-02 1.090e-02 3.522e-02 1.015e-02 2.797966e-01 4.980566e-03 3.426748e-03 -6.000000e+00 1.794674e-02 222.46 -2.00 3.56 -2.00 317.57 0.00e+00 7.708189e-04 7.604964e-04 1.213953e-04 -6.000000e+00 7.883447e-04 275.82 -2.00 20.00 -2.00 316.97 0.00e+00 2.257 0.000 302.00 328.00 3 5.1736e+00 1.3049e-02 2.5827e-02 -6.0000e+00 4.4163e-02 1.0628e-01 1.4753e-02 1.4255e-02 -6.0000e+00 4.8237e-02 -2.8641e-02 9.1047e-03 7.1129e-03 -6.0000e+00 2.8728e-02 3.6843e-03 4.6005e-03 2.1126e-03 -6.0000e+00 1.2277e-02 2.3966e-04 -1.7212e-04 2.8956e-04 2.3129e-05 -6.0000e+00 8.6313e-04 -1.4915e-03 0.0000e+00 12 9 9 12 1 1 999.00 27.25 1.34 -0.00149 -0.00278 2 10 1 5 0 3052.380 35.75 20.00 27.25 13.78 3.7 871.82 4419 -9145 2635 -10355 -9720 20576 -2087 -6556 1696 1477 -3380 3072 1097 2958 -9844 8108 4676 -473 -7010 1438 -2104 6755 -250 -2068 -211 3797 -2347 -1366 -1783 733 -348 6188 1247 -1492 -5657 -5976 2102 -2833 -588 3836 -2009 -1237 -1029 -1202 2907 486 637 3046 581 73 3674 56 -1000 723 2189 -1009 -104 983 403 1755 1290 1333 1686 1077 -76 -1951 -1818 -1659 -1085 -992 894 73 -1375 859 1739 -3127 -1088 -522 -2497 1433 -383 -2136 -1361 -226 -219 285 46 1526 1656 682 503 -575 282 -1332 -1591 -762 -150 102 1450 841 -596 -2395 -1598 -24 -1354 -1238 393 -361 1045 1542 -426 540 -118 1136 442 437 294 -65 1249 -624 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