File name: Pandora243s1_Toronto-CNTower_20241127_L2Fit_fwvt1c3d20240624p1-8.txt File generation date: 20241128T052004.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20241127_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20241127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241127T123644.0Z 9097.525510 154 1 24.27 2 89.34 120.81 59.95 151.01 0.00 1 0.00 1 0 15 6.805e-03 6.737e-03 1.614e-03 1.606e-03 6.967742e+03 1.018036e+02 4.428640e+02 -6.000000e+00 3.702073e+02 274.94 -2.00 20.00 -2.00 505.44 0.00e+00 2.149311e-03 4.393245e-05 1.242575e-04 -6.000000e+00 1.878381e-04 274.94 -2.00 20.00 -2.00 501.12 0.00e+00 1.416488e+00 3.082116e-02 6.925834e-02 -6.000000e+00 1.348471e-01 222.36 -2.00 3.56 -2.00 502.62 0.00e+00 19.618 0.146 489.00 513.00 1 4.5985e+00 2.3552e-03 3.4273e-02 -6.0000e+00 1.0327e-02 -3.0638e-02 5.8987e-04 2.3653e-03 -6.0000e+00 2.6631e-03 1.1689e-03 -4.2501e-04 1.6228e-04 7.3980e-05 -6.0000e+00 7.1710e-04 -2.0310e-03 8.3810e-05 12 9 9 12 1 1 99.77 28.07 7.36 -0.00203 -0.00498 8 11 1 4 0 2696.660 36.25 19.99 28.07 4.20 3.9 804.81 -1589 -1258 -702 -61 179 464 1397 839 790 711 859 -31 22 -534 -738 -711 19 232 138 308 234 535 362 731 937 752 483 298 115 -256 -985 -930 -861 6 68 64 78 -51 -276 -231 -138 451 216 456 522 461 848 813 244 -180 -535 -1315 -1135 -1345 -625 -133 257 353 577 764 608 690 1036 859 412 397 238 155 -612 -509 -696 -965 -401 -396 -554 -664 -1038 -804 -702 -1382 -945 -926 -1000 -498 -338 -644 -459 -331 -694 -342 84 -90 329 255 517 250 239 -228 -839 -1175 -1251 -1024 -850 -494 96 -209 -5 -296 -237 -232 -370 -60 640 814 948 1727 1291 1529 1168 933 930 322 469 280 243 589 445 701 313 742 483 252 -268 -528 -393 -785 -184 -33 -80 441 406 391 298 468 132 84 -241 -395 -1139 -995 -1088 -1376 -1102 -631 -54 164 436 1326 783 739 661 816 -29 20 -497 -685 -664 18 216 131 298 228 523 356 720 927 749 481 295 112 -243 -927 -876 -827 6 67 64 78 -51 -271 -225 -135 441 214 458 530 472 865 823 245 -177 -516 -1250 -1065 -1272 -601 -131 259 350 574 759 606 692 1041 867 416 397 236 151 -596 -506 -688 -957 -399 -386 -548 -657 -1020 -776 -692 -1364 -930 -888 -969 -485 -333 -643 -460 -331 -697 -343 84 -91 328 256 514 253 236 -221 -797 -1101 -1165 -963 -821 -495 96 -213 -5 -301 -239 -235 -380 -62 672 838 983 1790 1357 1618 1243 988 973 334 482 288 252 613 465 734 330 778 507 263 -277 -543 -403 -816 -194 -35 -85 475 443 430 332 523 148 94 -269 -434 -1240 -1072 -1179 SQ 20241127T123931.7Z 9097.527450 158 1 25.37 2 88.91 121.30 59.72 151.74 0.00 1 0.00 1 0 22 5.420e-03 5.384e-03 3.480e-04 3.470e-04 7.005250e+03 2.188921e+01 4.699843e+02 -6.000000e+00 2.948561e+02 274.94 -2.00 20.00 -2.00 505.40 0.00e+00 1.947854e-03 9.476964e-06 1.132303e-04 -6.000000e+00 1.496220e-04 274.94 -2.00 20.00 -2.00 501.01 0.00e+00 1.315537e+00 6.692411e-03 6.261742e-02 -6.000000e+00 1.074906e-01 222.36 -2.00 3.56 -2.00 502.52 0.00e+00 18.615 0.125 489.00 513.00 1 2.0839e+00 5.1123e-04 3.1392e-02 -6.0000e+00 8.2310e-03 -2.7960e-02 1.2887e-04 2.1909e-03 -6.0000e+00 2.1248e-03 1.6734e-02 8.6420e-04 3.4953e-05 7.5679e-05 -6.0000e+00 5.7140e-04 6.9984e-03 -3.5872e-05 12 9 9 12 1 1 87.76 28.08 5.81 0.00700 0.01299 90 108 1 4 0 278.690 36.25 19.99 28.08 4.30 3.9 804.77 -1062 -889 -498 -14 358 664 1030 940 963 667 396 160 -109 -261 -407 -441 -272 91 190 255 231 405 507 480 637 538 457 227 -158 -602 -806 -756 -466 -85 76 26 197 95 -93 -249 -112 -66 117 334 514 548 569 390 167 -182 -550 -888 -1041 -982 -569 -206 -29 177 389 491 563 625 625 621 526 345 94 -117 -260 -463 -669 -584 -489 -308 -218 -374 -578 -630 -666 -810 -968 -842 -860 -613 -512 -532 -445 -409 -384 -330 -83 104 270 440 413 321 153 -179 -476 -928 -1125 -989 -770 -331 -120 -177 -345 -189 -261 -205 -94 142 307 666 969 1064 1264 1117 988 738 560 465 379 547 516 303 415 536 372 412 439 1 -285 -281 -453 -431 -151 -85 18 249 314 264 331 365 288 177 -2 -487 -804 -864 -799 -952 -793 -456 -13 336 625 988 897 921 646 380 152 -103 -243 -378 -412 -258 87 185 248 226 398 500 476 624 531 450 223 -155 -576 -773 -725 -447 -82 76 26 196 94 -93 -248 -112 -65 117 337 516 553 574 390 168 -180 -540 -855 -1008 -940 -555 -204 -29 178 394 498 571 627 631 629 531 345 95 -116 -256 -452 -660 -575 -478 -305 -218 -375 -574 -616 -654 -793 -950 -819 -844 -606 -504 -530 -445 -409 -384 -331 -83 104 274 447 417 318 150 -175 -456 -892 -1077 -940 -752 -325 -120 -180 -354 -192 -264 -207 -96 145 317 685 1002 1107 1325 1166 1035 770 586 480 387 559 532 315 433 559 389 431 458 1 -293 -287 -461 -443 -156 -89 19 264 337 285 356 395 312 192 -2 -524 -854 -910 -845 SQ 20241127T124221.5Z 9097.529416 162 1 29.88 2 88.47 121.79 59.50 152.49 0.00 1 0.00 1 0 15 4.683e-03 4.666e-03 3.697e-04 3.689e-04 6.451202e+03 2.315160e+01 4.338382e+02 -6.000000e+00 2.547712e+02 274.94 -2.00 20.00 -2.00 505.39 0.00e+00 1.836608e-03 1.007627e-05 1.064747e-04 -6.000000e+00 1.292797e-04 274.94 -2.00 20.00 -2.00 500.95 0.00e+00 1.320940e+00 7.138617e-03 5.819241e-02 -6.000000e+00 9.287114e-02 222.36 -2.00 3.56 -2.00 502.47 0.00e+00 17.465 0.103 489.00 513.00 1 2.5290e+00 5.4560e-04 2.8430e-02 -6.0000e+00 7.1116e-03 -2.4082e-02 1.3755e-04 2.0024e-03 -6.0000e+00 1.8357e-03 1.2568e-02 8.3199e-04 3.7240e-05 7.0160e-05 -6.0000e+00 4.9371e-04 3.1760e-03 -7.2285e-06 12 8 8 10 0 0 96.02 28.09 4.86 0.00318 0.00895 100 100 1 4 0 298.790 36.25 19.99 28.09 4.37 3.9 804.70 -746 -706 -421 -104 222 632 846 774 758 588 408 200 -65 -312 -407 -425 -198 60 211 144 210 426 433 495 527 508 291 299 -126 -480 -623 -539 -365 -41 14 -34 -7 60 -101 -173 -148 -51 21 297 474 503 471 306 74 -171 -442 -735 -888 -763 -510 -202 -61 62 287 456 504 555 461 422 492 348 96 -31 -178 -431 -538 -475 -341 -320 -59 -379 -550 -631 -558 -721 -864 -723 -705 -599 -435 -493 -421 -361 -345 -326 -82 27 298 266 369 257 63 -89 -420 -783 -1019 -866 -594 -315 -133 -249 -235 -222 -270 -216 -12 162 324 612 832 996 1046 1135 793 693 532 429 305 506 457 259 356 429 384 412 341 35 -305 -291 -409 -379 -152 -46 -12 270 281 234 326 276 308 119 -45 -408 -688 -747 -707 -673 -634 -389 -97 210 609 815 755 740 571 392 190 -61 -297 -386 -405 -187 58 206 142 205 418 427 490 525 507 291 296 -123 -466 -595 -514 -354 -40 14 -35 -7 60 -100 -170 -146 -50 21 296 478 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-45 8 39 -8 58 183 291 359 442 448 325 202 207 202 158 264 212 42 137 254 152 232 220 -1 -87 -34 -106 -52 91 -10 -76 118 144 108 223 238 126 23 -80 -234 -336 -344 -263 SQ 20241127T141002.9Z 9097.590312 207 5 5.46 2 76.35 138.39 55.72 177.14 0.00 1 0.00 1 0 15 1.918e-03 1.911e-03 6.345e-05 6.339e-05 1.304694e+03 3.571180e+00 9.394924e+01 -6.000000e+00 1.043174e+02 274.93 -2.00 20.00 -2.00 505.28 0.00e+00 5.125140e-04 1.715611e-06 3.012026e-05 -6.000000e+00 5.293628e-05 274.93 -2.00 20.00 -2.00 500.53 0.00e+00 3.706055e-01 1.244703e-03 1.239711e-02 -6.000000e+00 3.803269e-02 222.36 -2.00 3.56 -2.00 502.11 0.00e+00 4.140 0.001 489.00 513.00 1 -7.2733e-01 9.5298e-05 5.8309e-03 -6.0000e+00 2.9123e-03 3.9646e-04 2.4508e-05 4.1221e-04 -6.0000e+00 7.5185e-04 2.2220e+00 7.6115e-04 6.5214e-06 1.6915e-05 -6.0000e+00 2.0215e-04 1.0589e-03 -4.5592e-06 10 0 0 10 0 0 10.36 28.00 2.19 0.00106 0.00634 2011 2011 1 4 0 2.710 36.00 20.00 28.00 6.62 3.7 819.06 -152 -129 -145 -83 -2 279 383 272 294 282 174 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43 58 150 132 110 128 28 -90 -110 -257 -429 -336 -253 -169 -166 -325 -193 -36 -47 -4 27 -11 58 199 298 374 430 451 329 194 208 206 152 258 210 27 136 248 152 229 209 4 -73 -39 -108 -60 82 -1 -66 113 139 123 223 232 121 18 -82 -228 -333 -341 -265 SQ 20241127T141013.9Z 9097.590439 207 7 5.46 2 76.33 138.42 55.71 177.19 0.00 1 0.00 1 0 15 1.915e-03 1.908e-03 6.336e-05 6.330e-05 1.301627e+03 3.571841e+00 9.358939e+01 -6.000000e+00 1.041515e+02 274.93 -2.00 20.00 -2.00 505.28 0.00e+00 5.213262e-04 1.713229e-06 3.060176e-05 -6.000000e+00 5.285197e-05 274.93 -2.00 20.00 -2.00 500.53 0.00e+00 3.701704e-01 1.242855e-03 1.242349e-02 -6.000000e+00 3.797177e-02 222.36 -2.00 3.56 -2.00 502.11 0.00e+00 4.134 0.001 489.00 513.00 1 -7.2973e-01 9.5146e-05 5.8242e-03 -6.0000e+00 2.9076e-03 4.2826e-04 2.4466e-05 4.1173e-04 -6.0000e+00 7.5063e-04 2.2291e+00 7.3650e-04 6.5162e-06 1.6900e-05 -6.0000e+00 2.0183e-04 9.2020e-04 -2.7513e-06 10 0 0 10 0 0 10.52 28.00 2.19 0.00092 0.00603 2011 2011 1 4 0 2.710 36.00 20.00 28.00 6.62 3.7 819.06 -151 -135 -135 -89 0 292 384 274 296 285 172 97 -23 -62 -154 -166 -3 64 59 -42 12 182 219 239 247 179 65 86 -34 -184 -202 -103 -64 54 -84 -219 -48 74 -14 -107 -34 -59 0 94 153 151 174 112 12 -95 -251 -291 -391 -367 -201 -168 -193 -108 8 151 241 237 178 155 173 125 50 -38 -60 -154 -242 -169 -151 -65 -14 -185 -305 -191 -121 -151 -286 -292 -297 -239 -141 -212 -166 -133 -115 -105 29 76 152 133 100 127 26 -76 -115 -271 -446 -352 -263 -173 -172 -334 -186 -42 -65 15 41 -21 60 200 282 351 431 448 330 205 201 203 161 265 219 29 127 247 149 222 212 -18 -87 -31 -115 -55 92 -6 -72 112 143 126 212 246 127 35 -92 -232 -337 -347 -275 -146 -131 -133 -89 0 299 395 285 308 294 175 98 -23 -62 -153 -166 -3 65 60 -44 12 189 227 248 258 187 67 90 -34 -186 -202 -103 -64 54 -86 -227 -50 76 -14 -110 -34 -60 0 97 158 156 179 115 12 -95 -250 -286 -379 -357 -197 -168 -196 -110 8 154 245 241 181 157 176 126 50 -38 -59 -150 -237 -166 -148 -64 -14 -183 -301 -185 -117 -146 -276 -284 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-137 -52 -20 -195 -296 -182 -123 -140 -275 -288 -283 -238 -135 -190 -180 -132 -112 -105 37 76 147 144 108 133 18 -80 -114 -253 -423 -340 -256 -157 -183 -337 -188 -47 -44 -1 34 -11 59 194 297 364 437 456 315 207 201 208 158 258 207 43 133 234 154 234 205 -5 -78 -34 -109 -48 77 -32 -66 108 142 120 219 245 119 25 -79 -230 -339 -332 -266 SQ 20241127T141025.0Z 9097.590567 207 9 5.46 2 76.31 138.46 55.71 177.24 0.00 1 0.00 1 0 15 1.907e-03 1.901e-03 6.329e-05 6.323e-05 1.290259e+03 3.566774e+00 9.256777e+01 -6.000000e+00 1.037527e+02 274.93 -2.00 20.00 -2.00 505.28 0.00e+00 5.418273e-04 1.710876e-06 3.161207e-05 -6.000000e+00 5.264962e-05 274.93 -2.00 20.00 -2.00 500.53 0.00e+00 3.703137e-01 1.240819e-03 1.244475e-02 -6.000000e+00 3.782654e-02 222.36 -2.00 3.56 -2.00 502.11 0.00e+00 4.128 0.001 489.00 513.00 1 -7.3191e-01 9.5000e-05 5.8190e-03 -6.0000e+00 2.8965e-03 4.1700e-04 2.4425e-05 4.1062e-04 -6.0000e+00 7.4776e-04 2.2353e+00 7.6885e-04 6.5078e-06 1.7043e-05 -6.0000e+00 2.0106e-04 9.6846e-04 -3.4718e-06 10 0 0 10 0 0 18.47 28.00 2.19 0.00097 0.00630 2011 2011 1 4 0 2.710 36.00 20.00 28.00 6.65 3.7 819.06 -155 -139 -140 -81 -8 275 380 282 287 288 170 116 -30 -67 -136 -161 -11 74 70 -50 16 177 220 235 250 192 62 86 -31 -179 -200 -102 -57 52 -89 -210 -51 69 -11 -105 -36 -58 -6 96 146 145 167 99 24 -87 -255 -299 -387 -357 -205 -180 -193 -117 15 165 249 230 182 150 179 122 52 -43 -64 -152 -241 -173 -144 -52 -26 -189 -290 -194 -118 -152 -290 -283 -295 -232 -143 -212 -175 -131 -109 -113 28 60 159 140 111 116 26 -89 -119 -277 -449 -353 -255 -158 -181 -321 -186 -43 -67 1 39 -9 48 196 289 365 433 443 309 211 193 204 162 270 212 38 137 246 172 230 213 -21 -87 -34 -108 -50 89 -12 -66 106 144 122 214 222 124 19 -73 -235 -339 -346 -271 -151 -135 -138 -81 -8 282 392 291 296 298 173 118 -30 -67 -135 -160 -11 75 72 -52 17 183 228 244 261 200 64 88 -31 -181 -200 -102 -57 53 -91 -218 -53 72 -11 -108 -36 -60 -6 99 151 150 173 101 25 -87 -252 -294 -376 -347 -201 -180 -194 -119 16 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7.3277e-04 6.5124e-06 1.7252e-05 -6.0000e+00 2.0189e-04 7.6090e-04 -1.7335e-06 10 0 0 10 0 0 15.98 28.00 2.19 0.00076 0.00584 2011 2011 1 4 0 2.710 36.00 20.00 28.00 6.65 3.7 819.06 -164 -148 -130 -74 7 276 382 273 283 285 178 106 -19 -64 -134 -154 -1 70 50 -48 20 177 231 248 240 181 62 75 -27 -172 -214 -100 -69 58 -87 -218 -57 65 -20 -92 -36 -55 8 99 151 149 168 108 14 -96 -240 -302 -406 -350 -211 -177 -201 -108 12 160 239 242 183 146 172 132 46 -54 -56 -160 -247 -176 -135 -43 -21 -191 -303 -179 -121 -144 -296 -290 -297 -255 -140 -197 -181 -128 -121 -104 23 70 157 130 122 131 14 -90 -121 -269 -443 -353 -262 -173 -182 -335 -187 -45 -58 12 34 -22 60 200 296 358 438 439 313 210 198 207 162 263 217 42 151 247 156 217 216 -5 -94 -31 -107 -56 85 -11 -59 110 127 129 222 234 110 32 -69 -243 -335 -341 -278 -159 -143 -128 -73 7 283 394 285 292 294 182 107 -19 -64 -133 -154 -1 71 52 -50 21 183 240 257 250 189 65 77 -27 -174 -214 -99 -69 59 -89 -226 -59 67 -21 -94 -37 -56 8 102 156 155 174 111 15 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31 150 243 155 221 197 0 -62 -12 -92 -43 91 -16 -82 123 138 114 219 242 126 11 -81 -229 -314 -317 -239 SQ 20241127T151131.9Z 9097.633008 238 7 5.46 2 69.99 151.79 57.08 194.84 0.00 1 0.00 1 0 15 1.833e-03 1.826e-03 5.853e-05 5.847e-05 9.704970e+02 3.251425e+00 7.036869e+01 -6.000000e+00 9.971192e+01 274.93 -2.00 20.00 -2.00 505.27 0.00e+00 5.795945e-04 1.580755e-06 3.339308e-05 -6.000000e+00 5.059939e-05 274.93 -2.00 20.00 -2.00 500.50 0.00e+00 2.002113e-01 1.147674e-03 9.863130e-03 -6.000000e+00 3.635373e-02 222.36 -2.00 3.56 -2.00 502.09 0.00e+00 2.891 0.000 489.00 513.00 1 -7.0715e-01 8.7878e-05 4.1344e-03 -6.0000e+00 2.7837e-03 -2.2044e-04 2.2641e-05 2.9733e-04 -6.0000e+00 7.1864e-04 2.6154e+00 7.7360e-04 6.0260e-06 1.5706e-05 -6.0000e+00 1.9323e-04 7.5620e-04 -1.2523e-06 10 0 0 10 0 0 26.31 28.07 2.22 0.00076 0.00612 2270 2270 1 4 0 2.400 36.25 20.00 28.07 7.83 3.7 829.15 -123 -92 -133 -53 10 275 364 252 274 270 165 108 -12 -44 -124 -159 7 78 61 -51 -4 164 215 226 245 178 60 72 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20241127T181353.2Z 9097.759644 327 3 5.46 2 66.83 197.35 76.94 237.53 0.00 1 0.00 1 0 15 1.767e-03 1.761e-03 6.401e-05 6.394e-05 9.528065e+02 3.555613e+00 6.968623e+01 -6.000000e+00 9.612897e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.399087e-04 1.729011e-06 3.652041e-05 -6.000000e+00 4.878299e-05 274.91 -2.00 20.00 -2.00 500.49 0.00e+00 1.641617e-01 1.256074e-03 9.815674e-03 -6.000000e+00 3.505241e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.522 0.000 489.00 513.00 1 -4.7657e-01 9.6189e-05 3.6637e-03 -6.0000e+00 2.6840e-03 1.3718e-04 2.4785e-05 2.7427e-04 -6.0000e+00 6.9298e-04 2.1885e+00 9.5742e-04 6.5893e-06 1.6576e-05 -6.0000e+00 1.8630e-04 7.2500e-04 -7.7987e-06 10 0 0 10 0 0 95.73 28.25 2.23 0.00073 0.00737 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.52 3.7 846.53 -118 -96 -116 -78 5 269 355 249 267 269 161 110 -10 -46 -129 -142 16 80 53 -52 0 170 203 226 230 177 54 56 -40 -162 -186 -79 -46 47 -97 -234 -74 65 -22 -92 -31 -54 -16 85 128 128 151 92 7 -95 -237 -268 -383 -314 -169 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105 22 -67 -215 -302 -300 -240 SQ 20241127T181358.7Z 9097.759708 327 4 5.46 2 66.83 197.37 76.95 237.55 0.00 1 0.00 1 0 15 1.782e-03 1.777e-03 6.368e-05 6.361e-05 9.518956e+02 3.531935e+00 6.966114e+01 -6.000000e+00 9.693507e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.336517e-04 1.719118e-06 3.624600e-05 -6.000000e+00 4.919135e-05 274.91 -2.00 20.00 -2.00 500.49 0.00e+00 1.655059e-01 1.249314e-03 9.785069e-03 -6.000000e+00 3.534361e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.522 0.000 489.00 513.00 1 -4.8771e-01 9.5656e-05 3.6622e-03 -6.0000e+00 2.7064e-03 6.9023e-05 2.4657e-05 2.7414e-04 -6.0000e+00 6.9867e-04 2.2129e+00 8.3377e-04 6.5627e-06 1.6546e-05 -6.0000e+00 1.8786e-04 1.7158e-04 2.2095e-06 10 0 0 10 0 0 72.06 28.25 2.23 0.00017 0.00595 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.52 3.7 846.53 -120 -105 -124 -64 -4 271 363 245 267 270 173 105 -8 -64 -124 -134 5 75 52 -56 3 178 217 228 229 170 58 60 -48 -167 -194 -92 -53 53 -110 -225 -61 69 -3 -95 -33 -59 -9 87 136 120 168 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-11 -70 112 142 127 218 234 113 11 -93 -225 -305 -298 -238 SQ 20241127T181404.2Z 9097.759771 327 5 5.46 2 66.84 197.40 76.97 237.56 0.00 1 0.00 1 0 15 1.776e-03 1.771e-03 6.421e-05 6.414e-05 9.551947e+02 3.568937e+00 6.980790e+01 -6.000000e+00 9.662183e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.372781e-04 1.733426e-06 3.641758e-05 -6.000000e+00 4.903238e-05 274.91 -2.00 20.00 -2.00 500.50 0.00e+00 1.627259e-01 1.259403e-03 9.839711e-03 -6.000000e+00 3.522940e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.523 0.000 489.00 513.00 1 -4.7074e-01 9.6411e-05 3.6648e-03 -6.0000e+00 2.6976e-03 1.7344e-04 2.4851e-05 2.7487e-04 -6.0000e+00 6.9641e-04 2.1758e+00 8.2705e-04 6.6190e-06 1.6527e-05 -6.0000e+00 1.8725e-04 2.4971e-04 1.7469e-06 10 0 0 10 0 0 71.85 28.25 2.23 0.00025 0.00599 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.46 3.7 846.53 -128 -92 -120 -68 -9 274 359 253 269 264 175 114 -19 -52 -120 -137 9 85 49 -65 5 176 213 220 237 171 57 62 -43 -156 -189 -77 -50 53 -114 -235 -80 70 -14 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220 200 3 -64 -29 -81 -36 90 -1 -73 112 143 124 225 223 116 12 -75 -229 -303 -303 -233 SQ 20241127T181409.7Z 9097.759835 327 6 5.46 2 66.84 197.42 76.98 237.58 0.00 1 0.00 1 0 15 1.784e-03 1.779e-03 6.372e-05 6.365e-05 9.550056e+02 3.536923e+00 6.951446e+01 -6.000000e+00 9.705201e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.419368e-04 1.720245e-06 3.660649e-05 -6.000000e+00 4.925107e-05 274.91 -2.00 20.00 -2.00 500.49 0.00e+00 1.635546e-01 1.250137e-03 9.893681e-03 -6.000000e+00 3.538767e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.523 0.000 489.00 513.00 1 -4.8658e-01 9.5711e-05 3.6674e-03 -6.0000e+00 2.7097e-03 1.0635e-04 2.4674e-05 2.7522e-04 -6.0000e+00 6.9958e-04 2.2101e+00 9.0490e-04 6.5646e-06 1.6628e-05 -6.0000e+00 1.8809e-04 4.8595e-04 -3.1200e-06 10 0 0 10 0 0 91.80 28.25 2.23 0.00049 0.00676 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.46 3.6 846.53 -109 -109 -117 -78 -1 259 357 255 273 273 175 115 -14 -46 -135 -157 9 80 62 -58 -2 178 217 224 227 171 59 65 -43 -172 -187 -85 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189 185 156 257 200 19 132 226 147 210 200 -9 -61 -37 -88 -31 82 -6 -67 106 140 123 221 224 123 19 -78 -221 -309 -301 -235 SQ 20241127T181415.2Z 9097.759898 327 7 5.46 2 66.85 197.44 77.00 237.60 0.00 1 0.00 1 0 15 1.776e-03 1.771e-03 6.476e-05 6.468e-05 9.494064e+02 3.599397e+00 6.967378e+01 -6.000000e+00 9.660399e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.404719e-04 1.748295e-06 3.653993e-05 -6.000000e+00 4.902317e-05 274.91 -2.00 20.00 -2.00 500.50 0.00e+00 1.655285e-01 1.270601e-03 9.770391e-03 -6.000000e+00 3.522224e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.524 0.000 489.00 513.00 1 -4.5507e-01 9.7277e-05 3.6656e-03 -6.0000e+00 2.6971e-03 1.7588e-04 2.5071e-05 2.7374e-04 -6.0000e+00 6.9626e-04 2.1412e+00 8.0721e-04 6.6751e-06 1.6616e-05 -6.0000e+00 1.8722e-04 -4.1525e-05 5.0785e-06 10 0 0 10 0 0 55.98 28.25 2.23 -0.00004 0.00556 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.46 3.6 846.53 -113 -96 -108 -77 13 263 358 251 277 270 167 108 -10 -46 -133 -145 2 83 61 -56 -3 172 218 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38 172 258 323 398 404 288 186 179 180 147 248 199 23 139 230 157 216 201 4 -71 -23 -88 -30 82 -18 -76 102 130 125 230 226 123 18 -71 -225 -298 -292 -238 SQ 20241127T181420.7Z 9097.759962 327 8 5.46 2 66.85 197.46 77.01 237.62 0.00 1 0.00 1 0 15 1.776e-03 1.770e-03 6.495e-05 6.488e-05 9.483733e+02 3.601551e+00 6.951516e+01 -6.000000e+00 9.657837e+01 274.91 -2.00 20.00 -2.00 505.27 0.00e+00 6.437834e-04 1.753329e-06 3.673537e-05 -6.000000e+00 4.901110e-05 274.91 -2.00 20.00 -2.00 500.50 0.00e+00 1.660056e-01 1.273680e-03 9.779339e-03 -6.000000e+00 3.521659e-02 222.36 -2.00 3.56 -2.00 502.08 0.00e+00 2.524 0.000 489.00 513.00 1 -4.4841e-01 9.7519e-05 3.6675e-03 -6.0000e+00 2.6966e-03 1.7578e-04 2.5135e-05 2.7367e-04 -6.0000e+00 6.9623e-04 2.1266e+00 9.9425e-04 6.6915e-06 1.6686e-05 -6.0000e+00 1.8717e-04 8.0494e-04 -9.1243e-06 10 0 0 10 0 0 96.73 28.25 2.23 0.00080 0.00770 1996 1996 1 4 0 2.730 36.25 20.00 28.25 10.46 3.6 846.53 -131 -91 -103 -80 12 277 355 244 260 266 175 107 -8 -55 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