File name: Pandora243s1_Toronto-CNTower_20250531_L2Fit_fout2c3d20240624p1-8.txt
File generation date: 20250601T052516.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c3p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250531_L1_smca1c3d20240624p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250531
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250531T143912.5Z 9282.610562 234 1 31.28 2 38.76 111.15 86.16 65.35 0.00 1 0.00 1 0 17 2.549e-02 1.032e-02 2.062e-02 7.247e-03 2.449508e-01 3.637444e-03 2.985227e-03 -6.000000e+00 1.467406e-02 231.83 -2.00 3.56 -2.00 317.21 0.00e+00 4.931554e-04 5.054314e-04 2.020019e-04 -6.000000e+00 6.379606e-04 281.85 -2.00 20.00 -2.00 316.48 0.00e+00 1.281 0.000 302.00 328.00 3 6.4596e+00 9.6620e-03 1.8175e-02 -6.0000e+00 3.6832e-02 8.3407e-02 1.0856e-02 1.2995e-02 -6.0000e+00 3.9908e-02 -1.5965e-02 6.4589e-03 6.3208e-03 -6.0000e+00 2.3675e-02 1.3268e-03 3.1338e-03 1.7201e-03 -6.0000e+00 9.9753e-03 1.7063e-04 -3.7146e-04 2.0617e-04 1.9246e-05 -6.0000e+00 6.8272e-04 -4.4650e-03 0.0000e+00 12 9 8 11 8 0 86.98 27.86 0.48 -0.00446 -0.00726 9 9 1 5 0 3474.470 36.25 20.00 27.86 15.71 3.7 886.43 2465 5804 -136 -15408 -1712 -11203 1249 1324 -4944 -933 -513 -6197 -7283 1614 664 -2442 -196 7986 3786 2734 4693 294 3731 1550 4265 1353 1430 -973 -5099 -2490 3530 -977 549 -2361 -2912 -592 -568 -2152 1542 -2468 1133 -1241 -1100 -855 441 25 1805 -2145 -1940 -504 381 1404 -169 -638 272 -1074 1362 3238 -615 1873 -26 1190 1936 1447 304 3077 -2202 -553 97 -948 254 2262 774 -280 -1066 -1013 -2577 -1780 -2062 -2119 -913 -1086 -1677 -1746 -527 314 762 -102 1374 809 1066 -1754 168 -759 -10 -418 502 2272 199 -260 -2361 589 -747 -896 -1093 -148 -391 95 542 1054 1072 880 971 354 -195 -751 -532 -193 -106 859 -320 220 -423 746 421 -819 -928 -411 212 -544 110 371 -495 76 141 -965 235 258 554 130 54 -421 6 288 767 -19 -2254 -195 -1386 147 175 -762 -141 -75 -1012 -1359 314 147 -599 -48 1879 961 723 1221 79 999 447 1248 419 432 -279 -1420 -677 963 -299 178 -784 -897 -179 -191 -862 713 -1362 646 -750 -680 -527 267 15 1041 -1249 -1101 -285 226 878 -113 -449 194 -788 988 2277 -440 1302 -19 931 1625 1286 266 2385 -1675 -406 76 -851 244 2203 757 -265 -938 -795 -1860 -1218 -1497 -1734 -825 -1078 -1772 -1930 -561 355 899 -125 1648 1025 1237 -1902 163 -724 -10 -465 614 3014 257 -360 -3123 695 -847 -1062 -1412 -199 -550 138 751 1543 1646 1359 1432 536 -271 -984 -695 -263 -155 1324 -509 343 -646 1074 575 -1076 -1157 -511 280 -771 163 559 -763 121 238 -1568 387 434 934 214 86 -710 10
SS 20250531T151356.6Z 9282.634683 253 1 4.15 2 33.11 120.96 80.60 70.92 0.00 1 0.00 1 0 17 7.824e-03 6.150e-03 3.656e-03 2.427e-03 2.085240e-01 1.248464e-03 2.537819e-03 -6.000000e+00 4.503255e-03 231.84 -2.00 3.56 -2.00 315.12 0.00e+00 2.814070e-04 1.081501e-04 2.481626e-05 -6.000000e+00 1.957998e-04 281.85 -2.00 20.00 -2.00 314.51 0.00e+00 1.193 0.000 302.00 328.00 3 3.4993e+00 3.2305e-03 1.6063e-02 -6.0000e+00 1.1303e-02 2.6210e-02 3.5892e-03 1.0931e-02 -6.0000e+00 1.2248e-02 1.5780e-03 2.0475e-03 5.3232e-03 -6.0000e+00 7.2659e-03 -3.0725e-03 9.0199e-04 1.4709e-03 -6.0000e+00 3.0610e-03 3.9256e-03 5.6062e-05 6.7169e-05 1.8570e-05 -6.0000e+00 2.0954e-04 -3.8018e-03 0.0000e+00 12 1 1 12 1 1 99.91 27.88 0.47 -0.00380 -0.00338 5 43 1 5 0 691.190 36.00 20.00 27.88 15.72 3.7 886.15 -177 -572 -392 -1978 -3161 -1465 -228 869 139 31 -177 -919 790 1470 -195 -468 1244 156 483 945 539 652 829 1279 -360 67 -198 -465 -425 95 1448 1805 538 -1466 -1349 -1416 -1117 -228 -793 -714 -671 -458 -908 -899 -302 22 -1354 -232 -1011 -55 681 1237 731 638 1095 919 915 528 903 434 1015 1223 1470 877 40 -902 -437 755 581 186 166 -107 515 41 -422 -611 -291 -485 97 -234 -876 -1834 -1766 -2045 -837 -512 -183 -85 611 618 292 -281 345 405 470 -95 454 778 535 -157 -659 -35 2 -728 -187 -580 -789 -182 -225 152 153 199 280 189 -208 180 -189 93 217 257 30 -255 36 872 581 420 487 181 793 290 -172 41 124 66 -313 -97 105 -7 44 -146 -367 -563 -299 -55 -190 -128 -589 -921 -416 -64 269 47 11 -60 -327 287 600 -84 -216 578 76 241 452 260 311 406 657 -196 37 -107 -233 -212 47 744 922 298 -819 -694 -735 -644 -144 -539 -526 -528 -371 -720 -712 -248 18 -1082 -177 -756 -41 533 1021 607 554 965 787 793 454 795 384 886 1146 1417 853 39 -855 -382 669 531 185 171 -114 542 42 -415 -562 -252 -402 84 -219 -878 -1945 -1897 -2304 -964 -605 -227 -105 769 742 335 -306 355 421 496 -106 537 974 676 -201 -794 -40 2 -841 -226 -737 -1012 -242 -302 208 218 285 394 254 -265 224 -236 117 282 345 41 -347 50 1130 740 529 580 217 1007 377 -227 55 168 90 -438 -143 153 -10 66 -213 -536 -797 -427
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