File name: Pandora145s1_Toronto-Scarborough_20240515_L2Fit_fout2c8d20221111p1-8.txt
File generation date: 20240516T051708.4Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c8p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v8d20221111.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20240515_L1_smca1c8d20221111p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20240515
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 4 for field cal VP 20221111
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0546 305.1954 305.3363 305.4771 305.6179 305.7586 305.8994 306.0402 306.1809 306.3217 306.4624 306.6031 306.7438 306.8845 307.0252 307.1659 307.3065 307.4472 307.5878 307.7284 307.8691 308.0097 308.1503 308.2908 308.4314 308.5720 308.7125 308.8531 308.9936 309.1341 309.2746 309.4151 309.5556 309.6961 309.8365 309.9770 310.1174 310.2578 310.3982 310.5386 310.6790 310.8194 310.9598 311.1001 311.2405 311.3808 311.5212 311.6615 311.8018 311.9421 312.0823 312.2226 312.3629 312.5031 312.6433 312.7836 312.9238 313.0640 313.2042 313.3444 313.4845 313.6247 313.7648 313.9049 314.0451 314.1852 314.3253 314.4654 314.6054 314.7455 314.8856 315.0256 315.1656 315.3057 315.4457 315.5857 315.7256 315.8656 316.0056 316.1455 316.2855 316.4254 316.5653 316.7052 316.8451 316.9850 317.1249 317.2647 317.4046 317.5444 317.6842 317.8240 317.9639 318.1036 318.2434 318.3832 318.5229 318.6627 318.8024 318.9422 319.0819 319.2216 319.3612 319.5009 319.6406 319.7802 319.9199 320.0595 320.1991 320.3387 320.4783 320.6179 320.7575 320.8971 321.0366 321.1761 321.3157 321.4552 321.5947 321.7342 321.8737 322.0131 322.1526 322.2920 322.4315 322.5709 322.7103 322.8497 322.9891 323.1285 323.2678 323.4072 323.5465 323.6859 323.8252 323.9645 324.1038 324.2431 324.3824 324.5216 324.6609 324.8001 324.9393
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240515T140604.6Z 8901.587554 254 1 29.67 2 46.10 107.12 112.16 37.47 0.00 1 0.00 1 0 17 8.616e-03 5.767e-03 2.930e-03 1.440e-03 2.309553e-01 7.229521e-04 2.825336e-03 -6.000000e+00 4.853358e-03 230.99 -2.00 3.57 -2.00 316.15 0.00e+00 3.254143e-04 7.746496e-05 3.778127e-05 -6.000000e+00 2.099530e-04 281.20 -2.00 20.00 -2.00 315.49 0.00e+00 1.440 0.000 302.00 328.00 3 4.4377e+00 1.8891e-03 1.8860e-02 -6.0000e+00 1.2170e-02 3.6223e-02 2.1082e-03 1.2169e-02 -6.0000e+00 1.3194e-02 -6.7615e-03 1.2189e-03 5.9398e-03 -6.0000e+00 7.8293e-03 1.9120e-04 5.6812e-04 1.6547e-03 -6.0000e+00 3.3273e-03 1.1288e-03 -3.2343e-05 3.8257e-05 1.7765e-05 -6.0000e+00 2.1437e-04 -3.2867e-03 -1.6415e-05 11 1 0 11 8 0 99.95 17.91 0.33 -0.00329 -0.00353 27 27 1 5 0 1098.520 22.50 15.00 17.91 29.81 23.8 1100.00 193 -952 -31 -2287 -606 -3610 -929 -253 2012 -1114 -1711 -2490 -1989 -247 -8 -260 -321 631 166 1449 727 883 648 1023 837 1149 168 124 -91 327 1225 913 1807 -179 -1071 -1683 -2112 -1363 16 -608 -507 -721 -532 -1205 -407 -737 -646 -575 -581 -362 526 459 856 660 693 1322 882 883 172 767 456 1210 1072 1674 580 -112 -538 -795 673 256 493 9 292 401 481 86 -463 -1031 -250 -430 -645 -1041 -1764 -1629 -1157 -833 -247 -153 137 543 257 112 -142 456 598 424 435 671 234 64 -200 -751 -218 -112 -697 -794 -509 -744 -341 227 432 200 274 -29 -98 159 208 29 329 106 -151 126 112 241 790 445 267 935 519 808 38 -119 -199 -97 -76 -223 13 73 -134 -62 -184 -582 -308 37 -204 -7 -474 -107 -615 -162 -50 434 -262 -391 -571 -506 -70 -2 -85 -109 218 60 531 275 326 242 403 348 495 73 51 -34 117 459 369 785 -82 -457 -687 -942 -702 9 -378 -345 -510 -387 -888 -295 -537 -459 -395 -388 -239 361 338 661 538 542 1043 714 712 136 596 365 1030 993 1548 544 -103 -451 -640 561 247 489 9 303 402 451 77 -399 -834 -207 -376 -635 -1067 -1944 -1751 -1324 -1024 -302 -193 173 661 308 122 -148 449 619 484 517 836 314 84 -248 -908 -244 -129 -891 -1016 -676 -1034 -467 329 627 296 408 -41 -130 208 269 37 449 149 -218 179 156 338 1042 562 336 1155 688 1081 54 -164 -276 -140 -116 -343 20 117 -219 -98 -281 -907 -465
SS 20240515T142858.5Z 8901.603455 270 1 30.60 2 42.21 112.52 109.67 42.48 0.00 1 0.00 1 0 17 1.075e-02 7.140e-03 7.214e-03 3.306e-03 2.228576e-01 1.658937e-03 2.712597e-03 -6.000000e+00 6.057178e-03 230.99 -2.00 3.57 -2.00 316.32 0.00e+00 5.434836e-04 1.843417e-04 4.885474e-05 -6.000000e+00 2.620688e-04 281.20 -2.00 20.00 -2.00 315.64 0.00e+00 1.348 0.000 302.00 328.00 3 5.9966e+00 4.3479e-03 1.7899e-02 -6.0000e+00 1.5188e-02 5.9378e-02 4.8538e-03 1.1735e-02 -6.0000e+00 1.6467e-02 -4.4509e-03 2.8162e-03 5.7192e-03 -6.0000e+00 9.7714e-03 -2.2850e-03 1.3256e-03 1.6082e-03 -6.0000e+00 4.1524e-03 2.6013e-04 -2.5380e-04 8.8382e-05 1.6902e-05 -6.0000e+00 2.6758e-04 -3.5320e-03 -4.4758e-05 11 8 0 10 0 0 99.88 17.96 0.13 -0.00353 -0.00544 8 8 1 5 0 3824.710 22.50 15.00 17.96 30.80 24.1 1100.00 -379 1707 1006 27 -2281 383 -5328 51 -344 -154 -2272 -1843 -274 -360 1065 -1870 -98 -600 3151 555 720 -705 -581 294 164 -888 1140 248 -195 -305 633 1488 2445 -203 -1134 -2804 -3060 -2588 -948 -632 -1039 319 -678 283 11 203 -307 46 -147 -198 23 411 1431 160 1094 704 1982 512 1315 -197 469 1166 1170 1080 336 -11 -1170 -1454 -333 693 207 778 37 1389 178 470 -1089 -1862 -1783 24 -1419 -686 -1441 -1703 -767 -489 274 -48 921 -117 772 -467 -700 -1493 325 -360 817 876 1051 278 -281 -938 -740 -388 -655 -511 -362 -418 -498 552 622 888 -123 175 -563 -35 -588 -289 116 449 63 432 102 429 1165 16 407 59 824 216 -61 -561 -277 119 -252 56 430 -81 460 246 -368 -743 -632 -67 322 195 5 -369 62 -875 9 -68 -32 -466 -373 -61 -91 303 -602 -32 -201 1054 197 261 -253 -210 111 65 -371 467 95 -69 -104 225 563 992 -88 -454 -1085 -1289 -1260 -506 -395 -712 224 -494 206 8 146 -217 32 -97 -129 16 300 1087 120 836 548 1552 405 1006 -163 366 970 1056 1043 328 -10 -956 -1228 -271 640 211 771 37 1417 172 404 -915 -1467 -1442 21 -1346 -713 -1502 -1845 -880 -602 333 -60 1155 -143 922 -512 -743 -1513 339 -389 964 1147 1380 363 -367 -1128 -829 -446 -829 -684 -473 -569 -707 825 923 1332 -179 250 -736 -44 -752 -383 155 643 93 630 145 585 1587 21 500 71 1060 300 -84 -789 -393 173 -391 86 674 -131 748 392 -568 -1177 -970
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