File name: Pandora145s1_Toronto-Scarborough_20230628_L2Fit_fwvt1c4d20220506p1-8.txt File generation date: 20230703T234236.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v4d20220506.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20230628_L1_smca1c4d20220506p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20230628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Copy of session 3 for New VP First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0721 492.1932 492.3143 492.4354 492.5564 492.6775 492.7985 492.9195 493.0405 493.1615 493.2824 493.4034 493.5243 493.6452 493.7661 493.8870 494.0078 494.1287 494.2495 494.3703 494.4911 494.6119 494.7326 494.8534 494.9741 495.0948 495.2155 495.3362 495.4568 495.5775 495.6981 495.8187 495.9393 496.0599 496.1804 496.3010 496.4215 496.5420 496.6625 496.7830 496.9034 497.0239 497.1443 497.2647 497.3851 497.5055 497.6258 497.7462 497.8665 497.9868 498.1071 498.2274 498.3477 498.4679 498.5881 498.7083 498.8285 498.9487 499.0689 499.1890 499.3091 499.4292 499.5493 499.6694 499.7895 499.9095 500.0295 500.1495 500.2695 500.3895 500.5094 500.6294 500.7493 500.8692 500.9891 501.1090 501.2288 501.3487 501.4685 501.5883 501.7081 501.8279 501.9476 502.0674 502.1871 502.3068 502.4265 502.5462 502.6658 502.7855 502.9051 503.0247 503.1443 503.2638 503.3834 503.5029 503.6225 503.7420 503.8614 503.9809 504.1004 504.2198 504.3392 504.4586 504.5780 504.6974 504.8167 504.9361 505.0554 505.1747 505.2940 505.4132 505.5325 505.6517 505.7709 505.8901 506.0093 506.1285 506.2476 506.3668 506.4859 506.6050 506.7241 506.8431 506.9622 507.0812 507.2002 507.3192 507.4382 507.5572 507.6761 507.7950 507.9140 508.0329 508.1517 508.2706 508.3894 508.5083 508.6271 508.7459 508.8647 508.9834 509.1022 509.2209 509.3396 509.4583 509.5770 509.6956 509.8143 509.9329 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230628T125932.1Z 8579.541344 199 1 28.23 2 56.47 88.77 148.90 3.82 0.00 1 0.00 1 0 15 3.403e-03 3.404e-03 1.532e-03 1.528e-03 2.446361e+03 8.913573e+01 1.820813e+02 -6.000000e+00 1.824840e+02 285.49 -2.00 20.00 -2.00 505.25 0.00e+00 5.802216e-04 4.148533e-05 3.547754e-05 -6.000000e+00 9.441901e-05 285.49 -2.00 20.00 -2.00 500.37 0.00e+00 1.163175e-01 2.981623e-02 1.637315e-02 -6.000000e+00 6.631306e-02 232.99 -2.00 3.57 -2.00 501.97 0.00e+00 1.805 0.000 489.00 513.00 1 7.9825e+00 2.2790e-03 3.0228e-03 -6.0000e+00 5.0723e-03 1.2946e-02 5.9949e-04 4.1873e-04 -6.0000e+00 1.3363e-03 5.0917e-04 1.4434e-04 1.2645e-04 2.3352e-05 -6.0000e+00 2.8990e-04 1.3898e-02 1.9688e-07 10 0 0 10 0 0 94.14 17.78 0.56 0.01390 0.01490 8 8 1 4 0 3528.000 22.19 15.00 17.78 25.46 21.8 1100.00 -1029 -423 -141 -10 477 686 630 727 687 137 170 -224 -143 83 -190 -245 -56 -110 179 375 -9 171 313 -106 306 608 298 34 -283 -607 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-21 236 334 375 634 368 389 91 302 286 239 -225 -63 -114 -135 26 244 16 237 -7 197 219 -322 -159 -192 -503 -84 303 27 324 461 235 258 299 203 388 -89 -246 -277 -564 SQ 20230628T130352.3Z 8579.544355 202 1 30.74 2 55.69 89.52 148.85 5.78 0.00 1 0.00 1 0 15 3.520e-03 3.501e-03 1.088e-03 1.085e-03 2.207006e+03 6.271318e+01 1.668268e+02 -6.000000e+00 1.887001e+02 285.49 -2.00 20.00 -2.00 505.25 0.00e+00 5.609549e-04 2.947564e-05 3.444094e-05 -6.000000e+00 9.765710e-05 285.49 -2.00 20.00 -2.00 500.37 0.00e+00 1.030348e-01 2.112801e-02 1.453695e-02 -6.000000e+00 6.860477e-02 232.99 -2.00 3.57 -2.00 501.97 0.00e+00 1.769 0.000 489.00 513.00 1 7.4576e+00 1.6160e-03 2.9046e-03 -6.0000e+00 5.2473e-03 1.1030e-02 4.2510e-04 3.7820e-04 -6.0000e+00 1.3831e-03 8.6653e-04 5.5141e-04 8.9962e-05 2.2358e-05 -6.0000e+00 2.9989e-04 1.3444e-02 -2.5665e-05 10 0 0 10 0 0 99.96 17.78 0.58 0.01344 0.01727 10 10 1 4 0 3073.110 22.19 14.99 17.78 25.49 21.8 1100.00 -917 -428 -57 64 382 744 666 722 410 366 93 20 -624 -188 -481 -366 -20 -19 27 338 231 -246 199 137 225 315 303 -43 -46 -457 -446 -410 -8 16 448 358 128 -17 -222 -229 -206 -107 278 142 500 255 322 288 -340 -371 -571 -739 -725 -387 -352 32 100 163 188 195 361 339 309 490 303 78 175 -243 -434 -235 -350 -193 -258 -163 -24 -63 -9 -626 -590 -432 -185 -398 -260 -264 -78 222 -242 -145 -295 -205 33 181 164 494 415 243 314 -392 -468 -391 -685 -674 -441 -172 352 77 -1 -119 -332 -237 6 213 179 490 575 665 362 137 338 304 159 -21 28 -71 115 237 156 284 88 119 26 6 -165 -350 -288 -321 80 296 239 85 267 422 419 514 358 86 -124 -579 -689 -754 -904 -429 -57 67 392 776 709 774 438 384 97 21 -653 -193 -493 -378 -20 -19 29 364 249 -257 214 143 237 330 316 -45 -48 -455 -454 -420 -9 17 471 375 132 -18 -232 -238 -214 -112 285 148 521 266 334 295 -353 -374 -558 -730 -710 -383 -349 33 101 165 190 195 363 344 314 497 305 80 176 -242 -428 -227 -337 -187 -253 -162 -24 -63 -9 -599 -560 -408 -176 -384 -252 -258 -78 221 -241 -144 -295 -199 32 180 166 496 410 236 308 -376 -437 -358 -632 -635 -432 -170 352 77 -1 -115 -318 -229 6 212 181 483 568 659 363 137 334 304 157 -20 27 -70 113 232 153 277 86 117 25 6 -153 -334 -274 -303 77 289 230 82 260 412 411 507 353 84 -118 -555 -650 -713 SQ 20230628T131414.1Z 8579.551552 209 1 3.71 2 53.82 91.32 148.64 10.43 0.00 1 0.00 1 0 15 3.524e-03 3.505e-03 1.154e-04 1.153e-04 1.716773e+03 6.501070e+00 1.303346e+02 -6.000000e+00 1.889413e+02 285.49 -2.00 20.00 -2.00 505.27 0.00e+00 6.018837e-04 3.130148e-06 3.586618e-05 -6.000000e+00 9.778884e-05 285.49 -2.00 20.00 -2.00 500.49 0.00e+00 8.158795e-02 2.229902e-03 1.215546e-02 -6.000000e+00 6.870322e-02 232.99 -2.00 3.57 -2.00 502.08 0.00e+00 1.689 0.000 489.00 513.00 1 9.6193e-01 1.7049e-04 2.7317e-03 -6.0000e+00 5.2547e-03 -1.1002e-02 4.4835e-05 3.1256e-04 -6.0000e+00 1.3853e-03 5.8149e-01 9.0786e-04 9.5908e-06 1.8890e-05 -6.0000e+00 3.0033e-04 1.4394e-02 -4.1049e-05 10 0 0 10 0 0 99.94 17.78 0.65 0.01439 0.02069 593 593 1 4 0 6.220 22.19 14.99 17.78 25.77 22.1 1100.00 -961 -535 -122 231 479 509 690 613 503 382 76 -88 -256 -340 -323 -328 -173 21 187 341 188 109 144 151 304 375 349 -98 -122 -430 -697 -555 -282 29 369 435 89 -84 -231 -223 -239 55 189 330 403 400 337 146 -178 -390 -672 -839 -691 -642 -285 17 231 230 197 160 218 386 446 417 351 195 27 -214 -329 -287 -348 -292 -142 -115 24 69 -151 -503 -590 -425 -440 -334 -219 -268 -137 -119 -153 -142 -164 -122 42 152 274 478 500 278 69 -334 -445 -636 -668 -536 -295 -51 294 162 -158 -266 -368 -284 -38 238 408 472 582 545 479 332 360 151 30 6 -57 -56 196 148 131 210 184 9 115 76 -238 -287 -277 -233 36 244 225 249 335 300 362 404 287 62 -157 -352 -658 -786 -936 -519 -123 235 487 528 714 639 522 399 79 -89 -257 -343 -325 -332 -175 22 195 358 197 115 151 156 316 388 360 -102 -123 -428 -688 -552 -287 30 385 453 92 -86 -238 -227 -245 57 193 341 420 416 349 149 -183 -389 -663 -827 -674 -623 -285 17 233 233 199 161 220 392 456 425 354 198 27 -212 -322 -282 -341 -287 -139 -114 24 68 -146 -490 -571 -411 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