File name: Pandora145s1_Toronto-Scarborough_20240402_L2Fit_fwvt1c8d20221111p1-8.txt
File generation date: 20240403T052738.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c8p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v8d20221111.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20240402_L1_smca1c8d20221111p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20240402
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 4 for field cal VP 20221111
First and last pixel inside fitting window: 1647 1796
Nominal wavelengths inside fitting window [nm]: 492.0874 492.2085 492.3296 492.4507 492.5718 492.6928 492.8138 492.9348 493.0558 493.1768 493.2978 493.4187 493.5397 493.6606 493.7815 493.9024 494.0232 494.1441 494.2649 494.3857 494.5065 494.6273 494.7481 494.8688 494.9895 495.1102 495.2309 495.3516 495.4723 495.5929 495.7136 495.8342 495.9548 496.0754 496.1959 496.3165 496.4370 496.5575 496.6780 496.7985 496.9190 497.0394 497.1598 497.2803 497.4007 497.5210 497.6414 497.7618 497.8821 498.0024 498.1227 498.2430 498.3632 498.4835 498.6037 498.7239 498.8441 498.9643 499.0845 499.2046 499.3248 499.4449 499.5650 499.6850 499.8051 499.9252 500.0452 500.1652 500.2852 500.4052 500.5251 500.6451 500.7650 500.8849 501.0048 501.1247 501.2446 501.3644 501.4842 501.6040 501.7238 501.8436 501.9634 502.0831 502.2029 502.3226 502.4423 502.5619 502.6816 502.8012 502.9209 503.0405 503.1601 503.2796 503.3992 503.5187 503.6383 503.7578 503.8773 503.9967 504.1162 504.2356 504.3551 504.4745 504.5939 504.7132 504.8326 504.9519 505.0712 505.1905 505.3098 505.4291 505.5484 505.6676 505.7868 505.9060 506.0252 506.1444 506.2635 506.3827 506.5018 506.6209 506.7400 506.8590 506.9781 507.0971 507.2161 507.3351 507.4541 507.5731 507.6920 507.8110 507.9299 508.0488 508.1677 508.2865 508.4054 508.5242 508.6430 508.7618 508.8806 508.9993 509.1181 509.2368 509.3555 509.4742 509.5929 509.7116 509.8302 509.9488
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240402T144441.1Z 8858.614365 291 1 29.06 2 51.44 126.96 81.59 216.75 0.00 1 0.00 1 0 15 4.157e-03 4.162e-03 2.601e-03 2.589e-03 4.048175e+03 1.542995e+02 3.034535e+02 -6.000000e+00 2.148821e+02 276.31 -2.00 20.00 -2.00 505.27 0.00e+00 7.752225e-04 6.881795e-05 4.843166e-05 -6.000000e+00 1.127936e-04 276.31 -2.00 20.00 -2.00 500.27 0.00e+00 1.026259e-01 5.087991e-02 2.772452e-02 -6.000000e+00 8.093134e-02 227.25 -2.00 3.57 -2.00 501.90 0.00e+00 1.601 0.000 489.00 513.00 1 8.6245e+00 3.8688e-03 3.4728e-03 -6.0000e+00 6.1720e-03 1.1560e-02 1.0205e-03 6.9615e-04 -6.0000e+00 1.6308e-03 2.7437e-04 -6.6749e-05 2.1273e-04 4.1593e-05 -6.0000e+00 3.5412e-04 -5.1768e-03 -6.8896e-05 11 8 0 10 0 0 10.56 17.92 0.71 -0.00518 -0.00564 15 15 1 4 0 1936.950 22.50 15.00 17.92 16.87 22.5 1100.00 -892 -442 -714 366 604 277 465 467 949 -113 418 -265 8 -628 -22 -470 -223 81 24 428 220 15 316 94 292 534 315 19 -461 -194 -1115 -21 -326 202 114 370 542 -319 272 -639 -518 -280 656 91 370 169 637 28 -311 -528 -445 -866 -1012 -52 -163 113 173 350 -367 241 -40 267 423 855 -54 534 -430 112 -805 165 -376 -447 -143 -119 345 -148 536 -126 -409 -486 82 -468 -237 -197 -137 7 -419 -208 217 -636 -271 69 431 1007 281 688 -237 -21 -639 -318 -903 -445 21 -199 531 267 24 -848 -341 -74 465 -86 408 -211 669 330 392 120 251 117 -148 324 -625 -151 -193 148 98 494 342 88 179 264 -419 71 -341 -291 149 -159 -29 -206 323 171 196 61 602 -138 211 -183 8 -726 -899 -428 -720 379 640 300 513 520 1047 -124 449 -283 9 -650 -23 -486 -233 86 26 451 232 16 333 100 311 567 334 20 -496 -200 -1143 -22 -341 209 122 395 569 -333 278 -655 -531 -289 677 96 392 180 669 29 -319 -528 -451 -860 -995 -51 -167 113 177 360 -378 245 -41 275 437 877 -55 534 -427 109 -783 156 -355 -426 -137 -116 339 -145 508 -118 -380 -450 77 -442 -224 -188 -132 7 -411 -202 210 -623 -267 69 435 1010 279 666 -225 -20 -577 -281 -803 -402 20 -195 531 268 24 -829 -329 -72 458 -86 413 -216 682 323 387 119 246 118 -147 315 -611 -149 -190 146 96 483 334 86 173 250 -393 66 -317 -275 145 -150 -27 -199 311 165 190 60 586 -134 199 -169 8 -659
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SQ 20240402T151102.9Z 8858.632672 310 1 28.36 2 47.82 134.15 84.46 221.65 0.00 1 0.00 1 0 15 3.767e-03 3.766e-03 1.434e-03 1.430e-03 2.754759e+03 8.126814e+01 2.096791e+02 -6.000000e+00 1.947320e+02 276.31 -2.00 20.00 -2.00 505.24 0.00e+00 5.556997e-04 3.802580e-05 3.437892e-05 -6.000000e+00 1.022124e-04 276.31 -2.00 20.00 -2.00 500.33 0.00e+00 1.594813e-01 2.791784e-02 1.960610e-02 -6.000000e+00 7.335969e-02 227.25 -2.00 3.57 -2.00 501.94 0.00e+00 1.487 0.000 489.00 513.00 1 7.7766e+00 2.1301e-03 2.8068e-03 -6.0000e+00 5.5943e-03 6.5724e-03 5.6103e-04 4.9512e-04 -6.0000e+00 1.4786e-03 6.5187e-04 6.6309e-04 1.1801e-04 3.0672e-05 -6.0000e+00 3.2095e-04 -6.0341e-03 -8.5754e-05 10 0 0 10 0 0 20.43 17.96 0.62 -0.00603 -0.00143 8 8 1 4 0 3544.310 22.50 15.00 17.96 17.27 22.8 1100.00 -1125 -361 -370 190 583 651 622 716 436 443 -69 33 -274 -439 -528 -545 -167 -201 347 290 135 157 191 204 373 453 291 -80 50 -298 -908 -609 -139 -237 474 526 -40 -5 -195 -313 -451 155 522 337 602 381 210 363 -353 -449 -795 -537 -818 -467 -45 -39 306 106 95 116 253 360 687 292 125 182 85 -174 -157 -329 -535 -495 -106 -121 -86 159 -299 -393 -646 -258 -346 -182 -283 -146 -470 -129 114 -124 -62 -291 229 205 478 375 394 109 125 -231 -344 -490 -723 -525 -369 -255 321 163 -209 38 -389 -203 -213 120 102 401 370 631 624 420 61 189 363 258 7 -176 359 75 194 29 242 -117 348 -34 -433 -118 -147 -278 -139 412 136 149 94 216 202 634 269 45 -7 -408 -573 -829 -1124 -351 -373 199 597 680 663 769 468 467 -73 34 -278 -456 -546 -567 -170 -210 370 312 146 169 205 220 390 473 315 -86 51 -297 -900 -606 -141 -251 496 551 -42 -6 -204 -326 -471 162 551 348 626 398 217 370 -369 -456 -784 -535 -808 -465 -44 -40 307 107 96 117 254 364 696 296 126 186 86 -174 -155 -319 -517 -482 -104 -121 -87 158 -292 -377 -615 -244 -330 -176 -275 -142 -468 -129 113 -124 -62 -281 222 203 478 376 388 105 122 -221 -320 -449 -664 -491 -359 -250 320 162 -205 36 -371 -196 -209 119 103 405 376 641 618 417 60 189 356 249 6 -172 350 74 189 29 235 -114 334 -32 -403 -109 -135 -261 -134 401 129 144 91 209 197 621 264 44 -7 -391 -540 -784
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