File name: Pandora145s1_Toronto-Scarborough_20240114_L2Fit_fwvt1c9d20230821p1-8.txt File generation date: 20241123T063720.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20240114_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20240114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0731 492.1943 492.3153 492.4364 492.5575 492.6785 492.7995 492.9205 493.0415 493.1625 493.2834 493.4044 493.5253 493.6462 493.7671 493.8880 494.0088 494.1297 494.2505 494.3713 494.4921 494.6128 494.7336 494.8543 494.9751 495.0958 495.2165 495.3371 495.4578 495.5784 495.6990 495.8197 495.9402 496.0608 496.1814 496.3019 496.4224 496.5429 496.6634 496.7839 496.9044 497.0248 497.1452 497.2656 497.3860 497.5064 497.6267 497.7471 497.8674 497.9877 498.1080 498.2283 498.3485 498.4688 498.5890 498.7092 498.8294 498.9495 499.0697 499.1898 499.3100 499.4301 499.5502 499.6702 499.7903 499.9103 500.0303 500.1503 500.2703 500.3903 500.5103 500.6302 500.7501 500.8700 500.9899 501.1098 501.2296 501.3495 501.4693 501.5891 501.7089 501.8286 501.9484 502.0681 502.1878 502.3075 502.4272 502.5469 502.6665 502.7862 502.9058 503.0254 503.1450 503.2645 503.3841 503.5036 503.6231 503.7426 503.8621 503.9816 504.1010 504.2205 504.3399 504.4593 504.5786 504.6980 504.8174 504.9367 505.0560 505.1753 505.2946 505.4138 505.5331 505.6523 505.7715 505.8907 506.0099 506.1290 506.2482 506.3673 506.4864 506.6055 506.7246 506.8436 506.9627 507.0817 507.2007 507.3197 507.4387 507.5576 507.6766 507.7955 507.9144 508.0333 508.1522 508.2710 508.3899 508.5087 508.6275 508.7463 508.8650 508.9838 509.1025 509.2212 509.3399 509.4586 509.5773 509.6959 509.8146 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240114T141053.8Z 8779.590901 91 1 29.42 2 78.91 134.51 101.27 97.24 0.00 1 0.00 1 0 15 3.802e-03 3.780e-03 1.282e-03 1.280e-03 9.924075e+02 6.707788e+01 8.337826e+01 -6.000000e+00 1.931787e+02 272.15 -2.00 20.00 -2.00 505.28 0.00e+00 1.424642e-03 3.364775e-05 7.850948e-05 -6.000000e+00 1.021466e-04 272.15 -2.00 20.00 -2.00 500.49 0.00e+00 7.588575e-01 2.467070e-02 1.390972e-02 -6.000000e+00 7.382655e-02 223.38 -2.00 3.57 -2.00 502.07 0.00e+00 5.020 0.002 489.00 513.00 1 7.3204e+00 1.8794e-03 7.3788e-03 -6.0000e+00 5.6247e-03 -5.7585e-04 4.9517e-04 4.4857e-04 -6.0000e+00 1.4864e-03 5.9612e-04 2.8038e-04 1.0670e-04 2.5430e-05 -6.0000e+00 3.2377e-04 -1.8448e-03 1.9650e-05 11 8 0 10 0 0 99.77 17.75 0.73 -0.00184 0.00010 8 8 1 4 0 3676.310 22.40 15.00 17.75 0.12 20.4 964.78 -800 -293 -346 66 578 544 873 634 546 329 9 263 -158 -331 -654 -295 10 132 162 332 -83 -31 31 458 130 590 205 48 33 -334 -848 -623 2 -158 389 396 87 -229 -131 -262 -76 -53 343 81 251 485 49 -7 -144 -258 -586 -854 -908 -536 -437 135 65 331 224 8 223 524 252 339 455 129 -85 -248 33 -381 -478 -387 15 65 48 -15 -430 -612 -680 -420 -522 -234 -267 -459 -281 -58 -213 -239 -117 -310 98 214 434 575 411 208 103 -207 -328 -771 -980 -610 -313 -84 292 83 -38 -239 -453 -401 -65 7 297 410 609 566 610 559 434 364 298 168 -64 93 283 197 53 98 79 183 -36 100 -118 52 -131 -466 -74 311 200 222 488 387 267 418 188 35 -148 -480 -533 -806 -779 -279 -343 65 585 563 918 675 579 344 9 267 -158 -328 -647 -293 11 137 166 343 -86 -33 32 475 136 616 214 50 34 -333 -839 -619 2 -162 410 418 91 -236 -134 -265 -77 -54 354 85 265 513 51 -7 -147 -256 -584 -832 -877 -523 -441 136 67 342 231 8 229 541 262 352 466 130 -85 -245 32 -378 -471 -372 15 64 48 -14 -415 -600 -662 -407 -511 -224 -256 -444 -276 -57 -210 -235 -116 -308 98 210 433 575 406 203 101 -200 -308 -737 -908 -573 -305 -82 291 82 -37 -229 -445 -386 -64 7 300 419 623 565 613 561 430 366 296 164 -63 92 281 196 53 97 79 181 -36 96 -112 49 -123 -447 -73 301 196 220 484 385 268 422 191 35 -145 -472 -515 -782 SQ 20240114T141527.4Z 8779.594067 94 1 30.20 2 78.33 135.42 100.47 97.97 0.00 1 0.00 1 0 15 3.750e-03 3.720e-03 6.910e-04 6.900e-04 9.499193e+02 3.597445e+01 7.678627e+01 -6.000000e+00 1.905142e+02 272.15 -2.00 20.00 -2.00 505.27 0.00e+00 1.339181e-03 1.816065e-05 7.335813e-05 -6.000000e+00 1.007367e-04 272.15 -2.00 20.00 -2.00 500.49 0.00e+00 7.177165e-01 1.326122e-02 1.331772e-02 -6.000000e+00 7.282676e-02 223.38 -2.00 3.57 -2.00 502.08 0.00e+00 4.789 0.002 489.00 513.00 1 6.2194e+00 1.0106e-03 7.0302e-03 -6.0000e+00 5.5483e-03 -1.7242e-03 2.6664e-04 4.2938e-04 -6.0000e+00 1.4667e-03 1.8596e-03 6.2000e-04 5.7562e-05 2.3732e-05 -6.0000e+00 3.1934e-04 1.2429e-03 -1.9528e-05 10 0 0 10 0 0 99.90 17.76 0.74 0.00124 0.00554 19 19 1 4 0 1589.140 22.40 15.00 17.76 0.14 20.5 964.87 -944 -483 -237 173 410 491 655 698 488 450 182 62 -155 -351 -547 -401 -137 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-474 -263 -92 339 112 -124 -308 -355 -423 17 141 474 474 719 646 461 455 434 169 69 130 -83 112 148 151 75 269 211 -26 180 62 -287 -306 -320 -442 4 221 212 199 277 306 416 476 265 92 -99 -439 -679 -656 SQ 20240114T142019.8Z 8779.597452 97 1 26.86 2 77.72 136.40 99.62 98.75 0.00 1 0.00 1 0 15 3.532e-03 3.509e-03 3.762e-04 3.757e-04 8.840712e+02 1.951944e+01 7.597238e+01 -6.000000e+00 1.794766e+02 272.15 -2.00 20.00 -2.00 505.27 0.00e+00 1.190770e-03 9.871502e-06 6.592078e-05 -6.000000e+00 9.490011e-05 272.15 -2.00 20.00 -2.00 500.51 0.00e+00 7.034420e-01 7.217619e-03 1.173600e-02 -6.000000e+00 6.860871e-02 223.38 -2.00 3.57 -2.00 502.09 0.00e+00 4.568 0.002 489.00 513.00 1 4.9348e+00 5.4970e-04 6.6693e-03 -6.0000e+00 5.2270e-03 -3.0514e-03 1.4507e-04 4.0286e-04 -6.0000e+00 1.3818e-03 6.9532e-03 6.8373e-04 3.1340e-05 2.1992e-05 -6.0000e+00 3.0084e-04 1.3581e-03 -2.1739e-05 12 1 1 12 1 1 99.56 17.76 0.76 0.00136 0.00610 52 59 1 4 0 506.740 22.40 15.00 17.76 0.10 20.4 964.80 -785 -469 -242 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