File name: Pandora243s1_Toronto-CNTower_20250111_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20250112T053003.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250111_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250111T143448.4Z 9142.607504 320 1 29.94 2 76.18 139.54 108.50 350.55 0.00 1 0.00 1 0 25 2.862e-01 6.602e-03 1.189e-01 2.972e-03 6.391690e-01 1.519521e-03 7.372970e-03 -6.000000e+00 1.593868e-01 223.20 -2.00 3.56 -2.00 320.58 0.00e+00 1.760794e-03 5.690539e-04 4.802574e-04 -6.000000e+00 6.856151e-03 271.30 -2.00 20.00 -2.00 320.14 0.00e+00 4.092 0.001 302.00 328.00 3 2.3131e+00 4.4733e-03 5.1342e-02 -6.0000e+00 3.9344e-01 7.8886e-02 5.8221e-03 3.3650e-02 -6.0000e+00 4.2986e-01 -8.3173e-02 6.1394e-03 1.7652e-02 -6.0000e+00 2.5520e-01 2.7987e-02 3.1107e-03 5.8495e-03 -6.0000e+00 1.0847e-01 4.9787e-04 -6.7039e-04 8.0001e-05 6.5787e-05 -6.0000e+00 7.6468e-03 -9.2040e-04 0.0000e+00 11 9 0 11 8 0 99.99 26.93 0.66 -0.00092 -0.00596 85 85 1 5 0 352.220 35.25 20.00 26.93 6.70 3.7 821.19 -134568 -73683 -132493 -138808 -93863 -31595 -76581 -100867 -6377 -86410 -37508 -27251 -69804 -38249 -28125 -52379 938 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-355 -1293 -486 -1877 -469 253 528 301 1050 326 -497 14 21 -304 -261 170 533 1228 -685 -795 -673 -545 -1078 -616 -1432 -1332 -254 439 10 527 635 395 445 861 -123 -211 -730 -335 -301 -316 275 608 1174 645 -61 213 914 951 683 -197 158 -168 505 -167 -487 -287 -317 118 -87 -125 -642 -112 SS 20250111T144002.3Z 9142.611138 323 1 30.09 2 75.57 140.62 108.64 351.70 0.00 1 0.00 1 0 17 4.936e-01 1.448e-02 3.446e-01 1.091e-02 6.024736e-01 5.619427e-03 6.812773e-03 -6.000000e+00 2.749835e-01 223.20 -2.00 3.56 -2.00 320.71 0.00e+00 3.895240e-03 2.169204e-03 5.653936e-04 -6.000000e+00 1.203919e-02 271.30 -2.00 20.00 -2.00 320.27 0.00e+00 3.931 0.001 302.00 328.00 3 4.2073e+00 1.6791e-02 4.9058e-02 -6.0000e+00 6.7873e-01 1.6161e-01 2.2053e-02 3.2416e-02 -6.0000e+00 7.4157e-01 -1.0964e-01 2.3116e-02 1.7260e-02 -6.0000e+00 4.4072e-01 3.3970e-02 1.1615e-02 7.6878e-03 -6.0000e+00 1.8859e-01 8.5694e-05 -3.8594e-04 3.0334e-04 6.7944e-05 -6.0000e+00 1.3227e-02 -1.2343e-03 0.0000e+00 12 8 8 10 0 0 99.97 26.93 0.57 -0.00123 -0.00413 13 13 1 5 0 2314.180 35.25 20.00 26.93 6.83 3.7 821.59 -171753 900000 -90430 -105445 142702 -196028 -110689 -83243 -3446 111917 186091 -5228 900000 -18891 134879 -10473 160921 -52197 154464 79989 251146 11365 37265 -6150 -47189 -21955 -36232 -37916 590 18690 17105 21927 -5368 23253 37434 2516 -13827 14582 631 23889 1100 3634 -5551 3996 -1626 1392 -3369 7973 367 12291 6444 5437 2314 1863 1897 -825 3490 4813 -7084 368 -1523 4687 6753 338 -356 -5093 -3669 -6278 5790 5476 2553 2178 2384 2763 2986 3547 395 -2411 -6860 792 1138 -2949 -3664 -2503 -1027 -1250 -786 -15 1552 -261 1780 -2282 401 -1459 311 2343 -1723 2056 1413 1221 -1058 -2655 -376 578 -1108 -1141 896 211 -1681 -70 242 783 -688 196 219 -1082 579 -814 368 -110 1004 -54 287 2202 733 -1130 -584 -60 818 548 -1081 -208 783 63 -632 769 -322 -253 -20 668 -381 -904 215 -3821 900000 -1050 -1326 1518 -5688 -1499 -966 -37 1191 1980 -56 900000 -274 1435 -203 1712 -1868 1643 851 2672 266 714 -196 -2410 -911 -1735 -1775 19 557 619 887 -326 1089 1434 139 -1015 962 58 2059 131 449 -785 523 -228 194 -502 1094 57 1805 1118 1053 502 438 466 -215 888 1188 -1907 91 -404 1296 2076 123 -133 -1924 -1351 -2451 2230 2424 1263 1112 1184 1279 1249 1321 143 -918 -3095 391 647 -1976 -2670 -1899 -821 -1062 -694 -13 1356 -221 1366 -1700 280 -1073 252 2143 -1888 2465 1822 1547 -1273 -2912 -371 577 -1212 -1310 1062 269 -2386 -110 373 1253 -1104 298 343 -1639 870 -1299 615 -175 1702 -89 455 3289 1062 -1604 -796 -85 1292 968 -1916 -387 1501 129 -1384 1738 -750 -596 -46 1483 -803 -1809 412 SS 20250111T144512.3Z 9142.614726 326 1 29.66 2 74.98 141.70 108.75 352.84 0.00 1 0.00 1 0 17 2.469e-01 7.288e-03 1.035e-01 3.664e-03 5.894734e-01 1.856741e-03 6.824275e-03 -6.000000e+00 1.375450e-01 223.20 -2.00 3.56 -2.00 320.34 0.00e+00 3.763203e-03 6.488264e-04 4.142232e-04 -6.000000e+00 5.916371e-03 271.30 -2.00 20.00 -2.00 319.88 0.00e+00 3.787 0.001 302.00 328.00 3 2.9788e+00 5.3790e-03 4.7309e-02 -6.0000e+00 3.3953e-01 9.6328e-02 6.7610e-03 3.0777e-02 -6.0000e+00 3.7095e-01 -8.4259e-02 6.7410e-03 1.6567e-02 -6.0000e+00 2.2023e-01 2.6816e-02 3.4690e-03 6.8342e-03 -6.0000e+00 9.3607e-02 3.5054e-04 -4.9595e-04 9.9907e-05 6.5113e-05 -6.0000e+00 6.5985e-03 -1.2762e-03 0.0000e+00 11 8 0 10 0 0 85.44 26.95 0.60 -0.00128 -0.00500 29 29 1 5 0 1022.560 35.25 20.00 26.95 6.61 3.6 818.36 -67524 -122678 -18734 -97217 -114350 -114957 -115564 -35860 -21387 -81132 -14721 -27135 -39240 -15114 -7919 -28358 -6881 -10872 -21898 315 9508 -8371 -13197 -7237 9416 -10864 -13021 -10557 3591 1264 -7191 -9907 -277 2599 -3693 -759 -3047 -1997 -2307 -4514 -2410 1375 2332 -1040 3043 476 6122 -1187 137 2960 6569 2939 1201 1999 3596 -702 1040 1579 -238 490 275 855 2944 1711 3175 -387 701 1364 -710 1118 1328 1147 547 330 -1182 -1342 -1499 -2345 -1240 -1554 -756 -1031 -1964 -1538 -960 60 -580 846 551 696 574 -143 1437 -228 334 345 -96 754 377 -346 -915 -472 -1116 -1020 -901 -574 -829 -626 -157 61 175 701 401 204 78 -444 456 -173 18 13 402 -26 490 522 129 -244 85 1085 301 488 -186 -66 -248 238 50 -224 -221 -246 169 75 -410 282 -304 -636 -2272 -128 -1494 -1921 -1972 -2189 -346 -199 -1450 -142 -349 -729 -281 -170 -872 -189 -342 -822 10 275 -290 -509 -284 333 -493 -605 -460 136 55 -403 -669 -19 182 -260 -53 -245 -190 -269 -632 -364 213 374 -176 501 82 1020 -219 26 585 1394 715 323 576 1066 -224 333 496 -74 150 89 304 1162 689 1288 -156 304 607 -326 578 745 664 311 176 -582 -652 -686 -1106 -595 -883 -492 -762 -1582 -1300 -863 57 -529 777 550 661 505 -118 1122 -187 305 332 -107 946 507 -460 -1137 -525 -1149 -1074 -1022 -681 -1040 -838 -228 91 285 1182 671 326 117 -639 657 -262 28 22 660 -41 748 765 196 -359 121 1586 459 829 -346 -120 -470 474 107 -501 -505 -533 362 166 -853 550 -579 SS 20250111T145944.2Z 9142.624817 332 1 28.65 2 73.41 144.80 108.99 356.06 0.00 1 0.00 1 0 25 2.216e-01 1.315e-02 2.535e-01 1.014e-02 5.314816e-01 5.105159e-03 6.128971e-03 -6.000000e+00 1.242901e-01 223.20 -2.00 3.56 -2.00 320.25 0.00e+00 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